Concept explainers
(a)
Interpretation:
The variables that lead to band broadening are to be stated.
Concept introduction:
The band broadening is defined as a phenomenon. It leads the poor chromatographic performance and resolution which results in the reduction of the separation efficiency. This problem is responsible for both the quality and accuracy of the separation.
(b)
Interpretation:
The variable that leads to band separation in gas-liquid chromatography is to be stated.
Concept introduction:
The band broadening is defined as a phenomenon. It leads the poor chromatographic performance and resolution which results in the reduction of the separation efficiency. This problem is responsible for both the quality and accuracy of the separation.
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Chapter 27 Solutions
Principles of Instrumental Analysis
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- Explain IR spectroscopy as a characterization technique.arrow_forwardWhat is the major limitation of IR regarding the materials that can be used for instrumental components.arrow_forwardIn general, we want to have absorptions less than or equal to 1. Given that an ethanol solution of compound Y (150.0 g/mol) in a 1.00 cm quartz cell has an extinction coefficient (ε) of 23,150 at λmax=235 nm, what is the top concentration, in μM, we should consider for compound Y? Report your answer to the correct number of significant figures. Do not report the units in your answer.arrow_forward
- 2 Describe the primary barrier towards the broad adoption of FT-IR in the mid-20th century.arrow_forwardWhy HPLC is an important technique in the fields of chemistry . explain with different reasons?arrow_forwardDo not give handwriting solution Using 0.901 g/cm3 for density of tri - isopropylsilanol (i-C3H7)3SiOH and assuming spherical shape of the molecule, determine its molecular cross section and the maximal grafting density for these molecules supported on a flat silica surface.arrow_forward
- What major impact does reducing film thickness of stationary phase in a wall-coated capillary column have on the separation efficiency (i.e., band broadening) in GC: Shorter tr (retention time) Lower C-term Lower resolution Higher A-term Higher B-termarrow_forwardWhat are factors that determine the solid partitioning of a chemical/element and why is this an important property for transport and toxicity?arrow_forwardDescribe the similarities between fluorescence detectors in HPLC and chemiluminescence detectors in HPLC. What issues experienced with fluorescence detectors are resolved using chemiluminescence detectors?arrow_forward
- Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage LearningChemistry for Engineering StudentsChemistryISBN:9781285199023Author:Lawrence S. Brown, Tom HolmePublisher:Cengage Learning