Chapter 25, Problem 25.32P

Interpretation Introduction

(a)

Interpretation: The product formed by the reaction of ${\text{C}}_{\text{6}}{\text{H}}_{\text{5}}{\text{N}}_{\text{2}}{}^{+}{\text{Cl}}^{-}$ with given compound is to be drawn.

Concept introduction: Primary amines on reaction with ${\text{NaNO}}_{\text{2}}$ in the presence of $\text{HCl}$ yield diazonium salt. Aryl diazonium salts undergo substitution reaction and form different benzene derivatives. Diazonium salt undergoes coupling reaction when it is treated with an aromatic ring that contains electron releasing group.

Interpretation Introduction

(b)

Interpretation: The product formed by the reaction of ${\text{C}}_{\text{6}}{\text{H}}_{\text{5}}{\text{N}}_{\text{2}}{}^{+}{\text{Cl}}^{-}$ with given compound is to be drawn.

Concept introduction: Primary amines on reaction with ${\text{NaNO}}_{\text{2}}$ in the presence of $\text{HCl}$ yield diazonium salt. Aryl diazonium salts undergo substitution reaction and form different benzene derivatives. Diazonium salt undergoes coupling reaction when it is treated with an aromatic ring that contains electron releasing group.

Interpretation Introduction

(c)

Interpretation: The product formed by the reaction of ${\text{C}}_{\text{6}}{\text{H}}_{\text{5}}{\text{N}}_{\text{2}}{}^{+}{\text{Cl}}^{-}$ with given compound is to be drawn.

Concept introduction: Primary amines on reaction with ${\text{NaNO}}_{\text{2}}$ in the presence of $\text{HCl}$ yield diazonium salt. Aryl diazonium salts undergo substitution reaction and form different benzene derivatives. Diazonium salt undergoes coupling reaction when it is treated with an aromatic ring that contains electron releasing group.