Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 23.6, Problem 11P
Interpretation Introduction
Interpretation: Among the given
Concept Introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.
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In general, amines are nucleophilic due to:
Select one:
a. Existence of negative charge in amine group
b. Amines are more electronegative than other functional groups
C. Lone pairs in the amine group available for donation
d. None of the above
Which amines cannot be prepared by reduction of an amide?
The hydrolysis of an amide in acidic conditions forms
A. a carboxylate salt and an alcohol
B. a carboxylate salt and an amine
C. an alcohol and an amine salt (an ammonium ion)
D. a carboxylic acid and an amine salt (an ammonium ion)
Chapter 23 Solutions
Organic Chemistry (6th Edition)
Ch. 23.2 - Prob. 1PCh. 23.3 - Prob. 2PCh. 23.3 - Prob. 3PCh. 23.4 - Prob. 4PCh. 23.6 - Prob. 7PCh. 23.6 - Prob. 8PCh. 23.6 - Prob. 9PCh. 23.6 - Prob. 10PCh. 23.6 - Prob. 11PCh. 23.6 - Prob. 12P
Ch. 23.6 - Prob. 13PCh. 23.6 - Prob. 14PCh. 23.6 - Prob. 15PCh. 23.8 - Prob. 16PCh. 23.8 - Problem 25.18
Write out steps to show how each of...Ch. 23.9 - Prob. 18PCh. 23.9 - Prob. 19PCh. 23.9 - Prob. 20PCh. 23.9 - Problem 25.22
Which nitrogen atom in each compound...Ch. 23.9 - Prob. 22PCh. 23.10 - Prob. 23PCh. 23.10 - Prob. 24PCh. 23.11 - Prob. 25PCh. 23.11 - Prob. 26PCh. 23.11 - Problem 25.28
Draw the major product formed in...Ch. 23.12 - Prob. 28PCh. 23.13 - Prob. 29PCh. 23 - Give a systematic or common name for each...Ch. 23 - Prob. 38PCh. 23 - 25.40 How many stereogenic centers are present in...Ch. 23 - 25.41 Rank the compounds in each group in order of...Ch. 23 - 25.42 Decide which atom in each molecule is most...Ch. 23 - Prob. 47PCh. 23 - Prob. 48PCh. 23 - Prob. 49PCh. 23 - 25.52 Draw the products formed when methylaniline ...Ch. 23 - Prob. 53PCh. 23 - 25.60 A chiral amine A having the configuration...Ch. 23 - Prob. 68PCh. 23 - Prob. 69PCh. 23 - Prob. 70PCh. 23 - 25.70 Devise a synthesis of each biologically...Ch. 23 - 25.71 Devise a synthesis of each compound from...
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- Give each of the following amines an IUPAC name. a. b. c.arrow_forwardClassify the following compound: A. Imine В. Hemiacetal C. Amine D. Enaminearrow_forwardWhat are the functional groups present in this antibacterial antibiotic? A. Nitro, phenyl, amine, carbonyl, hydroxyl B. Nitro, phenyl, amine, carbonyl, C. Nitro, phenyl, amine, hydroxyl D. Nitro, phenol, amine, carbonyl, hydroxyl A brief explanation would be highly appreciated + upvotearrow_forward
- Draw a structural formula for each amine and amine derivative. Q.) Benzylaminearrow_forward19. Which of the following molecules contain an amide? H2N-CHC-OH ČH3 a. c. NH2 NH2 b. H2N H2N-CHC-N-CHC-OH d. CHз CH3arrow_forward1. What amine and what carbonyl compound are required to make the following molecule: N.arrow_forward
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