(a) Interpretation: The amine formed by reduction of given amide is to be determined. Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

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Answer 1

Question

Chapter 23.6, Problem 10P

Interpretation Introduction

(a)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

Interpretation Introduction

(b)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

Interpretation Introduction

(c)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

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Draw a structural formula for each amine and amine derivative. Q.) tert-Butylamine

In general, amines are nucleophilic due to: Select one: a. Existence of negative charge in amine group b. Amines are more electronegative than other functional groups C. Lone pairs in the amine group available for donation d. None of the above

3.63 Quinapril (trade name Accupril) is a drug used to treat hypertension and congestive heart falure. a. Identify the functional groups in quinapril. b. Classify any alcohol, amide, or amine as 1°, 2°, or 3°º. H. C. At which sites can quinapril hydrogen bond to water? d. At which sites can quinapril hydrogen bond to acetone [(CH3),CO]? e. Label the most acidic hydrogen atom. f. Which site is most basic? quinapril

Answer 2

Question

Chapter 23.6, Problem 10P

Interpretation Introduction

(a)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

Interpretation Introduction

(b)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

Interpretation Introduction

(c)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

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Answer 3

Question

Chapter 23.6, Problem 10P

Interpretation Introduction

(a)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

Interpretation Introduction

(b)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

Interpretation Introduction

(c)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

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Answer 4

Question

Chapter 23.6, Problem 10P

Interpretation Introduction

(a)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

Interpretation Introduction

(b)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

Interpretation Introduction

(c)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

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Answer 5

Chapter 23.6, Problem 10P

Interpretation Introduction

(a)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

Interpretation Introduction

(b)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

Interpretation Introduction

(c)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

Answer 6

Chapter 23.6, Problem 10P

Interpretation Introduction

(a)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

Answer 7

Chapter 23.6, Problem 10P

Interpretation Introduction

(a)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

Answer 8

Interpretation Introduction

(b)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

Answer 9

Interpretation Introduction

(b)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

Answer 10

Interpretation Introduction

(c)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

Answer 11

Interpretation Introduction

(c)

Interpretation: The amine formed by reduction of given amide is to be determined.

Concept introduction: The synthesis of amine can be carried out by reduction of nitro compounds, nitriles and amides. Nitro compounds can be reduced to amines using catalytic hydrogenation or iron/palladium metal in presence of acid. Nitriles and amides are reduced to amines using lithium aluminium hydride.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 23.2 - Prob. 1P Ch. 23.3 - Prob. 2P Ch. 23.3 - Prob. 3P Ch. 23.4 - Prob. 4P Ch. 23.6 - Prob. 7P Ch. 23.6 - Prob. 8P Ch. 23.6 - Prob. 9P Ch. 23.6 - Prob. 10P Ch. 23.6 - Prob. 11P Ch. 23.6 - Prob. 12P

Solution Summary: The author explains that the amine formed by reduction of given amide is to be determined.

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Chapter 23 Solutions