Organic Chemistry (6th Edition)
Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
Question
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Chapter 23.12, Problem 28P
Interpretation Introduction

(a)

Interpretation: The product formed by the treatment of given compound with NaNO2 and HCl is to be drawn.

Concept introduction: Primary and secondary amines on reaction with NaNO2 in the presence of HCl yield different products. Diazonium salt is formed by the reaction of primary amine with NaNO2+HCl whereas N-nitrosamine is formed by the reaction of secondary amine with NaNO2+HCl.

Interpretation Introduction

(b)

Interpretation: The product formed by the treatment of given compound with NaNO2 and HCl is to be drawn.

Concept introduction: Primary and secondary amines on reaction with NaNO2 in the presence of HCl yield different products. Diazonium salt is formed by the reaction of primary amine with NaNO2+HCl whereas N-nitrosamine is formed by the reaction of secondary amine with NaNO2+HCl.

Interpretation Introduction

(c)

Interpretation: The product formed by the treatment of given compound with NaNO2 and HCl is to be drawn.

Concept introduction: Primary and secondary amines on reaction with NaNO2 in the presence of HCl yield different products. Diazonium salt is formed by the reaction of primary amine with NaNO2+HCl whereas N-nitrosamine is formed by the reaction of secondary amine with NaNO2+HCl.

Interpretation Introduction

(d)

Interpretation: The product formed by the treatment of given compound with NaNO2 and HCl is to be drawn.

Concept introduction: Primary and secondary amines on reaction with NaNO2 in the presence of HCl yield different products. Diazonium salt is formed by the reaction of primary amine with NaNO2+HCl whereas N-nitrosamine is formed by the reaction of secondary amine with NaNO2+HCl.

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Draw the product formed when (CH3)2CHOH is treated with each reagent (a, b and c)
Draw the product formed when (CH3)2CHOH is treated with each reagent (d, e and f)
Answer each question for A and B depicted in the ball-and-stick models.a. What is the IUPAC name for each compound?b. What product is formed when each compound is treated with NaOH?c. Name the products formed in part (b).d. Draw the structure of an isomer that is at least 105 times less acidic than each compound.
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