(a) Interpretation: The formula and the name of the given structures needs to be determined. Concept introduction: The set of the chemical symbols and the elements is known as the chemical formula of any compound. In any compound, they are present in their relative proportion.

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Answer 1

Question

Chapter 21, Problem 21.84SP

Interpretation Introduction

(a)

Interpretation:

The formula and the name of the given structures needs to be determined.

Concept introduction:

The set of the chemical symbols and the elements is known as the chemical formula of any compound. In any compound, they are present in their relative proportion.

Interpretation Introduction

(b)

Interpretation:

The linkage isomer structures needs to be determined.

Concept introduction:

The linkage isomer is defined as the coordination compounds that have the different connectivity of metal with the ligand.

Interpretation Introduction

(c)

Interpretation:

The ionization isomer structures needs to be determined.

Concept introduction:

The ionization isomer can be defined as the coordination compound that has a difference in anion and bonded to the metal.

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Students have asked these similar questions

(b) Consider the oxalate (ox) ligand and answer the following questions:(i) Draw the structure of the ox ligand.(ii) Identify all the donor atoms of the ligand.(iii) What is the denticity of the ligand?(iv) What is the charge of the ligand?(v) Draw the structure of a homoleptic octahedral complex with ox as the ligand.Clearly show the geometry at the metal centre.(vi) Identify the stereoisomer in the structure drawn.

A complex ion is formed from one Fe*, two CN and four NO, ions. (a) What is the structural formula and name of the complex ion? (b) Identify the type of isomerism and draw the isomer structures exhibited by the complex ion. (c) Draw the molecular orbital diagram and calculate the CFSE for the complex ion.

A coordination compound has the following composition (by mass %): 23.53% Co; 42.47% Cl, and 34.00% NH3. When 4.91 g of the compound is dissolved in 75.0 mL of deionized water, and the solution is reacted with an excess of AGNO; solution, it yields 5.60 g of AgCl precipitate. (a) Determine the empirical formula of the compound and write in the form of Co(NH;),Cl, (where x and 24. y are simple integers), and calculate its molar mass. (Assume the compound contains only one Co atom). (b) Deduce the number of chloride (Cl) as counter ions and as ligand, respectively. (c) Write the Werner's formula of the compound and give its systematic name. (Answers: (a) Co(NH3);C13; molar mass = 250.43 g/mol; (b) 2 Cl are counter ions and one is ligand; (c) [Co(NH3);CI]Cl2 = pentaammonechlorocobalt(III) chloride)

Answer 2

Question

Chapter 21, Problem 21.84SP

Interpretation Introduction

(a)

Interpretation:

The formula and the name of the given structures needs to be determined.

Concept introduction:

The set of the chemical symbols and the elements is known as the chemical formula of any compound. In any compound, they are present in their relative proportion.

Interpretation Introduction

(b)

Interpretation:

The linkage isomer structures needs to be determined.

Concept introduction:

The linkage isomer is defined as the coordination compounds that have the different connectivity of metal with the ligand.

Interpretation Introduction

(c)

Interpretation:

The ionization isomer structures needs to be determined.

Concept introduction:

The ionization isomer can be defined as the coordination compound that has a difference in anion and bonded to the metal.

Expert Solution & Answer

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Answer 3

Question

Chapter 21, Problem 21.84SP

Interpretation Introduction

(a)

Interpretation:

The formula and the name of the given structures needs to be determined.

Concept introduction:

The set of the chemical symbols and the elements is known as the chemical formula of any compound. In any compound, they are present in their relative proportion.

Interpretation Introduction

(b)

Interpretation:

The linkage isomer structures needs to be determined.

Concept introduction:

The linkage isomer is defined as the coordination compounds that have the different connectivity of metal with the ligand.

Interpretation Introduction

(c)

Interpretation:

The ionization isomer structures needs to be determined.

Concept introduction:

The ionization isomer can be defined as the coordination compound that has a difference in anion and bonded to the metal.

Expert Solution & Answer

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Answer 4

Question

Chapter 21, Problem 21.84SP

Interpretation Introduction

(a)

Interpretation:

The formula and the name of the given structures needs to be determined.

Concept introduction:

The set of the chemical symbols and the elements is known as the chemical formula of any compound. In any compound, they are present in their relative proportion.

Interpretation Introduction

(b)

Interpretation:

The linkage isomer structures needs to be determined.

Concept introduction:

The linkage isomer is defined as the coordination compounds that have the different connectivity of metal with the ligand.

Interpretation Introduction

(c)

Interpretation:

The ionization isomer structures needs to be determined.

Concept introduction:

The ionization isomer can be defined as the coordination compound that has a difference in anion and bonded to the metal.

Expert Solution & Answer

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Answer 5

Chapter 21, Problem 21.84SP

Interpretation Introduction

(a)

Interpretation:

The formula and the name of the given structures needs to be determined.

Concept introduction:

The set of the chemical symbols and the elements is known as the chemical formula of any compound. In any compound, they are present in their relative proportion.

Interpretation Introduction

(b)

Interpretation:

The linkage isomer structures needs to be determined.

Concept introduction:

The linkage isomer is defined as the coordination compounds that have the different connectivity of metal with the ligand.

Interpretation Introduction

(c)

Interpretation:

The ionization isomer structures needs to be determined.

Concept introduction:

The ionization isomer can be defined as the coordination compound that has a difference in anion and bonded to the metal.

Answer 6

Chapter 21, Problem 21.84SP

Interpretation Introduction

(a)

Interpretation:

The formula and the name of the given structures needs to be determined.

Concept introduction:

The set of the chemical symbols and the elements is known as the chemical formula of any compound. In any compound, they are present in their relative proportion.

Answer 7

Chapter 21, Problem 21.84SP

Interpretation Introduction

(a)

Interpretation:

The formula and the name of the given structures needs to be determined.

Concept introduction:

The set of the chemical symbols and the elements is known as the chemical formula of any compound. In any compound, they are present in their relative proportion.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The linkage isomer structures needs to be determined.

Concept introduction:

The linkage isomer is defined as the coordination compounds that have the different connectivity of metal with the ligand.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The linkage isomer structures needs to be determined.

Concept introduction:

The linkage isomer is defined as the coordination compounds that have the different connectivity of metal with the ligand.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The ionization isomer structures needs to be determined.

Concept introduction:

The ionization isomer can be defined as the coordination compound that has a difference in anion and bonded to the metal.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The ionization isomer structures needs to be determined.

Concept introduction:

The ionization isomer can be defined as the coordination compound that has a difference in anion and bonded to the metal.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2A Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4A Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6A Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8A Ch. 21 - Which of the following [Pt( H 2O)2Cl3Br]...Ch. 21 - Prob. 21.10A

(a) Interpretation: The formula and the name of the given structures needs to be determined. Concept introduction: The set of the chemical symbols and the elements is known as the chemical formula of any compound. In any compound, they are present in their relative proportion.

Solution Summary: The author explains the chemical formula and the name of the given structures. The central atom Ru has +2 oxidation states.

Concept explainers

Videos

(a)

Interpretation:

The formula and the name of the given structures needs to be determined.

Concept introduction:

The set of the chemical symbols and the elements is known as the chemical formula of any compound. In any compound, they are present in their relative proportion.

(b)

Interpretation:

The linkage isomer structures needs to be determined.

Concept introduction:

The linkage isomer is defined as the coordination compounds that have the different connectivity of metal with the ligand.

(c)

Interpretation:

The ionization isomer structures needs to be determined.

Concept introduction:

The ionization isomer can be defined as the coordination compound that has a difference in anion and bonded to the metal.

Want to see the full answer?

Chapter 21 Solutions

(a) Interpretation: The formula and the name of the given structures needs to be determined. Concept introduction: The set of the chemical symbols and the elements is known as the chemical formula of any compound. In any compound, they are present in their relative proportion.

Solution Summary: The author explains the chemical formula and the name of the given structures. The central atom Ru has +2 oxidation states.

Concept explainers

Videos

(a) Interpretation: The formula and the name of the given structures needs to be determined. Concept introduction: The set of the chemical symbols and the elements is known as the chemical formula of any compound. In any compound, they are present in their relative proportion.

(b) Interpretation: The linkage isomer structures needs to be determined. Concept introduction: The linkage isomer is defined as the coordination compounds that have the different connectivity of metal with the ligand.

(c) Interpretation: The ionization isomer structures needs to be determined. Concept introduction: The ionization isomer can be defined as the coordination compound that has a difference in anion and bonded to the metal.

Want to see the full answer?

Chapter 21 Solutions

(a)

Interpretation:

The formula and the name of the given structures needs to be determined.

Concept introduction:

The set of the chemical symbols and the elements is known as the chemical formula of any compound. In any compound, they are present in their relative proportion.

(b)

Interpretation:

The linkage isomer structures needs to be determined.

Concept introduction:

The linkage isomer is defined as the coordination compounds that have the different connectivity of metal with the ligand.

(c)

Interpretation:

The ionization isomer structures needs to be determined.

Concept introduction:

The ionization isomer can be defined as the coordination compound that has a difference in anion and bonded to the metal.