(a) Interpretation: The oxidation state and the identity of M in the complexes should be determined. Concept introduction: When considering transition metals , some has partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

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Answer 1

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Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 21, Problem 21.128SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state and the identity of M in the complexes should be determined.

Concept introduction:

When considering transition metals, some has partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Interpretation Introduction

(b)

Interpretation:

The valence bond orbital diagram for possible ions needs to be drawn.

Concept introduction:

According to the valence bond theory, there is an electrons pair of opposite spin which are shared by two atoms as a result of orbital overlap. Here, a coordination complex is occurred as a result of overlapping of filled ligand orbital with pair of electrons and empty hybrid orbital of the metal.

Interpretation Introduction

(c)

Interpretation:

The complex which is more likely to exist should be determined.

Concept introduction:

Transition metals show different oxidation states. When considering a transition metal ion, it is more likely to exit their most stable oxidation state.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?

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Answer 2

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 21, Problem 21.128SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state and the identity of M in the complexes should be determined.

Concept introduction:

When considering transition metals, some has partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Interpretation Introduction

(b)

Interpretation:

The valence bond orbital diagram for possible ions needs to be drawn.

Concept introduction:

According to the valence bond theory, there is an electrons pair of opposite spin which are shared by two atoms as a result of orbital overlap. Here, a coordination complex is occurred as a result of overlapping of filled ligand orbital with pair of electrons and empty hybrid orbital of the metal.

Interpretation Introduction

(c)

Interpretation:

The complex which is more likely to exist should be determined.

Concept introduction:

Transition metals show different oxidation states. When considering a transition metal ion, it is more likely to exit their most stable oxidation state.

Expert Solution & Answer

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Answer 3

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 21, Problem 21.128SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state and the identity of M in the complexes should be determined.

Concept introduction:

When considering transition metals, some has partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Interpretation Introduction

(b)

Interpretation:

The valence bond orbital diagram for possible ions needs to be drawn.

Concept introduction:

According to the valence bond theory, there is an electrons pair of opposite spin which are shared by two atoms as a result of orbital overlap. Here, a coordination complex is occurred as a result of overlapping of filled ligand orbital with pair of electrons and empty hybrid orbital of the metal.

Interpretation Introduction

(c)

Interpretation:

The complex which is more likely to exist should be determined.

Concept introduction:

Transition metals show different oxidation states. When considering a transition metal ion, it is more likely to exit their most stable oxidation state.

Expert Solution & Answer

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See solution

Answer 4

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 21, Problem 21.128SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state and the identity of M in the complexes should be determined.

Concept introduction:

When considering transition metals, some has partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Interpretation Introduction

(b)

Interpretation:

The valence bond orbital diagram for possible ions needs to be drawn.

Concept introduction:

According to the valence bond theory, there is an electrons pair of opposite spin which are shared by two atoms as a result of orbital overlap. Here, a coordination complex is occurred as a result of overlapping of filled ligand orbital with pair of electrons and empty hybrid orbital of the metal.

Interpretation Introduction

(c)

Interpretation:

The complex which is more likely to exist should be determined.

Concept introduction:

Transition metals show different oxidation states. When considering a transition metal ion, it is more likely to exit their most stable oxidation state.

Expert Solution & Answer

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Answer 5

Chapter 21, Problem 21.128SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state and the identity of M in the complexes should be determined.

Concept introduction:

When considering transition metals, some has partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Interpretation Introduction

(b)

Interpretation:

The valence bond orbital diagram for possible ions needs to be drawn.

Concept introduction:

According to the valence bond theory, there is an electrons pair of opposite spin which are shared by two atoms as a result of orbital overlap. Here, a coordination complex is occurred as a result of overlapping of filled ligand orbital with pair of electrons and empty hybrid orbital of the metal.

Interpretation Introduction

(c)

Interpretation:

The complex which is more likely to exist should be determined.

Concept introduction:

Transition metals show different oxidation states. When considering a transition metal ion, it is more likely to exit their most stable oxidation state.

Answer 6

Chapter 21, Problem 21.128SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state and the identity of M in the complexes should be determined.

Concept introduction:

When considering transition metals, some has partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Answer 7

Chapter 21, Problem 21.128SP

Interpretation Introduction

(a)

Interpretation:

The oxidation state and the identity of M in the complexes should be determined.

Concept introduction:

When considering transition metals, some has partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The valence bond orbital diagram for possible ions needs to be drawn.

Concept introduction:

According to the valence bond theory, there is an electrons pair of opposite spin which are shared by two atoms as a result of orbital overlap. Here, a coordination complex is occurred as a result of overlapping of filled ligand orbital with pair of electrons and empty hybrid orbital of the metal.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The valence bond orbital diagram for possible ions needs to be drawn.

Concept introduction:

According to the valence bond theory, there is an electrons pair of opposite spin which are shared by two atoms as a result of orbital overlap. Here, a coordination complex is occurred as a result of overlapping of filled ligand orbital with pair of electrons and empty hybrid orbital of the metal.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The complex which is more likely to exist should be determined.

Concept introduction:

Transition metals show different oxidation states. When considering a transition metal ion, it is more likely to exit their most stable oxidation state.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The complex which is more likely to exist should be determined.

Concept introduction:

Transition metals show different oxidation states. When considering a transition metal ion, it is more likely to exit their most stable oxidation state.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2A Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4A Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6A Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8A Ch. 21 - Which of the following [Pt( H 2O)2Cl3Br]...Ch. 21 - Prob. 21.10A

Solution Summary: The author explains that the oxidation state and the identity of M in the complexes should be determined.

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(c)

Interpretation:

The complex which is more likely to exist should be determined.

Concept introduction:

Transition metals show different oxidation states. When considering a transition metal ion, it is more likely to exit their most stable oxidation state.

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Chapter 21 Solutions

Solution Summary: The author explains that the oxidation state and the identity of M in the complexes should be determined.

Concept explainers

Videos

(c) Interpretation: The complex which is more likely to exist should be determined. Concept introduction: Transition metals show different oxidation states. When considering a transition metal ion, it is more likely to exit their most stable oxidation state.

Want to see the full answer?

Chapter 21 Solutions

(c)

Interpretation:

The complex which is more likely to exist should be determined.

Concept introduction:

Transition metals show different oxidation states. When considering a transition metal ion, it is more likely to exit their most stable oxidation state.