(a) Interpretation: The Lewis acid and Lewis base needs to be identified in the reaction of ethylenediamine with Ni 2 + which results in [ Ni(en) 3 ] 2 + . Concept introduction: The molecules which donate the electrons are known as Lewis bases while the molecules which accept the electrons are known as Lewis acids.

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Answer 1

Question

Chapter 21, Problem 21.74SP

Interpretation Introduction

(a)

Interpretation:

The Lewis acid and Lewis base needs to be identified in the reaction of ethylenediamine with Ni2+ which results in [Ni(en)3]2+.

Concept introduction:

The molecules which donate the electrons are known as Lewis bases while the molecules which accept the electrons are known as Lewis acids.

Interpretation Introduction

(b)

Interpretation:

The ligands and donor atoms are to be identified.

Concept introduction:

Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.

Interpretation Introduction

(c)

Interpretation:

The coordination number and geometry of the metal present in the complex are to be determined.

Concept introduction:

The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.

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In acidic aqueous solution, the purple complex ion Co(NH3)5Br2+ undergoes a slow reaction in which the bromide ion is replaced by a water molecule, yielding the pinkish-orange complex ion : Co(NH3)5(H2O)3+ Co(NH3)5Br2+Purple(aq)+H2O(l) → Co(NH3)5(H2O)3+Pinkish−orange(aq)+Br−(aq)The reaction is first order in Co(NH3)5Br2+, the rate constant at 25 ∘C is 6.3×10−6 s−1, and the initial concentration of Co(NH3)5Br2+ is 0.100 MM. What is its molarity after a reaction time of 19.0 h ? How many hours are required for 85 %% of the Co(NH3)5Br2+ to react?

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Answer 2

Question

Chapter 21, Problem 21.74SP

Interpretation Introduction

(a)

Interpretation:

The Lewis acid and Lewis base needs to be identified in the reaction of ethylenediamine with Ni2+ which results in [Ni(en)3]2+.

Concept introduction:

The molecules which donate the electrons are known as Lewis bases while the molecules which accept the electrons are known as Lewis acids.

Interpretation Introduction

(b)

Interpretation:

The ligands and donor atoms are to be identified.

Concept introduction:

Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.

Interpretation Introduction

(c)

Interpretation:

The coordination number and geometry of the metal present in the complex are to be determined.

Concept introduction:

The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.

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Answer 3

Question

Chapter 21, Problem 21.74SP

Interpretation Introduction

(a)

Interpretation:

The Lewis acid and Lewis base needs to be identified in the reaction of ethylenediamine with Ni2+ which results in [Ni(en)3]2+.

Concept introduction:

The molecules which donate the electrons are known as Lewis bases while the molecules which accept the electrons are known as Lewis acids.

Interpretation Introduction

(b)

Interpretation:

The ligands and donor atoms are to be identified.

Concept introduction:

Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.

Interpretation Introduction

(c)

Interpretation:

The coordination number and geometry of the metal present in the complex are to be determined.

Concept introduction:

The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.

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Answer 4

Question

Chapter 21, Problem 21.74SP

Interpretation Introduction

(a)

Interpretation:

The Lewis acid and Lewis base needs to be identified in the reaction of ethylenediamine with Ni2+ which results in [Ni(en)3]2+.

Concept introduction:

The molecules which donate the electrons are known as Lewis bases while the molecules which accept the electrons are known as Lewis acids.

Interpretation Introduction

(b)

Interpretation:

The ligands and donor atoms are to be identified.

Concept introduction:

Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.

Interpretation Introduction

(c)

Interpretation:

The coordination number and geometry of the metal present in the complex are to be determined.

Concept introduction:

The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.

Expert Solution & Answer

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Answer 5

Chapter 21, Problem 21.74SP

Interpretation Introduction

(a)

Interpretation:

The Lewis acid and Lewis base needs to be identified in the reaction of ethylenediamine with Ni2+ which results in [Ni(en)3]2+.

Concept introduction:

The molecules which donate the electrons are known as Lewis bases while the molecules which accept the electrons are known as Lewis acids.

Interpretation Introduction

(b)

Interpretation:

The ligands and donor atoms are to be identified.

Concept introduction:

Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.

Interpretation Introduction

(c)

Interpretation:

The coordination number and geometry of the metal present in the complex are to be determined.

Concept introduction:

The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.

Answer 6

Chapter 21, Problem 21.74SP

Interpretation Introduction

(a)

Interpretation:

The Lewis acid and Lewis base needs to be identified in the reaction of ethylenediamine with Ni2+ which results in [Ni(en)3]2+.

Concept introduction:

The molecules which donate the electrons are known as Lewis bases while the molecules which accept the electrons are known as Lewis acids.

Answer 7

Chapter 21, Problem 21.74SP

Interpretation Introduction

(a)

Interpretation:

The Lewis acid and Lewis base needs to be identified in the reaction of ethylenediamine with Ni2+ which results in [Ni(en)3]2+.

Concept introduction:

The molecules which donate the electrons are known as Lewis bases while the molecules which accept the electrons are known as Lewis acids.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The ligands and donor atoms are to be identified.

Concept introduction:

Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The ligands and donor atoms are to be identified.

Concept introduction:

Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The coordination number and geometry of the metal present in the complex are to be determined.

Concept introduction:

The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The coordination number and geometry of the metal present in the complex are to be determined.

Concept introduction:

The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2A Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4A Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6A Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8A Ch. 21 - Which of the following [Pt( H 2O)2Cl3Br]...Ch. 21 - Prob. 21.10A

Solution Summary: The author explains that the Lewis acid and Lewis base are to be identified in the reaction of ethylenediamine with Ni2+

Concept explainers

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(b)

Interpretation:

The ligands and donor atoms are to be identified.

Concept introduction:

Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.

(c)

Interpretation:

The coordination number and geometry of the metal present in the complex are to be determined.

Concept introduction:

The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.

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Chapter 21 Solutions

Solution Summary: The author explains that the Lewis acid and Lewis base are to be identified in the reaction of ethylenediamine with Ni2+

Concept explainers

Videos

(b) Interpretation: The ligands and donor atoms are to be identified. Concept introduction: Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.

(c) Interpretation: The coordination number and geometry of the metal present in the complex are to be determined. Concept introduction: The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.

Want to see the full answer?

Chapter 21 Solutions

(b)

Interpretation:

The ligands and donor atoms are to be identified.

Concept introduction:

Ligand can be defined as the ion and molecule which have the tendency to donate the electrons to the central atom or ion.

(c)

Interpretation:

The coordination number and geometry of the metal present in the complex are to be determined.

Concept introduction:

The coordination number can be defined as the number of ligands attached to the central atom by coordinate bonds.