Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Textbook Question
Chapter 18.11, Problem 12P
Correct the following incorrect names:
a. 2,4,6-tribromobenzene
b. 3-hydroxynitrobenzene
c. para-methylbromobenzene
d. 1,6-dichlorobenzene
e. meta-bromotoluene
f. 6-ethyl-4-iodoaniline
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Correct the following incorrect names:
a. 2,4,6-tribromobenzene b. 3-hydroxynitrobenzene
c. para-methylbromobenzene d. 1,6-dichlorobenzene
e. meta-bromotoluene f. 6-ethyl-4-iodoaniline
A student mistakenly names a compound "3-ethylbutane." What should this compound correctly be called?
Answer choices:
A. 2-ethylbutane
B. Hexane
C. 3-methylpentane
D. 2-methylpentane
Draw skeletal structures for the following: a. 5-ethyl-2-methyloctane
b. 1,3-dimethylcyclohexane
c. 2,3,3,4-tetramethylheptane
d. propylcyclopentane
e. 2-methyl-4-(1-methylethyl)octane
f. 2,6-dimethyl-4-(2-methylpropyl)decane
Chapter 18 Solutions
Organic Chemistry (8th Edition)
Ch. 18.1 - Draw the structure for each of the following: a....Ch. 18.3 - Why does hydration inactivate FeBr3?Ch. 18.6 - Prob. 4PCh. 18.7 - What is the major product of a Friedel-Crafts...Ch. 18.9 - Describe two ways to prepare each of the following...Ch. 18.10 - Prob. 7PCh. 18.11 - Name the following:Ch. 18.11 - Draw a structure for each of the following: a....Ch. 18.11 - Draw the structure for each of the following: a....Ch. 18.11 - Correct the following incorrect names: a....
Ch. 18.12 - Prob. 14PCh. 18.12 - List the compounds in each set from most reactive...Ch. 18.13 - Prob. 16PCh. 18.13 - What product(s) result from nitration of each of...Ch. 18.13 - Prob. 18PCh. 18.13 - What products are obtained from the reaction of...Ch. 18.15 - Give the products, if any, of each of the...Ch. 18.16 - a. Does a coupling reaction have to be used to...Ch. 18.16 - Show how the following compounds can be...Ch. 18.16 - Prob. 24PCh. 18.17 - What is the major product(s) of each of the...Ch. 18.17 - Prob. 26PCh. 18.18 - Why isn't FeBr3 used as a catalyst in the first...Ch. 18.18 - Prob. 29PCh. 18.18 - Write the sequence of steps required for the...Ch. 18.18 - Show how the following compounds can be...Ch. 18.19 - What product is formed from reaction of...Ch. 18.19 - Prob. 33PCh. 18.19 - Draw the structure of the activated ring and the...Ch. 18.20 - Prob. 35PCh. 18.20 - Prob. 36PCh. 18.20 - Diazomethane can be used to convert a carboxylic...Ch. 18.21 - Prob. 38PCh. 18.21 - Prob. 39PCh. 18.21 - Prob. 40PCh. 18.22 - Prob. 41PCh. 18 - Draw the structure for each of the following: a....Ch. 18 - Name the following:Ch. 18 - Prob. 44PCh. 18 - Prob. 45PCh. 18 - For each of the statements in Column I, choose a...Ch. 18 - What product is obtained from the reaction of...Ch. 18 - Draw the product(s) of each of the following...Ch. 18 - Rank the following substituted anilines from most...Ch. 18 - Prob. 50PCh. 18 - Prob. 51PCh. 18 - Show how the following compounds can be...Ch. 18 - Prob. 53PCh. 18 - The compound with the 1H NMR spectrum shown below...Ch. 18 - Rank each group of compounds from most reactive to...Ch. 18 - Prob. 56PCh. 18 - Prob. 57PCh. 18 - For each of the following components, indicate the...Ch. 18 - Prob. 59PCh. 18 - Prob. 60PCh. 18 - Describe two ways to prepare anisole from benzene.Ch. 18 - Prob. 62PCh. 18 - The following tertiary alkyl bromides undergo an...Ch. 18 - An aromatic hydrocarbon with a molecular formula...Ch. 18 - Show how the following compounds can be...Ch. 18 - Use the four compounds shown below to answer the...Ch. 18 - a. Rank the following esters from most reactive to...Ch. 18 - A mixture of 0.10 mol benzene and 0.10 mol...Ch. 18 - Prob. 69PCh. 18 - Prob. 70PCh. 18 - Benzene underwent a Friedel-Crafts acylation...Ch. 18 - Prob. 72PCh. 18 - Prob. 73PCh. 18 - Friedel-Crafts alkylations can be carried out with...Ch. 18 - Show how the following compounds can be prepared...Ch. 18 - Prob. 76PCh. 18 - Prob. 77PCh. 18 - a. Describe four ways the following reaction can...Ch. 18 - Propose a mechanism for each of the following...Ch. 18 - How can you prepare the following compounds with...Ch. 18 - Describe how naphthalene can he prepared from the...Ch. 18 - Using resonance contributors for the carbocation...Ch. 18 - Prob. 83PCh. 18 - What reagents are required to carry out the...Ch. 18 - Prob. 85PCh. 18 - Prob. 86PCh. 18 - Prob. 87PCh. 18 - Propose a mechanism for each of the following...Ch. 18 - P-Fluoronitrobenzene is more reactive toward...Ch. 18 - When heated with chromic acid, compound A forms...Ch. 18 - Show how the following compounds can be prepared...Ch. 18 - How can you distinguish the following compounds...Ch. 18 - Describe how mescaline can be synthesized from...Ch. 18 - Propose a mechanism for the following reaction...Ch. 18 - Propose a mechanism for each of the following...Ch. 18 - Describe how 3-methyl-1-phenyl-3-pentanol can he...Ch. 18 - An unknown compound reacts with ethyl chloride and...Ch. 18 - a. Explain why the following reaction leads to the...Ch. 18 - Explain why hydroxide ion catalyzes the reaction...Ch. 18 - Prob. 100PCh. 18 - Prob. 101PCh. 18 - a. How can aspirin be synthesized from benzene? b....Ch. 18 - Prob. 103PCh. 18 - Show how Novocain, a painkiller used frequently by...Ch. 18 - Prob. 105PCh. 18 - Saccharin, an artificial sweetener, is about 300...
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- Name the following: A. n-heptane B. 2-methyl-2-ethylbutane C. 3,3-dimethylpentane D. 2,2-diethylpropane E. none of thesearrow_forwardAre the following names correct or incorrect? If they areincorrect, give the correct name.a. 1,3-Dimethylpentane c. 3-Butylbutaneb. 2-Ethylpropane d. 3-Ethyl-4-methyloctanearrow_forward62. Draw condensed structural formulas for the following compounds. Use line structures for rings. a. 1,4-diethylcyclohexene b. 2,4-dimethyl-1-octene c. 2,2-dimethyl-3-hexynearrow_forward
- which of the following is an isomer of 2- methylpropane? W. 1-propene X. n-propane Y. 1-propyne Z. n-butanearrow_forwardA student was given the structural formulas of several compounds and was asked to give them systematic names. How many did she name correctly? Correct those that are misnamed. a. 4-ethyl-2-pentyne b. 2-methyl-3-hexyne c. 4-chloro-2-pentyne d. 2,3-dimethyl-5-octyne e. 4-heptynearrow_forwardIn lecture, the professor named a molecule 4-ethylpentane. An alert student pointed out that although the correct structure could be drawn, the name did not follow systematic rules. What is the correct systematic name for the molecule? a. 2-ethylpentane b. 1-methyl-1-propylpropane c. 3-methylhexane d. 4-methylhexane e. none of thesearrow_forward
- Write the condensed structural formula for the following organic compound. a. 3 methyl hexane b. 1, 2, 3 tri Flouro cyclohexene. c. 1,3,5 tricholoro cyclo hexane d. 3 ethyl-1-butyne e 2 ethyl - 1 - butenearrow_forwardDraw the condensed formula of each of the following compounds:a. 1-Bromo-2-chlorohexane c. 1,3,5-Trichloroheptane e. 1,2-Dibromo-3-chlorobutaneb. 2,3-Dimethylpentane d. 3-Chloro-5-iodo-4-methyloctane f. Trifluorochloromethanearrow_forward10. The following structures have incorrect names. Give the correct names. a. 2-methyl-3-propanal b. 4-hexanonearrow_forward
- A student was given the structural formulas of several compounds and was asked to give them systematic names. How many did she name correctly? Correct those that are misnamed. a. 4-ethyl-2-pentyne b. 1-bromo-4-heptyne c. 2-methyl-3-hexyne d. 3-pentynearrow_forwardA student was given the structural formulas of several compounds and was asked to give them systematic names. How many did the student name correctly? Correct those that are misnamed. a. 4-bromo-3-pentanol b. 2,2-dimethyl-4-ethylheptane c. 5-methylcyclohexanol d. 1,1-dimethyl-2-cyclohexanol e. 5-(2,2-dimethylethyl)nonane f. isopentylbromide g. 3,3-dichlorooctane h. 5-ethyl-2-methylhexane i. 1-bromo-4-pentanol j. 3-isopropyloctane k. 2-methyl-2-isopropylheptane l. 2-methyl-N,N-dimethyl-4-hexanaminearrow_forwardWhat is the name of the product of this reaction? a. 2-bromohexane b. 3,3-dibromohexane c. 3,4-dibromohexene d. 1,1-dibromobutane e. 3,4-dibromohexanearrow_forward
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