Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 17, Problem 24P
Interpretation Introduction

Interpretation:

The products formed when ethyl propanoate reacts with the given compounds are to be identified.

Concept introduction:

Carboxylic salts are derived from their acids. These organic salts have the OH ion replaced with any other organic or inorganic cation.

In this type of salts, the name of the cation precedes the carboxylic anion.

When ethyl propanoate reacts with LiAlH4 and H2O, it forms propyl alcohol and ethanol.

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Methyllithium (CH3Li) is often used as a base in organic reactions. Predict the products of the following acid-base reaction.CH3CH2¬OH + CH3¬Li ¡
NaH HO HO PBR3 A (a) Name the functional groups in compounds A and B, including, if relevant, whether they are primary (1°), secondary (2°) or tertiary (3'). (b) Propose a reagent that could be used to convert A into B. (c) Draw the structure of the intermediate C formed by reaction of compound A with NaH. (d) Propose the structure of the organic compound D formed by reaction with PB.3. (e) Could HBr be used for the conversion of A into D? Explain very briefly.
What is the major product of the reaction below? (A) O A O O O U OH (B) 1) excess LiAlH4 2) H₂O HO (C) ? OH е он (D)

Chapter 17 Solutions

Organic Chemistry

Ch. 17 - Prob. 11PPCh. 17 - Practice Problem 17.12 What products would you...Ch. 17 - Practice Problem 17.13 (a) Provide the reagents...Ch. 17 - Prob. 14PPCh. 17 - Practice Problem 17.15 Using decarboxylation...Ch. 17 - Practice Problem 17.16 Diacyl peroxides, ,...Ch. 17 - Prob. 17PCh. 17 - Give an IUPAC systematic or common name for each...Ch. 17 - Prob. 19PCh. 17 - Prob. 20PCh. 17 - 17.21 What major organic product would you expect...Ch. 17 - Prob. 22PCh. 17 - Prob. 23PCh. 17 - Prob. 24PCh. 17 - Prob. 25PCh. 17 - 17.26 What products would you expect to obtain...Ch. 17 - Write structural formulas for the major organic...Ch. 17 - 17.28 Indicate reagents that would accomplish each...Ch. 17 - Write structural formulas for the major organic...Ch. 17 - Prob. 30PCh. 17 - Prob. 31PCh. 17 - Prob. 32PCh. 17 - 17.33 On heating,...Ch. 17 - Prob. 34PCh. 17 - Prob. 35PCh. 17 - 17.36 Show how pentanoic acid can be prepared from...Ch. 17 - 17.37 The active ingredient of the insect...Ch. 17 - Prob. 38PCh. 17 - Prob. 39PCh. 17 - Give stereochemical formulas for compounds AQ:...Ch. 17 - 17.41 -Glyceraldehyde can be transformed into...Ch. 17 - Prob. 42PCh. 17 - Prob. 43PCh. 17 - 17.44 Given here are the NMR spectra and carbonyl...Ch. 17 - 17.45 Compound Y dissolves slowly when warmed...Ch. 17 - Prob. 46PCh. 17 - Prob. 47PCh. 17 - Prob. 48PCh. 17 - Prob. 49PCh. 17 - Prob. 50PCh. 17 - Prob. 51PCh. 17 - 17.52 Starting with 1-naphthol, suggest an...Ch. 17 - Suggest a synthesis of ibuprofen (Section 5.11)...Ch. 17 - Prob. 54PCh. 17 - Prob. 55PCh. 17 - Prob. 1LGPCh. 17 - Prob. 2LGPCh. 17 - Prob. 3LGPCh. 17 - Prob. 4LGP
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