Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Question
Chapter 17, Problem 17.39E
Interpretation Introduction
Interpretation:
The validation of the statement that on breaking down all the units of all the quantities in equation 17.53 into their basic units, all the units are cancelled out is to be stated.
Concept introduction:
Partition function is defined as the functions of the
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Chapter 17 Solutions
Physical Chemistry
Ch. 17 - Prob. 17.1ECh. 17 - Prob. 17.2ECh. 17 - Prob. 17.3ECh. 17 - Prob. 17.4ECh. 17 - Prob. 17.5ECh. 17 - Prob. 17.6ECh. 17 - Prob. 17.7ECh. 17 - Prob. 17.8ECh. 17 - Prob. 17.9ECh. 17 - Prob. 17.10E
Ch. 17 - Prob. 17.11ECh. 17 - If the ni values are all the same, a shorthand way...Ch. 17 - Prob. 17.13ECh. 17 - Prob. 17.14ECh. 17 - Prob. 17.15ECh. 17 - Prob. 17.16ECh. 17 - Prob. 17.17ECh. 17 - Prob. 17.18ECh. 17 - Prob. 17.19ECh. 17 - Prob. 17.20ECh. 17 - Prob. 17.21ECh. 17 - Prob. 17.22ECh. 17 - Explain why q is a constant for a given system at...Ch. 17 - What is the ratio of ground-state nickel atoms in...Ch. 17 - Ti3+ has the following electronic energy levels:...Ch. 17 - Using the fact that =1/kT, show that equations...Ch. 17 - A one-dimensional particle-in-a-box has a length...Ch. 17 - Prob. 17.28ECh. 17 - Prob. 17.29ECh. 17 - Prob. 17.30ECh. 17 - Prob. 17.31ECh. 17 - What is the value of q at absolute zero? Is it the...Ch. 17 - Prob. 17.33ECh. 17 - Prob. 17.34ECh. 17 - Prob. 17.35ECh. 17 - Prob. 17.36ECh. 17 - Prob. 17.37ECh. 17 - Prob. 17.38ECh. 17 - Prob. 17.39ECh. 17 - Prob. 17.40ECh. 17 - Prob. 17.41ECh. 17 - Prob. 17.42ECh. 17 - What change is there in the Sackur-Tetrode...Ch. 17 - Prob. 17.44ECh. 17 - Prob. 17.45ECh. 17 - Prob. 17.46ECh. 17 - Calculate the thermal de Broglie wavelength of He...Ch. 17 - Prob. 17.48ECh. 17 - Prob. 17.49ECh. 17 - Prob. 17.50ECh. 17 - Prob. 17.51ECh. 17 - Prob. 17.52ECh. 17 - Prob. 17.53ECh. 17 - Use equation 17.56 to determine the change in...Ch. 17 - For an electron that has a velocity of 0.01c where...Ch. 17 - Use the Sackur-Tetrode equation to derive the...Ch. 17 - Prob. 17.57ECh. 17 - Prob. 17.58E
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Similar questions
- Explain why q is a constant for a given system at a specified temperature.arrow_forward5.10. If and gases were contained in a system such that the total pressure were , then the terms in equation would be equal to . True or false? Explain your answer.arrow_forward6.21. What assumption is used in the integration of equation 6.11 to get equation 6.12?arrow_forward
- Explain why the spontaneity conditions given in the equation 4.3 and 4.4 are in terms of the general derivatives dU and dH and not some partial derivative of U and H with respect to some other state variable.arrow_forward8.3. Two small metallic bodies are given opposite charges, with the negatively charged body having twice the charge of the positively charged body. They are immersed in water (dielectric constant) at a distance of, and it is found that the force of attraction between the two metal pieces is . (a) What are the charges on the pieces of metal? (b) What are the electric fields of the two bodies?arrow_forwardIn Chapters 17 and 18 we have derived expressions for the absolute amounts of the energies H and G. However, in tables of thermodynamic data, we always tabulate H and G that is, changes in enthalpy and Gibbs energy. How do you explain this apparent discrepancy?arrow_forward
- Thermodynamic properties can also be determined for ions. Determine H,S,andG for the following two reactions, which are simply reactions of dissolution: NaHCO3(s)Na+(aq)+HCO3(aq)Na2CO3(s)2Na+(aq)+CO32(aq) Assume standard conditions standard concentration is 1M for ions in aqueous solution, and consult the table of thermodynamic properties in Appendix 2. What similarities and differences are there?arrow_forwardConsider a system similar to the one in Figure 16.8, except that it contains six particles instead of four. What is the probability of having all the particles in only one of the two boxes in the case? Compare this with the similar probability for the system of four particles that we have derived to be equal to 18 . What does this comparison tell us about even larger systems?arrow_forwardEquation 4.19 says that (UV)S=p If we are considering the variation of U, the change in the change of the internal energy, we can write that as see the previous problem for an analogous argument ((U)V)S=p Show that this is entirely consistent with the first law of thermodynamics.arrow_forward
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