Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Textbook Question
Chapter 17, Problem 17.32E
What is the value of
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Prove that these derivatives are indeed 0 for ideal gases:
Chapter 17 Solutions
Physical Chemistry
Ch. 17 - Prob. 17.1ECh. 17 - Prob. 17.2ECh. 17 - Prob. 17.3ECh. 17 - Prob. 17.4ECh. 17 - Prob. 17.5ECh. 17 - Prob. 17.6ECh. 17 - Prob. 17.7ECh. 17 - Prob. 17.8ECh. 17 - Prob. 17.9ECh. 17 - Prob. 17.10E
Ch. 17 - Prob. 17.11ECh. 17 - If the ni values are all the same, a shorthand way...Ch. 17 - Prob. 17.13ECh. 17 - Prob. 17.14ECh. 17 - Prob. 17.15ECh. 17 - Prob. 17.16ECh. 17 - Prob. 17.17ECh. 17 - Prob. 17.18ECh. 17 - Prob. 17.19ECh. 17 - Prob. 17.20ECh. 17 - Prob. 17.21ECh. 17 - Prob. 17.22ECh. 17 - Explain why q is a constant for a given system at...Ch. 17 - What is the ratio of ground-state nickel atoms in...Ch. 17 - Ti3+ has the following electronic energy levels:...Ch. 17 - Using the fact that =1/kT, show that equations...Ch. 17 - A one-dimensional particle-in-a-box has a length...Ch. 17 - Prob. 17.28ECh. 17 - Prob. 17.29ECh. 17 - Prob. 17.30ECh. 17 - Prob. 17.31ECh. 17 - What is the value of q at absolute zero? Is it the...Ch. 17 - Prob. 17.33ECh. 17 - Prob. 17.34ECh. 17 - Prob. 17.35ECh. 17 - Prob. 17.36ECh. 17 - Prob. 17.37ECh. 17 - Prob. 17.38ECh. 17 - Prob. 17.39ECh. 17 - Prob. 17.40ECh. 17 - Prob. 17.41ECh. 17 - Prob. 17.42ECh. 17 - What change is there in the Sackur-Tetrode...Ch. 17 - Prob. 17.44ECh. 17 - Prob. 17.45ECh. 17 - Prob. 17.46ECh. 17 - Calculate the thermal de Broglie wavelength of He...Ch. 17 - Prob. 17.48ECh. 17 - Prob. 17.49ECh. 17 - Prob. 17.50ECh. 17 - Prob. 17.51ECh. 17 - Prob. 17.52ECh. 17 - Prob. 17.53ECh. 17 - Use equation 17.56 to determine the change in...Ch. 17 - For an electron that has a velocity of 0.01c where...Ch. 17 - Use the Sackur-Tetrode equation to derive the...Ch. 17 - Prob. 17.57ECh. 17 - Prob. 17.58E
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- Explain why q is a constant for a given system at a specified temperature.arrow_forwardDerive the fact that HpT is also zero for an ideal gas.arrow_forwardAsampleof a monatomic ideal gas doubles itsvolume reversibly and adiabatically. By what percentage does its absolute temperature change?arrow_forward
- Evaluate (U/V)T for an ideal gas. Use the expression from Example 4.11. Does your answer make sense?arrow_forwardUnder what conditions will U be exactly zero for a process whose initial conditions are not thesame as its final conditions?arrow_forwardWhich of the following functions are exact differentials? a dF=1xdx+1ydy b dF=1ydx+1xdy c dF=2x2y2dx+3x3y3dy d dF=2x2y3dx+2x3y2dy e dF=xndx+yndy,n= any integer f dF=(x3cosy)dx+(x3siny)dyarrow_forward
- Use the data in Table 2.2 to determine Hp T for Ar at 0C and 1atm. Make any reasonable assumptions necessary.arrow_forwardIn the equation w = P V, why is there a negative sign?arrow_forwardUse the data in Table 2.2 to determine PH T for N2 at 50C and 20atm. Make any reasonable assumptions necessary.arrow_forward
- Consider a system similar to the one in Figure 16.8, except that it contains six particles instead of four. What is the probability of having all the particles in only one of the two boxes in the case? Compare this with the similar probability for the system of four particles that we have derived to be equal to 18 . What does this comparison tell us about even larger systems?arrow_forwardHow much work is done in blowing up a balloon from zero volume to a volume of 2.2 L, assuming that p = 1.00 bar and no work is required to stretch the rubber? (In reality, the work that goes into stretching the rubber is substantial.) iarrow_forward1) Calculate the TOTOX value of Condition 1 and Condition 2 and based on the answer, which condition shows better quality oil? Justify your answer.arrow_forward
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