Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
expand_more
expand_more
format_list_bulleted
Question
Chapter 17, Problem 17.15E
Interpretation Introduction
Interpretation:
The different distinguishable distributions for total system energy of
Concept introduction:
The thermodynamic state of a large microscopic system is understood using the statistical
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
18. Which of the following is the definition of internal energy of
a system?
a.it is the sum of the kinetic energy of all of its components
b.it is the sum of the rotational, vibrational, and translational
energies of all of its components
c.lt refers only to the energies of the nuclei of the atoms of the
component molecules
d.It is the sum of the potential and kinetic energies of the
components
What is the signifi-cance of entropy being a state function?
Consider an ideal monatomic gas consisting of N atoms. Initially, it is contained in a volume of V. Then, it is allowed to expand isothermally to a volume of 2V. Find the change (a) in entropy, ( b) in Helmholtz energy, (c) in Gibbs free energy.
Chapter 17 Solutions
Physical Chemistry
Ch. 17 - Prob. 17.1ECh. 17 - Prob. 17.2ECh. 17 - Prob. 17.3ECh. 17 - Prob. 17.4ECh. 17 - Prob. 17.5ECh. 17 - Prob. 17.6ECh. 17 - Prob. 17.7ECh. 17 - Prob. 17.8ECh. 17 - Prob. 17.9ECh. 17 - Prob. 17.10E
Ch. 17 - Prob. 17.11ECh. 17 - If the ni values are all the same, a shorthand way...Ch. 17 - Prob. 17.13ECh. 17 - Prob. 17.14ECh. 17 - Prob. 17.15ECh. 17 - Prob. 17.16ECh. 17 - Prob. 17.17ECh. 17 - Prob. 17.18ECh. 17 - Prob. 17.19ECh. 17 - Prob. 17.20ECh. 17 - Prob. 17.21ECh. 17 - Prob. 17.22ECh. 17 - Explain why q is a constant for a given system at...Ch. 17 - What is the ratio of ground-state nickel atoms in...Ch. 17 - Ti3+ has the following electronic energy levels:...Ch. 17 - Using the fact that =1/kT, show that equations...Ch. 17 - A one-dimensional particle-in-a-box has a length...Ch. 17 - Prob. 17.28ECh. 17 - Prob. 17.29ECh. 17 - Prob. 17.30ECh. 17 - Prob. 17.31ECh. 17 - What is the value of q at absolute zero? Is it the...Ch. 17 - Prob. 17.33ECh. 17 - Prob. 17.34ECh. 17 - Prob. 17.35ECh. 17 - Prob. 17.36ECh. 17 - Prob. 17.37ECh. 17 - Prob. 17.38ECh. 17 - Prob. 17.39ECh. 17 - Prob. 17.40ECh. 17 - Prob. 17.41ECh. 17 - Prob. 17.42ECh. 17 - What change is there in the Sackur-Tetrode...Ch. 17 - Prob. 17.44ECh. 17 - Prob. 17.45ECh. 17 - Prob. 17.46ECh. 17 - Calculate the thermal de Broglie wavelength of He...Ch. 17 - Prob. 17.48ECh. 17 - Prob. 17.49ECh. 17 - Prob. 17.50ECh. 17 - Prob. 17.51ECh. 17 - Prob. 17.52ECh. 17 - Prob. 17.53ECh. 17 - Use equation 17.56 to determine the change in...Ch. 17 - For an electron that has a velocity of 0.01c where...Ch. 17 - Use the Sackur-Tetrode equation to derive the...Ch. 17 - Prob. 17.57ECh. 17 - Prob. 17.58E
Knowledge Booster
Similar questions
- Under what conditions will U be exactly zero for a process whose initial conditions are not thesame as its final conditions?arrow_forwardConsider a system similar to the one in Figure 16.8, except that it contains six particles instead of four. What is the probability of having all the particles in only one of the two boxes in the case? Compare this with the similar probability for the system of four particles that we have derived to be equal to 18 . What does this comparison tell us about even larger systems?arrow_forwardExplain why q is a constant for a given system at a specified temperature.arrow_forward
- The molar heat capacities for carbon dioxide at 298.0 K are shown below. C₁ = 28.95 J K-¹ mol-1 C₂ = 37.27 J K-¹ mol-1 The molar entropy of carbon dioxide gas at 298.0 K and 1.000 atm is 213.64 J K-1 mol-1. (a) Calculate the energy required to change the temperature of 1.000 mole of carbon dioxide gas from 298.0 K to 340.0 K, both at constant volume and at constant pressure. constant volume kJ kJ constant pressure (b) Calculate the molar entropy of CO₂(g) at 340.0 K and 1.000 atm. JK-1 mol-1 (c) Calculate the molar entropy of CO₂(g) at 340.0 K and 1.201 atm. JK-¹ mol-1arrow_forwardA linear molecule may rotate about two axes. If the molecule consists of N atoms, then there are 3N- 5 vibrational modes. Use the equipartition theorem to estimate the total contribution to the molar internal energy from translation, vibration, and rotation for (a) carbon dioxide, CO2, and (b) dibromoethyne, C2Br2, at 2000 K. In contrast, a nonlinear molecule may rotate about three axes and has 3N- 6 vibrational modes. Estimate the total contribution to the molar in ternal energy from translation, vibration, and rotation for (c) nitrogen dioxide, NO2, and (d) tetrabromoethene, C2Br4,at 2000 K. In each case, first assume that all vibrations are active; then assume that none is.arrow_forwardShow that = Cp – P ƏT. What can be said about (), for an ideal gas and what does this expression represent?arrow_forward
arrow_back_ios
arrow_forward_ios
Recommended textbooks for you
Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,
Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage Learning
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning