Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 5, Problem 5.10E
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Suppose you have 1.25 moles of gaseous napthalene (C10H8) at T = 292 K. What is the average kinetic energy of one molecule of napthalene? (The molar mass of napthalene is 128 g/mol. You may assume that the gas molecules behave ideally.)
Consider a vessel with a moveable piston. The initial volume of this vessel is 15.0 L,
and inside the vessel is x moles of N2(g) and x moles of H2(g). The total pressure in
the vessel is 2.00 bar.
The reaction between N₂ and H₂ is initiated, and NH3 forms.
N2(g) + 3 H2(g) →→→ 2NH3(g)
If this reaction goes to completion, what will be the final volume of the vessel if
the total pressure remains at 2.00 bar?
5.0 L
10.0 L
15.0 L
20.0 L
(a) A rigid tank contains 1.60 moles of helium, which can be treated as an ideal gas, at a pressure of 28.0 atm. While the tank and gas maintain a constant volume and temperature, a number of moles are removed from the tank, reducing the pressure to 5.00 atm. How many moles are removed?
mol
(b) What If? In a separate experiment beginning from the same initial conditions, including a temperature T, of 25.0°C, half the number of moles found in part (a) are withdrawn while the temperature is allowed to vary and the pressure undergoes the same change from 28.0 atm to 5.00 atm. What is the final temperature (in °C) of the gas?
°C
Chapter 5 Solutions
Physical Chemistry
Ch. 5 - 5.1. Can a battery that has a voltage be...Ch. 5 - 5.2. What is the difference between a static...Ch. 5 - Which system in each pair best represents...Ch. 5 -
5.4. Supersaturated solutions can be made in...Ch. 5 -
5.5. Following is a chemical reaction between...Ch. 5 - 5.6. The following is a reaction with its initial...Ch. 5 - The following is a reaction with initial amounts...Ch. 5 - 5.8. The hemoglobin in blood establishes an...Ch. 5 - Prob. 5.9ECh. 5 - 5.10. If and gases were contained in a system...
Ch. 5 - 5.11. Determine the numerical value of Q for the...Ch. 5 - 5.12. True or false: If all the partial pressures...Ch. 5 - For the reaction 2SO3(g)2SO2(g)+O2(g) when 2mol of...Ch. 5 - 5.14. Determine and for the following reaction at...Ch. 5 - 5.15. Consider the reaction
If the partial...Ch. 5 -
5.16. In atmospheric chemistry, the following...Ch. 5 - Prob. 5.17ECh. 5 - 5.18. Hydrogen cyanide can isomerize to hydrogen...Ch. 5 - 5.19. Assume that a reaction exists such that...Ch. 5 - Prob. 5.20ECh. 5 - 5.21. Show that if the coefficients of a balanced...Ch. 5 - 5.22. True or false: If for a gas-phase reaction,...Ch. 5 - 5.23. The balanced chemical reaction for the...Ch. 5 - The answers in exercise 5.23 should show that...Ch. 5 - At a high enough temperature, the equilibrium...Ch. 5 - Prob. 5.26ECh. 5 - 5.27. Nitrogen dioxide,, dimerizes easily to form...Ch. 5 - 5.28. Another nitrogen-oxygen reaction of some...Ch. 5 - Prob. 5.29ECh. 5 - Prob. 5.30ECh. 5 - Prob. 5.31ECh. 5 - 5.32. For the reaction
. (a) Using in Appendix...Ch. 5 - 5.33. Use the data in Appendix to calculate ...Ch. 5 - 5.34. The of diamond, a crystalline form of...Ch. 5 - 5.35. The densities of graphite and diamond are ...Ch. 5 - Buckminsterfullerene, C60, is a spherical molecule...Ch. 5 - Prob. 5.37ECh. 5 - At what pressure does H2O have an activity of...Ch. 5 - The bisulfate or hydrogen sulfate anion, HSO4, is...Ch. 5 - Prob. 5.40ECh. 5 - Write the equilibrium constant expression for each...Ch. 5 - Prob. 5.42ECh. 5 - For the given chemical equilibrium, these data are...Ch. 5 - Biological standard states include specifying a...Ch. 5 - a At 25.0C, Kw for the autoionization of water is...Ch. 5 - 5.46. For a reaction whose standard enthalpy...Ch. 5 - 5.47. For the reaction
and . Estimate for this...Ch. 5 - 5.48. The isotope exchange reaction
has an...Ch. 5 - 5.49. Consider the following equilibrium:
What...Ch. 5 - 5.50. For the equilibrium
Equilibrium partial...Ch. 5 - The decomposition of NaHCO3, used in kitchens to...Ch. 5 - 5.52. For the equilibrium
at,. In a flask, of...Ch. 5 - Prob. 5.53ECh. 5 - 5.54. For the reaction
The equilibrium...Ch. 5 - Prob. 5.55ECh. 5 - 5.56. Of the amino acids listed in Table , which...Ch. 5 - 5.57. Determine the concentration of the three...Ch. 5 - 5.58. The formation of zwitterionic glycine, ,...Ch. 5 - 5.59. Monosodium glutamate, or MSG, is the sodium...Ch. 5 - Prob. 5.60ECh. 5 - Consider the balanced chemical reaction...Ch. 5 - For the gas-phase reaction 2H2+O22H2O rxnG is...Ch. 5 - Prob. 5.63ECh. 5 - Prob. 5.64E
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- At the critical point for carbon dioxide, the substance is very far from being an ideal gas. Prove this statement by calculating the density of an ideal gas in g/cm3 at the conditions of the critical point and comparing it with the experimental value. Compute the experimental value from the fact that a mole of CO2 at its critical point occupies 94 cm3.arrow_forwardWhich of the following quantities can be taken to be independent of temperature? independent of pressure? (a) H for a reaction (b) S for a reaction (c) G for a reaction (d) S for a substancearrow_forwardWhat properties of a nonideal gas do the Vander Waals constants represent?arrow_forward
- Aerosol cans carry clear warnings against incineration because of the high pressures that can develop upon heating. Suppose that a can contains a residual amount of gas at a pressure of 745 Torr and a temperature of 30 ∘C What would the pressure be if the can were heated to 1285 ∘C ? P2 = ?arrow_forwardHw.13.arrow_forward100.0 g of propyne (C3H4) (g) is burnt in a 30.0 L rigid vessel containing pure O2 (g) at P = 10.00 bar and an initial temperature of 25.0 °C. At the end of the reaction the temperature of the vessel is 250. °C. At the end of the reaction, what are the partial pressures (in bar) of CO2 (g) and O2 (g)?arrow_forward
- Given R= 8.31 J mol·' K-' mol', k= 1.38 x10-23 J K-', NA = 6.23 x 10²3 mol- 1. Calculate a) the mean translational kinetic energy of carbon dioxide molecule with a relative molecular mass of 44 at 20 °C [ans: 6.07×10-21 J] b) the mean translational kinetic energy of a molecule on an ideal gas at 10 °C? [ans: 5.86×10-21 J]arrow_forwardAt 100 kPa and 0 °C, a 5.04 L mixture of methane (CH4) and propane (C3H8) combusts, producing 18.0 g CO2 . Calculate the mole fraction of each gas in the initial mixture. Assume complete combustion.arrow_forwardThe ideal gas law describes the relationship among the volume of an ideal gas (V), its pressure (P), its absolute temperature (T), and number of moles ( n): PV = nRT Under standard conditions, the ideal gas law does a good job of approximating these properties for any gas. However, the ideal gas law does not account for all the properties of real gases such as intermolecular attraction and molecular volume, which become more pronounced at low temperatures and high pressures. The van der Waals equation corrects for these factors with the constants a and b, which are unique to each substance: (P+ ²) (V-nb) = nRT an² The gas constant R is equal to 0.08206 L.atm/(K-mol). Part A A 3.00-L flask is filled with gaseous ammonia, NH3. The gas pressure measured at 16.0 °C is 2.45 atm . Assuming ideal gas behavior, how many grams of ammonia are in the flask? Express your answer to three significant figures and include the appropriate units. View Available Hint(s) mass of NH3 = Submit ▾ Part B HÅ…arrow_forward
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