General, Organic, and Biological Chemistry
General, Organic, and Biological Chemistry
7th Edition
ISBN: 9781285853918
Author: H. Stephen Stoker
Publisher: Cengage Learning
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Diol
In chemistry there are so many chemical compounds that have a hydroxyl group but a chemical compound having two hydroxyl groups (-OH) is termed as a diol. It also implies the presence of two alcohols whereas polyols contain two or more than two hydroxyl …
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Chapter 15, Problem 15.71EP

(a)

Interpretation Introduction

Interpretation:

The structure of aldehyde or ketone that is formed from the given alcohol has to be drawn.

Concept Introduction:

Carbonyl compounds such as aldehydes and ketones can be synthesized by oxidation or reduction reaction.  When a primary alcohol undergoes oxidation reaction, the product obtained is carboxylic acid that is formed through the intermediate aldehyde.  When mild oxidizing agent is used, aldehyde can be obtained as product from primary alcohol.  When a secondary alcohol undergoes oxidation reaction, the product obtained is a ketone.  This cannot be further oxidized.  Tertiary alcohols do not undergo oxidation reaction.  Some of the mild oxidizing agents used are KMnO4 or K2Cr2O7.

(b)

Interpretation Introduction

Interpretation:

The structure of aldehyde or ketone that is formed from the given alcohol has to be drawn.

Concept Introduction:

Carbonyl compounds such as aldehydes and ketones can be synthesized by oxidation or reduction reaction.  When a primary alcohol undergoes oxidation reaction, the product obtained is carboxylic acid that is formed through the intermediate aldehyde.  When mild oxidizing agent is used, aldehyde can be obtained as product from primary alcohol.  When a secondary alcohol undergoes oxidation reaction, the product obtained is a ketone.  This cannot be further oxidized.  Tertiary alcohols do not undergo oxidation reaction.  Some of the mild oxidizing agents used are KMnO4 or K2Cr2O7.

(c)

Interpretation Introduction

Interpretation:

The structure of aldehyde or ketone that is formed from the given alcohol has to be drawn.

Concept Introduction:

Carbonyl compounds such as aldehydes and ketones can be synthesized by oxidation or reduction reaction.  When a primary alcohol undergoes oxidation reaction, the product obtained is carboxylic acid that is formed through the intermediate aldehyde.  When mild oxidizing agent is used, aldehyde can be obtained as product from primary alcohol.  When a secondary alcohol undergoes oxidation reaction, the product obtained is a ketone.  This cannot be further oxidized.  Tertiary alcohols do not undergo oxidation reaction.  Some of the mild oxidizing agents used are KMnO4 or K2Cr2O7.

(d)

Interpretation Introduction

Interpretation:

The structure of aldehyde or ketone that is formed from the given alcohol has to be drawn.

Concept Introduction:

Carbonyl compounds such as aldehydes and ketones can be synthesized by oxidation or reduction reaction.  When a primary alcohol undergoes oxidation reaction, the product obtained is carboxylic acid that is formed through the intermediate aldehyde.  When mild oxidizing agent is used, aldehyde can be obtained as product from primary alcohol.  When a secondary alcohol undergoes oxidation reaction, the product obtained is a ketone.  This cannot be further oxidized.  Tertiary alcohols do not undergo oxidation reaction.  Some of the mild oxidizing agents used are KMnO4 or K2Cr2O7.

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Chapter 15 Solutions

General, Organic, and Biological Chemistry

Ch. 15.1 - Prob. 1QQCh. 15.1 - Prob. 2QQCh. 15.2 - Prob. 1QQCh. 15.2 - Prob. 2QQCh. 15.2 - Prob. 3QQCh. 15.3 - Prob. 1QQCh. 15.3 - Prob. 2QQCh. 15.3 - Prob. 3QQCh. 15.4 - Prob. 1QQCh. 15.4 - Prob. 2QQ
Ch. 15.4 - Prob. 3QQCh. 15.4 - Prob. 4QQCh. 15.4 - Prob. 5QQCh. 15.5 - Prob. 1QQCh. 15.5 - Prob. 2QQCh. 15.5 - Prob. 3QQCh. 15.5 - Prob. 4QQCh. 15.5 - Prob. 5QQCh. 15.6 - Prob. 1QQCh. 15.6 - Prob. 2QQCh. 15.6 - Prob. 3QQCh. 15.7 - Prob. 1QQCh. 15.7 - Prob. 2QQCh. 15.8 - Prob. 1QQCh. 15.8 - Prob. 2QQCh. 15.9 - Prob. 1QQCh. 15.9 - Prob. 2QQCh. 15.10 - Prob. 1QQCh. 15.10 - Prob. 2QQCh. 15.10 - Prob. 3QQCh. 15.10 - Prob. 4QQCh. 15.11 - Prob. 1QQCh. 15.11 - Prob. 2QQCh. 15.11 - Prob. 3QQCh. 15.11 - Prob. 4QQCh. 15.11 - Prob. 5QQCh. 15.12 - Prob. 1QQCh. 15.12 - Prob. 2QQCh. 15 - Prob. 15.1EPCh. 15 - Prob. 15.2EPCh. 15 - Prob. 15.3EPCh. 15 - In terms of polarity, which carbonyl group atom...Ch. 15 - Prob. 15.5EPCh. 15 - What is the geometrical arrangement for the atoms...Ch. 15 - Prob. 15.7EPCh. 15 - Prob. 15.8EPCh. 15 - Prob. 15.9EPCh. 15 - Prob. 15.10EPCh. 15 - Prob. 15.11EPCh. 15 - Classify each of the following structures as an...Ch. 15 - Prob. 15.13EPCh. 15 - Prob. 15.14EPCh. 15 - Prob. 15.15EPCh. 15 - Prob. 15.16EPCh. 15 - Prob. 15.17EPCh. 15 - Prob. 15.18EPCh. 15 - Prob. 15.19EPCh. 15 - Prob. 15.20EPCh. 15 - Prob. 15.21EPCh. 15 - Prob. 15.22EPCh. 15 - Prob. 15.23EPCh. 15 - Prob. 15.24EPCh. 15 - Prob. 15.25EPCh. 15 - Prob. 15.26EPCh. 15 - Prob. 15.27EPCh. 15 - Prob. 15.28EPCh. 15 - Prob. 15.29EPCh. 15 - Prob. 15.30EPCh. 15 - Prob. 15.31EPCh. 15 - Prob. 15.32EPCh. 15 - Prob. 15.33EPCh. 15 - Prob. 15.34EPCh. 15 - Prob. 15.35EPCh. 15 - Prob. 15.36EPCh. 15 - Prob. 15.37EPCh. 15 - Prob. 15.38EPCh. 15 - Prob. 15.39EPCh. 15 - Prob. 15.40EPCh. 15 - Draw a structural formula for each of the...Ch. 15 - Prob. 15.42EPCh. 15 - Prob. 15.43EPCh. 15 - Prob. 15.44EPCh. 15 - Prob. 15.45EPCh. 15 - Prob. 15.46EPCh. 15 - Prob. 15.47EPCh. 15 - Prob. 15.48EPCh. 15 - Prob. 15.49EPCh. 15 - Prob. 15.50EPCh. 15 - Prob. 15.51EPCh. 15 - Prob. 15.52EPCh. 15 - Prob. 15.53EPCh. 15 - Prob. 15.54EPCh. 15 - Prob. 15.55EPCh. 15 - Prob. 15.56EPCh. 15 - Prob. 15.57EPCh. 15 - Prob. 15.58EPCh. 15 - Prob. 15.59EPCh. 15 - Prob. 15.60EPCh. 15 - Prob. 15.61EPCh. 15 - Prob. 15.62EPCh. 15 - Prob. 15.63EPCh. 15 - Prob. 15.64EPCh. 15 - Prob. 15.65EPCh. 15 - Prob. 15.66EPCh. 15 - Prob. 15.67EPCh. 15 - Which member in each of the following pairs of...Ch. 15 - Prob. 15.69EPCh. 15 - Prob. 15.70EPCh. 15 - Prob. 15.71EPCh. 15 - Prob. 15.72EPCh. 15 - Prob. 15.73EPCh. 15 - Prob. 15.74EPCh. 15 - Prob. 15.75EPCh. 15 - Prob. 15.76EPCh. 15 - Prob. 15.77EPCh. 15 - Prob. 15.78EPCh. 15 - Prob. 15.79EPCh. 15 - What is the chemical formula of the inorganic...Ch. 15 - Prob. 15.81EPCh. 15 - Which of the following compounds would react with...Ch. 15 - Prob. 15.83EPCh. 15 - Prob. 15.84EPCh. 15 - Which of the three compounds pentanal,...Ch. 15 - Prob. 15.86EPCh. 15 - Prob. 15.87EPCh. 15 - Prob. 15.88EPCh. 15 - Prob. 15.89EPCh. 15 - Prob. 15.90EPCh. 15 - Prob. 15.91EPCh. 15 - Prob. 15.92EPCh. 15 - Which carbon atom is the hemiacetal carbon atom in...Ch. 15 - Prob. 15.94EPCh. 15 - Prob. 15.95EPCh. 15 - Prob. 15.96EPCh. 15 - Prob. 15.97EPCh. 15 - Prob. 15.98EPCh. 15 - Prob. 15.99EPCh. 15 - Prob. 15.100EPCh. 15 - Prob. 15.101EPCh. 15 - Prob. 15.102EPCh. 15 - Prob. 15.103EPCh. 15 - Prob. 15.104EPCh. 15 - Prob. 15.105EPCh. 15 - Prob. 15.106EPCh. 15 - Prob. 15.107EPCh. 15 - Prob. 15.108EPCh. 15 - Prob. 15.109EPCh. 15 - Prob. 15.110EPCh. 15 - Prob. 15.111EPCh. 15 - Prob. 15.112EPCh. 15 - Prob. 15.113EPCh. 15 - Prob. 15.114EPCh. 15 - Prob. 15.115EPCh. 15 - Prob. 15.116EPCh. 15 - Prob. 15.117EPCh. 15 - Prob. 15.118EP
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