Chemistry for Today: General, Organic, and Biochemistry
Chemistry for Today: General, Organic, and Biochemistry
9th Edition
ISBN: 9781305960060
Author: Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher: Cengage Learning
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Chapter 14, Problem 14.2E
Interpretation Introduction

Interpretation:

The structural formulas for an aldehyde and a ketone containing as few carbon atoms as possible are to be drawn.

Concept introduction:

A carbonyl group has a carbon atom that is bonded to an oxygen atom through a double bond and single bonded to two other carbon atoms respectively.

Aldehydes and ketones contain carbonyl Chemistry for Today: General, Organic, and Biochemistry, Chapter 14, Problem 14.2E functional group in their parent chain and are named by adding suffix –al and –one to the name of the parent alkane.

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Both aldehydes and ketones contain carbonyl groups. In aldehydes, the carbonyl carbon atom is bonded to a hydrogen atom, whereas in ketones, the carbonyl carbon atom is bonded to another carbon atom. Select the true statements about aldehydes and ketones.   - Ketones have lower boiling points than alcohols of similar size. - Aldehydes contain a carbon–oxygen double bond. - Butanal has a higher boiling point than 2-butanol. - Aldehydes with more than five carbon atoms are soluble in water, but not organic solvents. - Both aldehydes and ketones can hydrogen bond with water molecules. - Propanal is a gas at room temperature, whereas formaldehyde (methanal) is a liquid at room temperature.
Ethanol is the alcohol found in all alcoholic beverages. Discuss how an alcoholic beverage would be different if it contained ethane instead of ethanol. In the online portion of the test, you were asked to rank 1-pentene, 1-pentanol, and pentanal in order from lowest to highest boiling point. Explain the reasons for the boiling point ranking. Compare and contrast alcohols with aldehydes/ketones. List at least 3 similarities and 3 differences.
How many acids can be obtained from alcohols and aldehydes?

Chapter 14 Solutions

Chemistry for Today: General, Organic, and Biochemistry

Ch. 14 - Each of the following names is wrong. Give the...Ch. 14 - Each of the following names is wrong. Give the...Ch. 14 - Prob. 14.13ECh. 14 - Prob. 14.14ECh. 14 - Prob. 14.15ECh. 14 - Explain why propane boils at 42C, whereas ethanal,...Ch. 14 - Use a dotted line to show hydrogen bonding between...Ch. 14 - Use a dotted line to show hydrogen bonding between...Ch. 14 - Prob. 14.19ECh. 14 - Prob. 14.20ECh. 14 - Prob. 14.21ECh. 14 - Prob. 14.22ECh. 14 - Prob. 14.23ECh. 14 - Prob. 14.24ECh. 14 - Label each of the following as acetals, ketals, or...Ch. 14 - Label each of the following as acetals, ketals, or...Ch. 14 - Label each of the following structures as a cyclic...Ch. 14 - Label each of the following structures as a...Ch. 14 - What two functional groups react to form the...Ch. 14 - Hemiacetals are sometimes referred to as potential...Ch. 14 - Complete the following statements: a. Oxidation of...Ch. 14 - Prob. 14.32ECh. 14 - Prob. 14.33ECh. 14 - Prob. 14.34ECh. 14 - Prob. 14.35ECh. 14 - Not all aldehyde give a positve Bendicts test....Ch. 14 - A stockroom assistant prepares three bottles, each...Ch. 14 - Glucose, the sugar present within the blood, gives...Ch. 14 - Fructose, present with glucose in honey, reacts...Ch. 14 - Prob. 14.40ECh. 14 - Prob. 14.41ECh. 14 - Complete the following equations. If no reaction...Ch. 14 - Complete the following equations. If no reaction...Ch. 14 - Describe the products that result when hydrogen...Ch. 14 - Prob. 14.45ECh. 14 - Draw structural formulas for the products of the...Ch. 14 - The following compounds are cyclic acetals or...Ch. 14 - The following compounds are cyclic acetals or...Ch. 14 - Write equations to show how the following...Ch. 14 - Prob. 14.50ECh. 14 - Identify the most important aldehyde and ketone...Ch. 14 - Using Table 14.3, name an aldehyde or ketone used...Ch. 14 - Prob. 14.53ECh. 14 - CH3COH(O)CH3COOHacetaldehydeaceticacid You need to...Ch. 14 - The addition of water to aldehydes and ketones...Ch. 14 - Prob. 14.56ECh. 14 - Formaldehyde levels above 0.10mg/1000L of ambient...Ch. 14 - In the IUPAC name for the following ketone, it is...Ch. 14 - Why can formaldehyde (CH2O) be prepared in the...Ch. 14 - Other addition reactions of aldehydes occur....Ch. 14 - Prob. 14.61ECh. 14 - Prob. 14.62ECh. 14 - Vanilla flavoring is either extracted from a...Ch. 14 - Prob. 14.64ECh. 14 - The use of acetone in laboratory experiments must...Ch. 14 - Prob. 14.66ECh. 14 - Prob. 14.67ECh. 14 - Which of the following would be classified as a...
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