The major and minor products of the reaction of tertiary alcohol with concentrated sulphuric acid H 2 SO 4 in heat are to be determined. Concept Introduction: The reaction of tertiary alcohols with strong acids usually results in a dehydration reaction, which is the loss of water molecules from the reactant. This dehydration of alcohol usually results in the formation of an unsaturated hydrocarbon .

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 12.9, Problem 21CC

(a)

Interpretation Introduction

Interpretation:

The major and minor products of the reaction of tertiary alcohol with concentrated sulphuric acid H2SO4 in heat are to be determined.

Concept Introduction:

The reaction of tertiary alcohols with strong acids usually results in a dehydration reaction, which is the loss of water molecules from the reactant. This dehydration of alcohol usually results in the formation of an unsaturated hydrocarbon.

(b)

Interpretation Introduction

Interpretation:

The reaction of cyclopentanol with Tosyl chloride followed by a reaction with sodium ethoxide is to be determined.

Concept Introduction:

Tosyl chloride on reacting with alcoholic groups forms tosylates, which protects the alcoholic group and is a second substrate. It facilitates further reactions in which the otherwise open alcoholic group would hinder the rate and yield of the reactions.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

which of the compounds listed would be the expected enol intermediate? I II III IV V

Propose a plausible mechanism for the following transformation: HO [H3O+] EtOH 19.55 The first three steps of the mechanism involve the formation of The first step is The second step is The third step is eTextbook and Media Save for Later Attem

Which is the most acidic hydrogen in this compound? Briefly explain the choice. Write the structure of the corresponding enolate and its resonance structures.

Answer 2

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 12.9, Problem 21CC

(a)

Interpretation Introduction

Interpretation:

The major and minor products of the reaction of tertiary alcohol with concentrated sulphuric acid H2SO4 in heat are to be determined.

Concept Introduction:

The reaction of tertiary alcohols with strong acids usually results in a dehydration reaction, which is the loss of water molecules from the reactant. This dehydration of alcohol usually results in the formation of an unsaturated hydrocarbon.

(b)

Interpretation Introduction

Interpretation:

The reaction of cyclopentanol with Tosyl chloride followed by a reaction with sodium ethoxide is to be determined.

Concept Introduction:

Tosyl chloride on reacting with alcoholic groups forms tosylates, which protects the alcoholic group and is a second substrate. It facilitates further reactions in which the otherwise open alcoholic group would hinder the rate and yield of the reactions.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 12.9, Problem 21CC

(a)

Interpretation Introduction

Interpretation:

The major and minor products of the reaction of tertiary alcohol with concentrated sulphuric acid H2SO4 in heat are to be determined.

Concept Introduction:

The reaction of tertiary alcohols with strong acids usually results in a dehydration reaction, which is the loss of water molecules from the reactant. This dehydration of alcohol usually results in the formation of an unsaturated hydrocarbon.

(b)

Interpretation Introduction

Interpretation:

The reaction of cyclopentanol with Tosyl chloride followed by a reaction with sodium ethoxide is to be determined.

Concept Introduction:

Tosyl chloride on reacting with alcoholic groups forms tosylates, which protects the alcoholic group and is a second substrate. It facilitates further reactions in which the otherwise open alcoholic group would hinder the rate and yield of the reactions.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 12.9, Problem 21CC

(a)

Interpretation Introduction

Interpretation:

The major and minor products of the reaction of tertiary alcohol with concentrated sulphuric acid H2SO4 in heat are to be determined.

Concept Introduction:

The reaction of tertiary alcohols with strong acids usually results in a dehydration reaction, which is the loss of water molecules from the reactant. This dehydration of alcohol usually results in the formation of an unsaturated hydrocarbon.

(b)

Interpretation Introduction

Interpretation:

The reaction of cyclopentanol with Tosyl chloride followed by a reaction with sodium ethoxide is to be determined.

Concept Introduction:

Tosyl chloride on reacting with alcoholic groups forms tosylates, which protects the alcoholic group and is a second substrate. It facilitates further reactions in which the otherwise open alcoholic group would hinder the rate and yield of the reactions.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 12.9, Problem 21CC

(a)

Interpretation Introduction

Interpretation:

The major and minor products of the reaction of tertiary alcohol with concentrated sulphuric acid H2SO4 in heat are to be determined.

Concept Introduction:

The reaction of tertiary alcohols with strong acids usually results in a dehydration reaction, which is the loss of water molecules from the reactant. This dehydration of alcohol usually results in the formation of an unsaturated hydrocarbon.

(b)

Interpretation Introduction

Interpretation:

The reaction of cyclopentanol with Tosyl chloride followed by a reaction with sodium ethoxide is to be determined.

Concept Introduction:

Tosyl chloride on reacting with alcoholic groups forms tosylates, which protects the alcoholic group and is a second substrate. It facilitates further reactions in which the otherwise open alcoholic group would hinder the rate and yield of the reactions.

Answer 6

Chapter 12.9, Problem 21CC

(a)

Interpretation Introduction

Interpretation:

The major and minor products of the reaction of tertiary alcohol with concentrated sulphuric acid H2SO4 in heat are to be determined.

Concept Introduction:

The reaction of tertiary alcohols with strong acids usually results in a dehydration reaction, which is the loss of water molecules from the reactant. This dehydration of alcohol usually results in the formation of an unsaturated hydrocarbon.

Answer 7

Chapter 12.9, Problem 21CC

(a)

Interpretation Introduction

Interpretation:

The major and minor products of the reaction of tertiary alcohol with concentrated sulphuric acid H2SO4 in heat are to be determined.

Concept Introduction:

The reaction of tertiary alcohols with strong acids usually results in a dehydration reaction, which is the loss of water molecules from the reactant. This dehydration of alcohol usually results in the formation of an unsaturated hydrocarbon.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The reaction of cyclopentanol with Tosyl chloride followed by a reaction with sodium ethoxide is to be determined.

Concept Introduction:

Tosyl chloride on reacting with alcoholic groups forms tosylates, which protects the alcoholic group and is a second substrate. It facilitates further reactions in which the otherwise open alcoholic group would hinder the rate and yield of the reactions.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The reaction of cyclopentanol with Tosyl chloride followed by a reaction with sodium ethoxide is to be determined.

Concept Introduction:

Tosyl chloride on reacting with alcoholic groups forms tosylates, which protects the alcoholic group and is a second substrate. It facilitates further reactions in which the otherwise open alcoholic group would hinder the rate and yield of the reactions.

Answer 10

Expert Solution & Answer

Answer 11

Expert Solution & Answer

Answer 12

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 13

Ch. 12.1 - Prob. 1LTS Ch. 12.1 - Prob. 1PTS Ch. 12.1 - Prob. 2ATS Ch. 12.1 - Prob. 3CC Ch. 12.2 - Prob. 4CC Ch. 12.3 - Prob. 8CC Ch. 12.3 - Prob. 9CC Ch. 12.4 - Prob. 3LTS Ch. 12.4 - Prob. 10PTS Ch. 12.4 - Prob. 11ATS

Solution Summary: The author explains the reaction of tertiary alcohols with strong acids results in a dehydration reaction, which leads to the formation of an unsaturated hydrocarbon.

Want to see the full answer?

Chapter 12 Solutions