EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Chapter 12.4, Problem 11ATS
Interpretation Introduction
Interpretation:
The given reaction is the conversion of
Concept introduction:
It is done by calculating the oxidation state of the atoms. If there is an increase in the charge on any atom, it is said to be oxidized. If there is a decrease in the oxidation state of the atom, it is said to be reduced. The oxidation state of the carbon on which the change has occurred must be calculated by cleaving the bonds between carbon and the atom to which it is attached.
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I2 (aq) + CH3COCH3 (aq) HI (aq) + ICH2COCH3 (aq)Iodine in solution has a yellow-brown color, whereas the acetone and both products are colorless. This means that we can run the reaction using iodine as the limiting reagent, and when we see that the yellow-brown color of the iodine has disappeared, we know that the reaction has stopped and all of the iodine has been consumed.
Recall that to calculate a rate of reaction, we would like toknow the change in concentration of a reactant or product during a fixed amount of time. Wewill choose the reactant iodine in this case, because its brown color allows us to determinewhen its concentration has fallen to zero.
Rate = –Δ[I2] / Δt = – ([I2]final – [I2]initial) / ([tfinal – tinitial) = – (0 – [I2]initial) / (tfinal – 0) = [I2]initial / tfinal
Run several trials at different concentrations of reactants and use themethod of initial rates to obtain values for k, x, y, and z in the rate law.
Rate = k [I2]x [acetone]y [H+]z
Run the…
Which of the following compounds have the same oxidation level as the compound in row 1?
(Enter your answer in numerical order as the row number(s) separated by commas, i.e. 2,3,5. If none of the compounds have the same oxidation level, write 'none'.)
First set
Second set
Row 1
Row 2
NH2
OH
Row 3
Br
NH2
Row 4
NH2
Row 5
Br
First set:
Second set:
82. The space shuttle Orbiter utilizes the oxidation of methylhy-
drazine by dinitrogen tetroxide for propulsion:
4N₂H3CH3(1) + 5N₂O4 (1) 12H₂O(g) + 9N₂(g) + 4CO2(8)
Calculate AH for this reaction.
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Chapter 12 Solutions
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
Ch. 12.1 - Prob. 1LTSCh. 12.1 - Prob. 1PTSCh. 12.1 - Prob. 2ATSCh. 12.1 - Prob. 3CCCh. 12.2 - Prob. 4CCCh. 12.3 - Prob. 8CCCh. 12.3 - Prob. 9CCCh. 12.4 - Prob. 3LTSCh. 12.4 - Prob. 10PTSCh. 12.4 - Prob. 11ATS
Ch. 12.4 - Prob. 4LTSCh. 12.4 - Prob. 12PTSCh. 12.4 - Prob. 13ATSCh. 12.6 - Prob. 14CCCh. 12.6 - Prob. 5LTSCh. 12.6 - Prob. 15PTSCh. 12.6 - Prob. 16PTSCh. 12.7 - Prob. 18CCCh. 12.9 - Prob. 6LTSCh. 12.9 - Prob. 19PTSCh. 12.9 - Prob. 20ATSCh. 12.9 - Prob. 21CCCh. 12.10 - Prob. 7LTSCh. 12.10 - Prob. 22PTSCh. 12.10 - Prob. 23ATSCh. 12.13 - Prob. 8LTSCh. 12.13 - Prob. 24PTSCh. 12.13 - Prob. 25ATSCh. 12.13 - Prob. 26CCCh. 12.13 - Prob. 9LTSCh. 12.13 - Prob. 27PTSCh. 12.13 - Prob. 28ATSCh. 12 - Prob. 29PPCh. 12 - Prob. 30PPCh. 12 - Prob. 31PPCh. 12 - Prob. 32PPCh. 12 - Prob. 33PPCh. 12 - Prob. 34PPCh. 12 - Prob. 35PPCh. 12 - Prob. 36PPCh. 12 - Prob. 37PPCh. 12 - Prob. 38PPCh. 12 - Prob. 39PPCh. 12 - Prob. 40PPCh. 12 - Prob. 41PPCh. 12 - Prob. 42PPCh. 12 - Prob. 43PPCh. 12 - Prob. 44PPCh. 12 - Prob. 45PPCh. 12 - Prob. 46PPCh. 12 - Prob. 47PPCh. 12 - Prob. 48PPCh. 12 - Prob. 49PPCh. 12 - Prob. 50PPCh. 12 - Prob. 51PPCh. 12 - Prob. 52PPCh. 12 - Prob. 53ASPCh. 12 - Prob. 54ASPCh. 12 - Prob. 55ASPCh. 12 - Prob. 62IPCh. 12 - Prob. 64IPCh. 12 - Prob. 65IPCh. 12 - Prob. 66IPCh. 12 - Prob. 67IPCh. 12 - Prob. 68IPCh. 12 - Prob. 69IPCh. 12 - Prob. 74IP
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