A proper synthesis for the following compound using acetylene is to be determined. Concept introduction : The final product has ten carbon atoms, while the starting material acetylene has only two carbon atoms. This means there must be many carbon-carbon coupling reactions involved. The product is an ester which means one of the possible ways of synthesis must be a reaction of a carboxylic acid and an alcohol. Using this concept, an efficient synthesis can be described.

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 12.13, Problem 28ATS

Interpretation Introduction

Interpretation:

A proper synthesis for the following compound using acetylene is to be determined.

Concept introduction:

The final product has ten carbon atoms, while the starting material acetylene has only two carbon atoms. This means there must be many carbon-carbon coupling reactions involved. The product is an ester which means one of the possible ways of synthesis must be a reaction of a carboxylic acid and an alcohol. Using this concept, an efficient synthesis can be described.

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(a) Tsomane and Nyiko were given a task of synthesising methylenecyclohexane 2. After a brief discussion with each other, Tsomane proposed Method A to synthesise 2 from cyclohexanone 1 while Nyiko proposed Method B that started from hydroxymethylcyclohexane 3. Each student believed that their proposed method is better than the other. (Scheme below) (1) 1 Ph THF A Ph Ph B H₂SO4 100 °C 3 OH What is the name of the reaction that is followed by reaction Method A?

(a) Tsomane and Nyiko were given a task of synthesising methylenecyclohexane 2. After a brief discussion with each other, Tsomane proposed Method A to synthesise 2 from cyclohexanone 1 while Nyiko proposed Method B that started from hydroxymethylcyclohexane 3. Each student believed that their proposed method is better than the other. (Scheme below) (1) Ph Ph 8*8 Ph THF A 1 Santande B H₂SO4 100 °C 3 OH Using curly arrows, provide full mechanistic details accounting how methylenecyclohexane 2 was synthesised according to both Methods A and B.

Answer 2

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 12.13, Problem 28ATS

Interpretation Introduction

Interpretation:

A proper synthesis for the following compound using acetylene is to be determined.

Concept introduction:

The final product has ten carbon atoms, while the starting material acetylene has only two carbon atoms. This means there must be many carbon-carbon coupling reactions involved. The product is an ester which means one of the possible ways of synthesis must be a reaction of a carboxylic acid and an alcohol. Using this concept, an efficient synthesis can be described.

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Check out a sample textbook solution

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 12.13, Problem 28ATS

Interpretation Introduction

Interpretation:

A proper synthesis for the following compound using acetylene is to be determined.

Concept introduction:

The final product has ten carbon atoms, while the starting material acetylene has only two carbon atoms. This means there must be many carbon-carbon coupling reactions involved. The product is an ester which means one of the possible ways of synthesis must be a reaction of a carboxylic acid and an alcohol. Using this concept, an efficient synthesis can be described.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 12.13, Problem 28ATS

Interpretation Introduction