Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Textbook Question
Chapter 1, Problem 43P
Assign formal charges to each
a. 
b. 
c. 
d. 
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The element sulphur has atomic number 16. Sulphur forms a molecular compound with chloride with a molecular formula SCl2. The atomic number of chlorine is 17.
a. Write down the electronic configuration of a sulphur atom and a chlorine atom.
b. Draw a Lewis structure of an SCl2 molecule, by showing the electrons in the outer shells of the atoms.
c. State how many bond pairs and lone pairs of electrons are arranged around the sulphur atoms in SCl2 molecule.
d. Sketch the shape and state the molecular geometry of SCl2 molecule.
e. Explain the hybridisation of the central atom in SCl2 molecule.
f.Explain the intermolecular forces exists in SCl2 molecule.
Draw a Lewis structure for SO2 that obeys the octet rule if possible and answer the following questions based on your drawing.
1. For the central sulfur atom:
- The number of lone pairs = ?
- The number of single bonds = ?
- The number of double bonds = ?
2. The central sulfur atom
a. obeys the octet rule.
b. has an incomplete octet.
c. has an expanded octet.
A. CHF
i. Best Lewis Structure
B. HNO (H is connected to one of the O's)
i. Best Lewis Structure
ii. Electron geometry on the C atom
ii. Electron geometry on the N atom
iii. Approximate bond angles about the C atom
iii. Approximate bond angles around the N atom
v. Draw the shape with in and out wedges (as necessary) and
dipole arrows around the C atom.
v. Draw the shape with in and out wedges (as necessary) and
dipole arrows around the N atom.
vi. Is the molecule polar or nonpolar?
vi. Is the molecule polar or nonpolar?
Chapter 1 Solutions
Organic Chemistry (6th Edition)
Ch. 1.1 - While the most common isotope of nitrogen has a...Ch. 1.2 - Label each bond in the following compounds as...Ch. 1.3 - Draw a valid Lewis structure for each species. a....Ch. 1.3 - Prob. 9PCh. 1.4 - Draw Lewis structures for each molecular formula....Ch. 1.6 - Classify each pair of compounds as isomers or...Ch. 1.6 - Prob. 12PCh. 1.6 - Prob. 13PCh. 1.6 - Prob. 14PCh. 1.6 - Prob. 16P
Ch. 1.6 - Prob. 17PCh. 1.7 - Prob. 18PCh. 1.7 - Prob. 19PCh. 1.7 - Using the principles of VSEPR theory, you can...Ch. 1.8 - Convert each condensed formula to a Lewis...Ch. 1.8 - Prob. 22PCh. 1.8 - Prob. 23PCh. 1.8 - Convert each skeletal structure to a complete...Ch. 1 - Citric acid is responsible for the tartness of...Ch. 1 - Zingerone gives ginger its pungent taste. a.What...Ch. 1 - Assign formal charges to each and atom in the...Ch. 1 - Prob. 44PCh. 1 - Prob. 46PCh. 1 - Draw all possible isomers for each molecular...Ch. 1 - 1.45 Draw Lewis structures for the nine isomers...Ch. 1 - Prob. 52PCh. 1 - Prob. 53PCh. 1 - Prob. 54PCh. 1 - Consider compounds A-D, which contain both a...Ch. 1 - Draw in all the carbon and hydrogen atoms in each...Ch. 1 - 1.61 Convert each molecule into a skeletal...Ch. 1 - Prob. 65PCh. 1 - Predict the hybridization and geometry around each...Ch. 1 - Prob. 68PCh. 1 - Ketene, , is an unusual organic molecule that has...Ch. 1 - Rank the following bonds in order of increasing...Ch. 1 - Two useful organic compounds that contain Cl atoms...Ch. 1 - Use the symbols + and to indicate the polarity of...Ch. 1 - Prob. 74PCh. 1 - Anacin is an over-the-counter pain reliever that...Ch. 1 - 1.77 Stalevo is the trade name for a medication...Ch. 1 - 1.78 and are two highly reactive carbon...Ch. 1 - 1.79 The N atom in (acetamide) is hybridized,...Ch. 1 - Prob. 83PCh. 1 - Prob. 84PCh. 1 - Prob. 85PCh. 1 - Prob. 86PCh. 1 - Prob. 87PCh. 1 - Prob. 88P
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- To answer the questions, interpret the following Lewis diagram for SO42- . 1. For the central sulfur atom: ... The number of non-bonding electrons = The number of bonding electrons = The total number of electrons = 2. The central sulfur atom fill in the blank 4 ... A. obeys the octet rule. B. has more than an octet. C. has less than an octet.arrow_forwardDraw a Lewis structure for BF3 that obeys the octet rule if possible and answer the following questions based on your drawing. 1. For the central boron atom: - The number of lone pairs = ? - The number of single bonds = ? - The number of double bonds = ? 2. The central boron atom is a. obeys the octet rule. b. has an incomplete octet. c. has an expanded octet.arrow_forwardDraw a resonance structure that places a pi bond in a different position. Include all lone pairs in your structure. :O: H. H. 工 :O:arrow_forward
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