Chemical Principles: The Quest for Insight
Chemical Principles: The Quest for Insight
7th Edition
ISBN: 9781464183959
Author: Peter Atkins, Loretta Jones, Leroy Laverman
Publisher: W. H. Freeman
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Chapter 1, Problem 1F.2E

(a)

Interpretation Introduction

Interpretation:

The elements, bromine, chlorine and iodine has to be arranged in the decreasing order of atomic radius.

Concept Introduction:

Atomic radius is the distance between the atomic nucleus and outermost shell having electrons of an atom. From the atomic radius, the size of atoms can be visualized

Down the group, the principal quantum number increases and thus the size of orbital also increases which results in the increase in atomic radii.

Along the period, the valence electron is added to the same shell and thus attraction by the nucleus gets stronger. Therefore, atomic radii reduces from left to right in the periodic table.

(b)

Interpretation Introduction

Interpretation:

The elements, gallium, selenium and arsenic has to be arranged in the decreasing order of atomic radius.

Concept Introduction:

Refer to (a).

(c)

Interpretation Introduction

Interpretation:

The elements, calcium, potassium and zinc has to be arranged in the decreasing order of atomic radius.

Concept Introduction:

Refer to (a).

(d)

Interpretation Introduction

Interpretation:

The elements, barium, calcium and strontium has to be arranged in the decreasing order of atomic radius.

Concept Introduction:

Refer to (a).

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Boron, atomic number 5, occurs naturally as two isotopes, 10B and 11B, with natural abundances of 19.9% and 80.1%, respectively.  (a) In what ways do the two isotopes differ from each other? Does the electronic configuration of 10B differ from that of 11B? (b) Draw the orbital diagram for an atom of 11B. Which electrons are the valence electrons? (c) Indicate three ways in which the 1s electrons in boron differ from its 2s electrons. (d) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation for the reaction of solid boron with fluorine gas. (e) ­ΔHf° for BF3(g) is -1135.6 kj/mol. Calculate the standard enthalpy change in the reaction of boron with fluorine. (f) Will the mass percentage of F be the same in 10BF3 and 11BF3? If not, why is that the case?
Boron, atomic number 5, occurs naturally as two isotopes, 10B and 11B, with natural abundances of 19.9% and 80.1%, respectively.(a) In what ways do the two isotopes differ from each other? Does the electronic configuration of 10B differ from that of 11B? (b) Drawthe orbital diagram for an atom of 11B. Which electrons are the valence electrons? (c) Indicate three ways in which the 1s electrons inboron differ from its 2s electrons. (d) Elemental boron reacts with fluorine to form BF3, a gas. Write a balanced chemical equation forthe reaction of solid boron with fluorine gas. (e) ΔHf° for BF31g2 is -1135.6 kJ>mol. Calculate the standard enthalpy change in thereaction of boron with fluorine. (f) Will the mass percentage of F be the same in 10BF3 and 11BF3? If not, why is that the case?
3. Classify each of the following elements as a noble gas, a representative element, a transition element, or an inner-transition element. Also state whether the element is paramagnetic or diamagnetic: (a) potassium; (b) phosphorous; (c) promethium; (d) platinum; (e) krypton.

Chapter 1 Solutions

Chemical Principles: The Quest for Insight

Ch. 1 - Prob. 1A.8ECh. 1 - Prob. 1A.9ECh. 1 - Prob. 1A.10ECh. 1 - Prob. 1A.11ECh. 1 - Prob. 1A.12ECh. 1 - Prob. 1A.13ECh. 1 - Prob. 1A.14ECh. 1 - Prob. 1A.15ECh. 1 - Prob. 1A.16ECh. 1 - Prob. 1A.17ECh. 1 - Prob. 1B.1ASTCh. 1 - Prob. 1B.1BSTCh. 1 - Prob. 1B.2ASTCh. 1 - Prob. 1B.2BSTCh. 1 - Prob. 1B.3ASTCh. 1 - Prob. 1B.3BSTCh. 1 - Prob. 1B.4ASTCh. 1 - Prob. 1B.4BSTCh. 1 - Prob. 1B.5ASTCh. 1 - Prob. 1B.5BSTCh. 1 - Prob. 1B.1ECh. 1 - Prob. 1B.2ECh. 1 - Prob. 1B.3ECh. 1 - Prob. 1B.4ECh. 1 - Prob. 1B.5ECh. 1 - Prob. 1B.6ECh. 1 - Prob. 1B.7ECh. 1 - Prob. 1B.8ECh. 1 - Prob. 1B.9ECh. 1 - Prob. 1B.10ECh. 1 - Prob. 1B.11ECh. 1 - Prob. 1B.12ECh. 1 - Prob. 1B.13ECh. 1 - Prob. 1B.14ECh. 1 - Prob. 1B.15ECh. 1 - Prob. 1B.16ECh. 1 - Prob. 1B.17ECh. 1 - Prob. 1B.18ECh. 1 - Prob. 1B.19ECh. 1 - Prob. 1B.21ECh. 1 - Prob. 1B.22ECh. 1 - Prob. 1B.23ECh. 1 - Prob. 1B.24ECh. 1 - Prob. 1B.25ECh. 1 - Prob. 1B.26ECh. 1 - Prob. 1B.27ECh. 1 - Prob. 1B.28ECh. 1 - Prob. 1C.1ASTCh. 1 - Prob. 1C.1BSTCh. 1 - Prob. 1C.1ECh. 1 - Prob. 1C.2ECh. 1 - Prob. 1C.3ECh. 1 - Prob. 1C.7ECh. 1 - Prob. 1D.1ASTCh. 1 - Prob. 1D.1BSTCh. 1 - Prob. 1D.2ASTCh. 1 - Prob. 1D.2BSTCh. 1 - Prob. 1D.1ECh. 1 - Prob. 1D.2ECh. 1 - Prob. 1D.3ECh. 1 - Prob. 1D.4ECh. 1 - Prob. 1D.5ECh. 1 - Prob. 1D.6ECh. 1 - Prob. 1D.7ECh. 1 - Prob. 1D.9ECh. 1 - Prob. 1D.10ECh. 1 - Prob. 1D.11ECh. 1 - Prob. 1D.12ECh. 1 - Prob. 1D.13ECh. 1 - Prob. 1D.14ECh. 1 - Prob. 1D.15ECh. 1 - Prob. 1D.16ECh. 1 - Prob. 1D.17ECh. 1 - Prob. 1D.18ECh. 1 - Prob. 1D.19ECh. 1 - Prob. 1D.20ECh. 1 - Prob. 1D.21ECh. 1 - Prob. 1D.22ECh. 1 - Prob. 1D.23ECh. 1 - Prob. 1D.24ECh. 1 - Prob. 1D.25ECh. 1 - Prob. 1D.26ECh. 1 - Prob. 1E.1ASTCh. 1 - Prob. 1E.1BSTCh. 1 - Prob. 1E.2ASTCh. 1 - Prob. 1E.2BSTCh. 1 - Prob. 1E.1ECh. 1 - Prob. 1E.2ECh. 1 - Prob. 1E.3ECh. 1 - Prob. 1E.4ECh. 1 - Prob. 1E.5ECh. 1 - Prob. 1E.7ECh. 1 - Prob. 1E.8ECh. 1 - Prob. 1E.9ECh. 1 - Prob. 1E.10ECh. 1 - Prob. 1E.11ECh. 1 - Prob. 1E.12ECh. 1 - Prob. 1E.13ECh. 1 - Prob. 1E.14ECh. 1 - Prob. 1E.15ECh. 1 - Prob. 1E.16ECh. 1 - Prob. 1E.17ECh. 1 - Prob. 1E.18ECh. 1 - Prob. 1E.19ECh. 1 - Prob. 1E.20ECh. 1 - Prob. 1E.21ECh. 1 - Prob. 1E.22ECh. 1 - Prob. 1E.23ECh. 1 - Prob. 1E.24ECh. 1 - Prob. 1E.25ECh. 1 - Prob. 1E.26ECh. 1 - Prob. 1F.1ASTCh. 1 - Prob. 1F.1BSTCh. 1 - Prob. 1F.2ASTCh. 1 - Prob. 1F.2BSTCh. 1 - Prob. 1F.3BSTCh. 1 - Prob. 1F.1ECh. 1 - Prob. 1F.2ECh. 1 - Prob. 1F.3ECh. 1 - Prob. 1F.4ECh. 1 - Prob. 1F.5ECh. 1 - Prob. 1F.6ECh. 1 - Prob. 1F.7ECh. 1 - Prob. 1F.8ECh. 1 - Prob. 1F.10ECh. 1 - Prob. 1F.11ECh. 1 - Prob. 1F.12ECh. 1 - Prob. 1F.13ECh. 1 - Prob. 1F.14ECh. 1 - Prob. 1F.15ECh. 1 - Prob. 1F.17ECh. 1 - Prob. 1F.18ECh. 1 - Prob. 1F.19ECh. 1 - Prob. 1F.22ECh. 1 - Prob. 1.1ECh. 1 - Prob. 1.2ECh. 1 - Prob. 1.3ECh. 1 - Prob. 1.9ECh. 1 - Prob. 1.10ECh. 1 - Prob. 1.11ECh. 1 - Prob. 1.12ECh. 1 - Prob. 1.13ECh. 1 - Prob. 1.14ECh. 1 - Prob. 1.15ECh. 1 - Prob. 1.17ECh. 1 - Prob. 1.19ECh. 1 - Prob. 1.21ECh. 1 - Prob. 1.22ECh. 1 - Prob. 1.23ECh. 1 - Prob. 1.24ECh. 1 - Prob. 1.25ECh. 1 - Prob. 1.27ECh. 1 - Prob. 1.28ECh. 1 - Prob. 1.31E
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