Principles of General Chemistry
Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
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Chapter 1, Problem 1.65P

a)

Interpretation Introduction

Interpretation:Value of gold in double eagle before and after 1933 price change is to be determined.

Concept introduction:Conversion factor is ratio that is widely used to describe relation between two different units. In order to convert one unit into another, original unit is multiplied with proper conversion factor to yield new unit. This is done as mentioned below.

  Final unit=(Original unit)(Final unit Original unit)

a)

Expert Solution
Check Mark

Answer to Problem 1.65P

Values of gold in double eagle before and after 1933 price change are $19.3518 and $33.8657 respectively.

Explanation of Solution

Since double eagle contains 90.0 % gold by mass, amount of gold in double eagle can be calculated as follows:

  Amount of gold=( 90 % 100 %)(33.436 g)=30.092 g

This amount is to be converted into troy oz . Conversion factor for this is as follows:

  Amount of gold=(30.092 g)( 1 troy oz 31.1 g)=0.96759 troy oz

The value of gold before 1933 can be calculated as follows:

  Value of gold before 1933=(0.96759 troy oz)( $20.00 1 troy oz)=$19.3518

The value of gold after 1933 can be calculated as follows:

  Value of gold before 1933=(0.96759 troy oz)( $35.00 1 troy oz)=$33.8657

b)

Interpretation Introduction

Interpretation:Number of coins that can be made from 50 troy oz of gold is to be determined.

Concept introduction:Conversion factor is ratio that is widely used to describe relation between two different units. In order to convert one unit into another, original unit is multiplied with proper conversion factor to yield new unit. This is done as mentioned below.

  Final unit=(Original unit)(Final unit Original unit)

b)

Expert Solution
Check Mark

Answer to Problem 1.65P

52 coins can be made from 50 troy oz of gold.

Explanation of Solution

Since double eagle contains 90.0 % gold by mass, amount of gold in double eagle can be calculated as follows:

  Amount of gold=( 90 % 100 %)(33.436 g)=30.092 g

This amount is to be converted into troy oz . Conversion factor for this is as follows:

  Amount of gold=(30.092 g)( 1 troy oz 31.1 g)=0.96759 troy oz

Since 0.96759 troy oz of gold make one coin, number of coins formed by 50 troy oz of gold can be calculated as follows:

  Number of coins=(50 troy oz)( 1 coin 0.96759 troy oz)=51.7 coins52 coins

c)

Interpretation Introduction

Interpretation:Number of coins that can be made from 2.00 in3 of gold is to be determined.

Concept introduction:Density is defined as mass per unit volume. It is denoted by d . The expression to calculate density is as follows:

  d=MV

Where,

  • dis the density.
  • Mis mass.
  • Vis volume.

c)

Expert Solution
Check Mark

Answer to Problem 1.65P

21 coins can be made from 2.00 in3 of gold.

Explanation of Solution

The expression to calculate density of gold is as follows:

  d=MV

Where,

  • dis the density of gold.
  • Mis mass of gold.
  • Vis volume of gold.

Rearrange above equation for M .

  M=dV

The value of d is 19.3 g/cm3 .

The value of V is 2.00 in3 .

Substitute the values in above equation.

  M=dV=(19.3  g/cm3)(2.00  in3)( 16.3871  cm 3 1  in 3 )=632.54206 g

This amount is to be converted into troy oz . Conversion factor for this is as follows:

  Amount of gold=(632.54206 g)( 1 troy oz 31.1 g)=20.339 troy oz

Since 0.96759 troy oz of gold make one coin, number of coins formed by 20.339 troy oz of gold can be calculated as follows:

  Number of coins=(20.339 troy oz)( 1 coin 0.96759 troy oz)=21.02 coins21 coins

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Chapter 1 Solutions

Principles of General Chemistry

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