Principles of General Chemistry
Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
Question
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Chapter 1, Problem 1.76P

(a)

Interpretation Introduction

Interpretation:

The number of particles present in the air for the given space is to be determined.

Concept Introduction:

The air in the atmosphere is a mixture of different gases and particles. Usually, air contains a balanced composition of gases and particles. However, emissions from industries and automobiles can increase the amount of some gases and particles in air. It causes an imbalance of the atmosphere which can lead to some harmful outcomes.

(a)

Expert Solution
Check Mark

Answer to Problem 1.76P

The number of particles present in the air for the given space is 7.15×107 .

Explanation of Solution

Assuming the particles in air are spherical structures with a dimeter of 2.5μm , the volume of a single particle can be calculated. The equation for the calculation of the volume of a sphere is as follows.

  V=43πr3

Where, V is the volume of the sphere, and r is the radius of the sphere.The diameter of the sphere is given in the question.

  r=d2=2.52=1.25μmV=43πr3 V= 4 3 ×3.14× (1.25) 3 =8.17μ m 3

Thereafter, the total volume of the room has to be calculated. The dimensions of the room are given in the units of feet, thus, the units should be converted into meters.

  Vroom=103.28×8.253.28×12.53.28m3=29.21m3

The equation can be used to determine the number of particles in the room.

  Standard density=mass of a particle×number of particlestotal volume of the room

Therefore, first, the mass of a particles should be calculated.

  Mass of a particle=density×volume of a particleMass of a particle=2.5gcm3×8.17μm3=2.5×106gm3×8.17×1018m3=20.425×1012g

Then the obtained values can be used in the above mentioned equation to get the number of particles in the room.

  50.0×106gm3=20.425×1012g×number of particles29.21m3number of particles=50.0×106×29.2120.425×1012=7.15×107

(b)

Interpretation Introduction

Interpretation:

The amount of particles in air per breath a human takes is to be calculated.

Concept Introduction:

The air in the atmosphere is a mixture of different gases and particles. Usually, air contains a balanced composition of gases and particles. However, emissions from industries and automobiles can increase the amount of some gases and particles in air. It causes an imbalance of the atmosphere which can lead to some harmful outcomes.

(b)

Expert Solution
Check Mark

Answer to Problem 1.76P

The allowable amount of particles in air per breath a human takes is 1.22×103 .

Explanation of Solution

Assuming the particles in air are spherical structures with a dimeter of 2.5μm , the volume of a single particle can be calculated. The equation for the calculation of the volume of a sphere is as follows.

  V=43πr3

Where, V is the volume of the sphere, and r is the radius of the sphere. The diameter of the sphere is given in the question.

  r=d2=2.52=1.25μmV=43πr3 V= 4 3 ×3.14× (1.25) 3 =8.17μ m 3

Mass of a particle can be calculated using this volume.

  Mass of a particle=density×volume of a particleMass of a particle=2.5gcm3×8.17μm3=2.5×106gm3×8.17×1018m3=20.425×1012g

The allowable amount of particles in the human breath can be calculated as follows:

  Standard density=mass of a particle × number of particlesvolume of human breath50.0×106gm3=20.425×1012g×number of particles0.500×103m3number of particles=50.0×106×0.500×10320.425×1012=1.22×103

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Chapter 1 Solutions

Principles of General Chemistry

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