The structure of the cyclooctane has to be determined. Concept Introduction: Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word. Prefix - Represents the substituent present in the molecule and its position in the root name. Suffix denotes the presence of functional group if any in the molecule. It can be an alkene , alkyne , alcohol, carboxylic acid, alcohol etc... Root word - Represents the longest continuous carbon skeleton of the organic molecule. When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo , if it is two cyclic structure combined then prefixed with bicyclo . Naming of Cycloalkane using IUPAC nomenclature : Use the Cycloalkane name as the parent. Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes . There is no need to assign a number if there is one substituent on the ring. Identify and number the substituents. The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

Question

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Answer 1

Question

Chapter 23, Problem 23.53SP

(a)

Interpretation Introduction

Interpretation:

The structure of the cyclooctane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

(b)

Interpretation Introduction

Interpretation:

The structure of the 1,1-dimethylcyclopentane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

(c)

Interpretation Introduction

Interpretation:

The structure of the 1,2,3,4-Tetramethylcyclobutane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

(d)

Interpretation Introduction

Interpretation:

The structure of the 4-Ethyl-1,1-dimethylcyclohexane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

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Which of the following cycloalkanes are capable of geometric (cis-trans) isomerism?Draw the cis and trans isomers.(a) 3-ethyl-1,1-dimethylcyclohexane (b) 1-ethyl-3-methylcycloheptane(c) 1-ethyl-3-methylcyclopentane (d) 1-cyclopropyl-2-methylcyclohexane

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Draw structures corresponding to the following IUPAC names: (a) 2-Chloro-3,3-đimethylhexane (c) 3-Bromo-3-ethylpentane (e) 4-sec-Butyl-2-chlorononane (b) 3,3-Dichloro-2-methylhexane (d) 1.1-Dibromo-4-isopropylcyclohexane () 1,1-Dibromo-4-tert-butylcyclohexane

Answer 2

Question

Chapter 23, Problem 23.53SP

(a)

Interpretation Introduction

Interpretation:

The structure of the cyclooctane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

(b)

Interpretation Introduction

Interpretation:

The structure of the 1,1-dimethylcyclopentane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

(c)

Interpretation Introduction

Interpretation:

The structure of the 1,2,3,4-Tetramethylcyclobutane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

(d)

Interpretation Introduction

Interpretation:

The structure of the 4-Ethyl-1,1-dimethylcyclohexane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

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Answer 3

Question

Chapter 23, Problem 23.53SP

(a)

Interpretation Introduction

Interpretation:

The structure of the cyclooctane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

(b)

Interpretation Introduction

Interpretation:

The structure of the 1,1-dimethylcyclopentane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

(c)

Interpretation Introduction

Interpretation:

The structure of the 1,2,3,4-Tetramethylcyclobutane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

(d)

Interpretation Introduction

Interpretation:

The structure of the 4-Ethyl-1,1-dimethylcyclohexane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 23, Problem 23.53SP

(a)

Interpretation Introduction

Interpretation:

The structure of the cyclooctane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

(b)

Interpretation Introduction

Interpretation:

The structure of the 1,1-dimethylcyclopentane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

(c)

Interpretation Introduction

Interpretation:

The structure of the 1,2,3,4-Tetramethylcyclobutane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

(d)

Interpretation Introduction

Interpretation:

The structure of the 4-Ethyl-1,1-dimethylcyclohexane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 23, Problem 23.53SP

(a)

Interpretation Introduction

Interpretation:

The structure of the cyclooctane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

(b)

Interpretation Introduction

Interpretation:

The structure of the 1,1-dimethylcyclopentane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

(c)

Interpretation Introduction

Interpretation:

The structure of the 1,2,3,4-Tetramethylcyclobutane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

(d)

Interpretation Introduction

Interpretation:

The structure of the 4-Ethyl-1,1-dimethylcyclohexane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

Answer 6

Chapter 23, Problem 23.53SP

(a)

Interpretation Introduction

Interpretation:

The structure of the cyclooctane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

Answer 7

Chapter 23, Problem 23.53SP

(a)

Interpretation Introduction

Interpretation:

The structure of the cyclooctane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The structure of the 1,1-dimethylcyclopentane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The structure of the 1,1-dimethylcyclopentane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The structure of the 1,2,3,4-Tetramethylcyclobutane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The structure of the 1,2,3,4-Tetramethylcyclobutane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The structure of the 4-Ethyl-1,1-dimethylcyclohexane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The structure of the 4-Ethyl-1,1-dimethylcyclohexane has to be determined.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo, if it is two cyclic structure combined then prefixed with bicyclo.

Naming of Cycloalkane using IUPAC nomenclature:

Use the Cycloalkane name as the parent.

Cycloalkanes are named as alkyl-substituted cycloalkanes rather than as cycloalkyl-substituted alkanes. There is no need to assign a number if there is one substituent on the ring.

Identify and number the substituents.

The group which has alphabetical priority should be numbered first and proceed around the ring in a direction in which the second substituent gets the lowest possible number.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 23.1 - Prob. 23.1P Ch. 23.1 - Prob. 23.2P Ch. 23.1 - Prob. 23.3P Ch. 23.1 - Prob. 23.4CP Ch. 23.2 - Prob. 23.5P Ch. 23.2 - Prob. 23.6P Ch. 23.3 - Prob. 23.7P Ch. 23.3 - Prob. 23.8P Ch. 23.3 - Prob. 23.9CP Ch. 23.4 - Prob. 23.10P

Solution Summary: The author explains that any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).

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