(a) Interpretation: The structural formula of hexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified. Concept introduction: Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group . Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

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Answer 1

Question

Chapter E, Problem E.40P

Interpretation Introduction

(a)

Interpretation:

The structural formula of hexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(b)

Interpretation:

The structural formula of neopentyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(c)

Interpretation:

The structural formula of pentafluoroethyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(d)

Interpretation:

The structural formula of cyclohexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

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Students have asked these similar questions

(a) What is a functional group? (b) What functional groupcharacterizes an alcohol? (c) Write a structural formula for1-pentanol, the alcohol derived from pentane by making asubstitution on one of the carbon atoms.

1. (a) Draw the structures of the eight isomeric pentyl alcohols, C3H11OH. (b) Name each by the IUPAC system and by the carbinol system. (c) Label each as primary, secondary, or tertiary, (d) Which one is isopentyl alcohol? tert-Pentyl alcohol? (e) Give the structure of a primary, a secondary, and a tertiary alcohol of the formula C,H13OH.

(a) Enter the IUPAC name for this alcohol: CH,CH,CHCH, ОН Classify it as a primary, secondary, or tertiary alcohol: (b) Enter the IUPAC name for this alcohol: CH,CHCH,CH,CHOH CH, ČH, Classify it as a primary, secondary, or tertiary alcohol:

Answer 2

Question

Chapter E, Problem E.40P

Interpretation Introduction

(a)

Interpretation:

The structural formula of hexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(b)

Interpretation:

The structural formula of neopentyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(c)

Interpretation:

The structural formula of pentafluoroethyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(d)

Interpretation:

The structural formula of cyclohexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

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Answer 3

Question

Chapter E, Problem E.40P

Interpretation Introduction

(a)

Interpretation:

The structural formula of hexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(b)

Interpretation:

The structural formula of neopentyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(c)

Interpretation:

The structural formula of pentafluoroethyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(d)

Interpretation:

The structural formula of cyclohexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

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Answer 4

Question

Chapter E, Problem E.40P

Interpretation Introduction

(a)

Interpretation:

The structural formula of hexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(b)

Interpretation:

The structural formula of neopentyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(c)

Interpretation:

The structural formula of pentafluoroethyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(d)

Interpretation:

The structural formula of cyclohexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

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Answer 5

Chapter E, Problem E.40P

Interpretation Introduction

(a)

Interpretation:

The structural formula of hexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(b)

Interpretation:

The structural formula of neopentyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(c)

Interpretation:

The structural formula of pentafluoroethyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Interpretation Introduction

(d)

Interpretation:

The structural formula of cyclohexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Answer 6

Chapter E, Problem E.40P

Interpretation Introduction

(a)

Interpretation:

The structural formula of hexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Answer 7

Chapter E, Problem E.40P

Interpretation Introduction

(a)

Interpretation:

The structural formula of hexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structural formula of neopentyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structural formula of neopentyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structural formula of pentafluoroethyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structural formula of pentafluoroethyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The structural formula of cyclohexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The structural formula of cyclohexyl alcohol is to be drawn. The primary alcohol, secondary alcohol, or tertiary alcohol is to be identified.

Concept introduction:

Trivial names of some alcohols are still in common use. They are derived from the trivial names of the alkane to which the hydroxyl group is attached. The first part of the name is derived from the trivial name of the root alkane. The second part is simply alcohol, indicating the functional group.

Depending on the type of carbon – primary, secondary, or tertiary – to which the hydroxyl group is attached, the alcohol is classified as a primary, secondary, or tertiary alcohol.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. E - Prob. E.1P Ch. E - Prob. E.2P Ch. E - Prob. E.3P Ch. E - Prob. E.4P Ch. E - Prob. E.5P Ch. E - Prob. E.6P Ch. E - Prob. E.7P Ch. E - Prob. E.8P Ch. E - Prob. E.9P Ch. E - Prob. E.10P

Solution Summary: The author explains the structural formula of hexyl alcohol, which is based on the trivial names of the alkane to which the hydroxyl group is attached.

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Chapter E Solutions