Organic Chemistry: Principles and Mechanisms (Second Edition)
Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
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Chapter E, Problem E.11P
Interpretation Introduction

(a)

Interpretation:

The structure of propane-1, 2-diol is to be drawn.

Concept introduction:

The structure of a molecule can be drawn from its IUPAC name. The IUPAC name consists of three parts. A root name specifies the number of carbons in the root chain or the size of the ring. The suffix, along with a specifier di, tri, etc. indicates the highest priority functional group, and the number and locations of its instances. Finally, any other functional groups are listed as prefixes with the locators.

Interpretation Introduction

(b)

Interpretation:

The structure of 1-methoxypentane-2, 3-diamine is to be drawn.

Concept introduction:

The structure of the compound can be drawn from its IUPAC name. The IUPAC name consists of three parts. A root name specifies the number of carbons in the root chain of the size of the ring. The suffix, along with a specifierdi, tri, etc. indicates the highest priority functional group, and the number and locations of its instances. Finally, the other functional groups are listed as prefixes with their locators.

Interpretation Introduction

(c)

Interpretation:

The structure of but-2-ene-1, 4-diol  is to be drawn.

Concept introduction:

The structure of a molecule can be drawn from its IUPAC name. The IUPAC name consists of three parts. A root name indicates the number of carbons in the root chain or the size of the ring. The suffix, along with a specifier di, tri, etc. indicates the highest priority functional group, and the number and locations of its instances. Finally, any other functional groups are listed as prefixes with their locators.

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Draw the structure of each of the following molecules. (a) hexanedinitrile; (b) (S)-4-nitroheptanenitrile; (c) 4,4-diethylcyclohexanecarbonitrile
Draw structures for the following molecules. (a) 3-bromo-2-nitropentane; (b) 2,2-dichloro-4,4,5-trinitroheptane;(c) 1,2,3,4-tetranitrobutane; (d) 6-iodo-1,2-difluorohexane
In each pair of compounds, which compound has a higher boiling point? Explain your reasoning.(a) octane or 2,2,3-trimethylpentane
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