EBK ORGANIC CHEMISTRY-PRINT COMPANION (
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Chapter 8.3, Problem 2CC

(a)

Interpretation Introduction

Interpretation: The bond-line structure of 3-isopropyl-2,4-dimethyl-2-pentene is to be interpreted.

Concept Introduction: The bond-line structure of a hydrocarbon represents the bond between carbon atoms by lines and C and H atoms are not shown as symbols. The intersection of lines shows the C atoms. The presence of a double or triple bond must be shown as multiple lines.

(b)

Interpretation Introduction

Interpretation: The bond-line structure of 4-ethyl-2-methyl-2-hexene is to be interpreted.

Concept Introduction: The bond-line structure of a hydrocarbon represents the bond between carbon atoms by lines and C and H atoms are not shown as symbols. The intersection of lines shows the C atoms. The presence of a double or triple bond must be shown as multiple lines.

(c)

Interpretation Introduction

Interpretation: The bond-line structure of 1,2-dimethylcyclobutene is to be interpreted.

Concept Introduction: The bond-line structure of a hydrocarbon represents the bond between carbon atoms by lines and C and H atoms are not shown as symbols. The intersection of lines shows the C atoms. The presence of a double or triple bond must be shown as multiple lines.

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C. Butane Measurements: Strain energy—anti conformation 10. C1–C2–C3 bond angle—anti 11. H–C1–C2 bond angle—anti 12. C1–C2–C3–H dihedral angle—anti 13. Strain energy—gauche conformation 14. C1–C2–C3 bond angle—gauche 15. C1–C2–C3–C4 dihedral angle—gauche 16. C1–C4 H–H distance—gauche 17. H–C1–C2–C3 dihedral angle—gauche 18.
C. Alkenes 1. Construct a model of ethene (C₂H4) by joining two carbon atoms with a double bond. Toggle between skeletal and full Lewis structures by clicking the C-H tool. Note the trigonal planar geometry of the bonds around each carbon atom, and that the carbon-carbon double bond has restricted rotation. Observe that the six atoms in ethene all lie in the same plane, and the double bond is a fixed geometry within the molecule. 2. Add a CH3- group to each of the doubly-bonded carbons to create a four-carbon alkene with the double bond between carbons 2 and 3. Note that the CH3- groups can be attached in two different ways: Both CH3- groups on the same side of the fixed geometry of the double bond. The two CH3- groups on opposite sides of the double bond. Click the broom to tidy up the structures; convert each to a ball-and-stick model clicking the 2D to 3D tool. Take scr prints of your MolView structures, showing both the Lewis structure and 3D model. ● Below, draw structures for…
Use the following Lewis diagram for 1,2-butadiene to answer the questions: H H 2 H -C- H 3 -H Remember that geometry refers to the geometry defined by the atoms, not the electron pairs. The geometry about atom C₁ is The ideal value of the C-C-C angle at atom C₂ is The geometry about atom C3 is degrees.
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