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- 8. Three compounds, G, H and J are structural isomers. They have the molecular formula C3H$O. Their chemical properties are given below: React with 2,4-dinitrophenylhydrazine to form yellow precipitate. G is resistant to oxidation. H is oxidised to L (C7H6O2) J is oxidised to M (C8H6O4) Write the structural formula of G, H, J, L and M. Outline one chemical test to distinguish between G and H.arrow_forwardWhat is structure? Chemical formula is C10H14O2arrow_forwarda. Use bond energies (see Table 3-3) to estimate H for the reaction of two molecules of glycine to form a peptide linkage. b. Would you predict S to favor the formation of peptide linkages between two molecules of glycine? c. Would you predict the formation of proteins to be a spontaneous process?arrow_forward
- Formaldehyde, H2C=O, is known to all biologists because of its usefulness as a tissue preservative. When pure, formaldehyde trimerizes to give trioxane, C3H6O3, which, surprisingly enough, has no carbonyl groups. Only one monobromo derivative (C3H5BrO3) of trioxane is possible. Propose a structure for trioxane.arrow_forwardWhen aniline, C6H5NH2(Kb=7.41010) , reacts with a strong acid, its conjugate acid, C6H5NH3+, is formed. Calculate the pH of a 0.100 M solution of C6H5NH3+ and compare it with the pH of acetic acid (Ka=1.86105) .arrow_forwardHow does the carbon-atom hybridization change when polyethylene is prepared from ethylene?arrow_forward
- Draw the Lewis structure of acetic acid, CH3CO2H, clearly indicating all non-bonding pairs of electrons. Even though nitrogen and phosphorus have the same number of valence electrons, nitrogen can only bond to chlorine four times forming NCl4+ but phosphorus can bond with chlorine five times forming PCl5. Explain. Draw all the isomers of C4H9Br, using bond-line formulas. Draw the Lewis structure of the nitrite ion, NO2–, clearly indicating resonance contributors as well as non-bonding pairs of electrons and formal charges, as relevant. Nitromethane is a polar molecule but contains 2 equal polar covalent bonds. Briefly explain why and draw a relevant 3-dimensional structure to show the overall dipole moment of the molecule. Draw all isomers of C6H12O that are aldehydes.arrow_forwardMTBE, Methyl tert-butyl ether, CH3OC(CH3)3, is used as an oxygen source in oxygenated gasolines. MTBE is manufactured by reacting 2-methylpropene with methanol.(a) Using Lewis structures, write the chemical equation representing the reaction.(b) What volume of methanol, density 0.7915 g/mL, is required to produce exactly 1000 kg of MTBE, assuming a 100% yield?arrow_forward7. Bel₂(aq) + Cu₂SO4(aq) → (5arrow_forward
- Polymers that can conduct electricity are called conducting polymers. Some polymers can be made semiconducting; others can benearly metallic. Polyacetylene is an example of a polymer that is a semiconductor. It can also be doped to increase its conductivity.Polyacetylene is made from acetylene in a reaction that looks simple but is actually tricky to do:H—C≡ C— HAcetylene [— CH=CH— ]n Polyacetylene(a) What is the hybridization of the carbon atoms, and the geometry around those atoms, in acetylene and in polyacetylene?(b) Write a balanced equation to make polyacetylene from acetylene.arrow_forwardC28H37N10O23P3 How do you draw this structure?arrow_forward1: In the sweetening MEROX process for kerosene the mercaptans are converted into (a) Sulpher (b) Disulphide (c) Hydrogen sulphide (d) None of these 2: Which of the following products contain maximum sulphur? (a) Diesel fuel (b) Fuel oil (c) Jet fuel (d) LPG 3: Which of the following petroleum product has a maximum C/H ratio (by weight)? (a) Light diesel oil (b) Fuel oil (c) Naphtha (d) Heating oil 4: Which of the following hydrocarbon are most desirable in gasoline? (a) Paraffins (b) Isoparaffins (c) Naphthenes (d) Aromatic 5: Octane no. of paraffins: (a) Remain constant with change in the number of carbon atoms (b) Increases with increase in the number of carbon atoms (c)Decreases with increase in the number of carbon atoms (d)None of the above 6: Which of the following hydrocarbons has a maximum octane number? (a) Benzene (b) Cyclohexane (c) Hexane (d) Iso-hexane 7: Which of the following petroleum products has a minimum flashpoint? (a)Gasoline (b) Kerosene (c) Fuel oil (d) Heating…arrow_forward
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