Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 7, Problem 7.15P
Interpretation Introduction
Interpretation:
The methyl acetylene/allene mixture is prepared from propene using in the laboratory method has to be explained.
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Write a balanced chemical equation for the reaction of ethene with oxygen.
O a. C2H4(g) + 302(g) → 2CO2(g) + 2H2O(g)
O b. 2C2H2(g) + 502(g) → 4CO2(g) + 2H2O(g)
O c. CH4(g) + 2O2(g) → CO2(g) + 2H2O(g)
O d. C2H4(g) + 202(g) → 2CO2(g) + 2H2(g)
O e. 2C2H6(g) + 702(g) →> 4CO2(g) + 6H2O(g)
(5) One of Prof Cunningham's former students wrote his doctoral dissertation about a new
technology to clean up soil contaminated by certain types of chemicals. One of the
chemicals we tested in the lab was 1,2,4,5-tetrachlorobenzene (TECB).
(a) Draw the chemical structure of 1,2,4,5-tetrachlorobenzene.
(b) When we started working on the project, we thought maybe TeCB would be de-
stroyed according to first-order kinetics, but we weren't sure. Below are two tables
of actual data that the student collected in the laboratory. The two data sets were
collected under different experimental conditions. For each of the two experiments,
determine if the disappearance of TeCB is zero-order, first-order, second-order, or
something else. Specify the value of the rate constant (ko, k1, or k2, as appropriate).
Be sure to give the right units of k!
Table 1: Concentration of TECB vs. time, experiment 1
time (min)
Conc. (mg/L)
10
20
30
45
5.0
2.93
2.06
0.61
0.28
0.057
Table 2: Concentration of TECB…
Write the steps for formation of tetrachloromethane (CCl4) from the reaction of methane with Cl2 + hn.
Chapter 7 Solutions
Organic Chemistry
Ch. 7.2 - Write the IUPAC name of each compound.Ch. 7.2 - Write the common name of each alkyne.Ch. 7.5 - Prob. 7.3PCh. 7.7 - Draw a structural formula for a hydrocarbon with...Ch. 7.7 - Hydration of 2-pentyne gives a mixture of two...Ch. 7.9 - Prob. 7.6PCh. 7 - Prob. 7.7PCh. 7 - Show how to prepare each alkyne from the given...Ch. 7 - Prob. 7.9PCh. 7 - Complete each acid-base reaction and predict...
Ch. 7 - Draw structural formulas for the major product(s)...Ch. 7 - Draw the structural formula of the enol formed in...Ch. 7 - Prob. 7.13PCh. 7 - Prob. 7.14PCh. 7 - Prob. 7.15PCh. 7 - Show reagents and experimental conditions you...Ch. 7 - Show reagents and experimental conditions you...Ch. 7 - Show how to convert 1-butyne to each of these...Ch. 7 - Prob. 7.19PCh. 7 - Show reagents and experimental conditions to bring...Ch. 7 - Show reagents to bring about each conversion.Ch. 7 - Propose a synthesis for (Z)-9-tricosene...Ch. 7 - Propose a synthesis of each compound starting from...Ch. 7 - Show how to prepare each compound from 1-heptene....Ch. 7 - Prob. 7.25PCh. 7 - Prob. 7.26PCh. 7 - Following is the structural formula of the...Ch. 7 - The standard procedure for synthesizing a compound...Ch. 7 - Prob. 7.29PCh. 7 - Prob. 7.30PCh. 7 - Using your reaction roadmap as a guide, show how...Ch. 7 - Using your reaction roadmap as a guide, show how...Ch. 7 - Using your reaction roadmap as a guide, show how...Ch. 7 - Using your reaction roadmap as a guide, show how...Ch. 7 - Prob. 7.35P
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