Organic Chemistry
Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 7, Problem 7.9P
Interpretation Introduction

Interpretation:

For the given equilibrium reaction, the ratio between more stable isomer to less stable isomer has to be calculated.

Concept Introduction:

Standard reaction Gibbs energy and equilibrium constant:

The relationship between Gibbs energy and equilibrium constant is given by,

  ΔrGo=-RTlnKwhere, ΔrGo-standardreactionGibbsenergy R-gasconstant T-temperatureandK-equilibriumconstant

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If a catalyst could be found that would establish an equilibrium between 1,2-butadiene and 2-butyne, what would be the ratio of the more stable isomer to the less stable isomer at 25°C? CH,=C=CHCH, CH,C=CCH, AG° = -16.7 kJ (-4.0 kcal)/mol
∆H° values obtained for a series of similar reactions are one set of experimental data used to determine the relative stability of alkenes. Explain how the following data suggest that cis-but-2-ene is more stable than but-1-ene (Section 12.3A).
Mark the correct statements about the structural features of alkenes and alkynes. *         A- Free rotation is not possible around a double or triple bond.         B- A triple bond is shorter and stronger than a double bond.         C- A pi-bond can only form by overlap of p-orbitals on adjacent atoms if these atoms are from the same element.         D- The pi-bond in an alkene is weaker than the sigma bond because the sideways overlap of p-orbitals is less than the head-to-head overlap of sp² hybrid orbitals.         E- All the bond angles in an alkyne are 180°.

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Organic Chemistry

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