Concept explainers
(a)
Interpretation:
The differences between the first step in reactions of
Concept introduction:
Addition Reaction: It is defined as
In addition reaction of
Regioselective reaction: They are reactions which contain more than one product which are actually molecules with same molecular formula but different in the way they are connected and among those products only one product is major.
Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.
Carbocation: it is carbon ion that bears a positive charge on it.
Leaving group: it is a fragment that leaves from a substrate with a pair of electrons via
Carbocation stability order:
(b)
Interpretation:
The product and reason for attack of
Concept introduction:
Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.
In addition reaction of alkenes when two substituents are placed on same side of
Regioselective reaction: They are reactions which contain more than one product which are actually molecules with same molecular formula but different in the way they are connected and among those products only one product is major.
Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the more substitution position of carbon-carbon double bond.
Trending nowThis is a popular solution!
Chapter 6 Solutions
Organic Chemistry (8th Edition)
- Draw the structure of the major organic product you would expect from the reaction of 1-bromopropane with Nal. You do not have to explicitly draw H atoms. • Draw only the product derived from 1-bromopropane. Do not draw other organic by-products.arrow_forwardCompounds such as aldehyde and ketone may cause a hydration reaction, which is a nucleophilic addition reaction, by an acid or base catalyst. What's the role of the base catalyst?arrow_forward2-Methyl-2-butene reacts with HBr in the presence of peroxide to give a. a secondary alkyl bromide. b. a primary alkyl bromide. c. a tertiary alkyl bromide. d. a vicinal dibromide.arrow_forward
- 4. Draw the structure and name the first ten (10) members of Acid Halides using bromine as the halide.arrow_forwardConsider the molecule nitrobenzene, C6H5NO2. a. Draw a full Lewis structure of nitrobenzene, showing ALL formal charges and lone pairs. b. In an electrophilic aromatic substitution reaction, is nitrobenzene an ortho/para director, or a meta director? Use a resonance form to explain why.arrow_forward4.arrow_forward
- 5. Consider the reaction below and answer the following questions + OH + H₂O a. Draw in ALL missing lone pair electrons as well as electron movement arrows on the reactant side Identify the nucleophile and electrophile on the reactant side b. c. Identify which side of the equilibrium will dominate. d. Draw resonance structures for the organic compound on the product side CHEM 241-Group05. Ormord d ****arrow_forwardB) 21. What is a major product of the conjugate addition reaction shown in the box? 1. Base 130 (= neutralization) Ph CO,Et 1305 130 4d.arrow_forwardBased on the characteristics of the carbonyl group (C = O), what reactions or transformations take place with aldehydes and ketones? a. nucleophilic additions by oxygenb. electrophilic additions by carbon attackc. nucleophilic additions by carbon attackd. electrophilic substitutions through a carbocationand. acid-base because carbonyl can act as both an electrophile and a nucleophilearrow_forward
- Please provide structures for the given reactions NN, OO, and PParrow_forward1. What is the bond angle in carbon tetrachloride? 2. What is the product of the reaction of pent-2-ene with Cl2? 3.Which statement is correct? * A. The bond length increases when the difference between the electronegativity of the atoms is higher B. The bond length increases when the number when there is an increase in pi bonds. C. Increasing the bond polarity increases the bond length. D. Sp2 has shorter bond length that sp. 4. How many moles of O2 gas is theoretically needed for 1 mole of hexane? 5. What is the MOST LIKELY product of the reaction of pent-1-ene with HCL? 6. Which one creates a sigma bond? * A. 2 pz atomic orbitals B. 2 py atomic orbitals C. 2 px atomic orbitals D. none of these 7.How many hydrogen atoms are there in trans-1-bromo-2-methylcyclohexane? 8.arrow_forwardThe reaction will produce which of the following results? A. Decolorization of a brown solution B. Production of a brown precipitate C. Acidification of a solution D. Production of fumes What property is expected in the organic product in the reaction? A.Solubility in alcohol is increased B.Polarity of the compound is decreased C.A cis-configuration is expected. D. The electrophile becomes a nucleophile. Which among the reactants is a reducing agent? A.Alkene B.MnO4, anion C.Water D. All of the Abovearrow_forward
- EBK A SMALL SCALE APPROACH TO ORGANIC LChemistryISBN:9781305446021Author:LampmanPublisher:CENGAGE LEARNING - CONSIGNMENT