Package: Loose Leaf Organic Chemistry with Connect 2-year Access Card
5th Edition
ISBN: 9781259729980
Author: SMITH
Publisher: MCG
expand_more
expand_more
format_list_bulleted
Question
Chapter 6, Problem 6.57P
Interpretation Introduction
Interpretation: The reason for the different
Concept introduction: The change in Gibbs free energy is represented by
If the
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Esterication is the reaction of a carboxylic acid (RCOOH) with an alcohol (R'OH) to form an ester (RCOOR') with loss of water. Equation [1] is an example of an intermolecular esterication reaction. Equation [2] is an example of an intramolecular esterication reaction; that is, the carboxylic acid and alcohol are contained in the same starting material, forming a cyclic ester as product. The equilibrium constants for both reactions are given. Explain why Keq is different for these two apparently similar reactions.
Ester formation and ester hydrolysis are exactly the same reaction only written in reverse.
General reaction of ester formation:
H*, heat
R—с—он + Н—о—R'
R—с—о-R' + H,O
carboxylic
acid
alcohol
carboxylic
or phenol
ester
General reaction of ester hydrolysis:
||
R—с—OR' + H—оН
R—с—оН +R—ОH
ester
carboxylic
acid
alcohol
or phenol
What determines which direction the reaction proceeds and what actually forms?
o the boiling point of the carboxylic acid
o the presence (or absence) of heat as well as the concentration of reactants and products
o the molecular weight of reactants and products
o the presence (or absence) of heat as well as the catalyst
Write the chemical equation for the decarboxylation of 2-methyl-propanoic acid.
Which is formula of this rule of reaction?
Chapter 6 Solutions
Package: Loose Leaf Organic Chemistry with Connect 2-year Access Card
Ch. 6 - Problem 6.1 Classify each transformation as...Ch. 6 - Prob. 6.2PCh. 6 - Problem 6.3 By taking into account...Ch. 6 - Problem 6.4 Use curved arrows to show the movement...Ch. 6 - Problem 6.5 Follow the curved arrows and draw the...Ch. 6 - Prob. 6.6PCh. 6 - Problem 6.7 Use the values in Table 6.2 to...Ch. 6 - Prob. 6.8PCh. 6 - aWhich Keq corresponds to a negative value of G,...Ch. 6 - Given each of the following values, is the...
Ch. 6 - Given each of the following values, is the...Ch. 6 - The equilibrium constant for the conversion of the...Ch. 6 - Prob. 6.13PCh. 6 - For a reaction with H=40kJ/mol, decide which of...Ch. 6 - For a reaction with H=20kJ/mol, decide which of...Ch. 6 - Draw an energy diagram for a reaction in which the...Ch. 6 - Prob. 6.17PCh. 6 - Prob. 6.18PCh. 6 - Problem 6.19 Consider the following energy...Ch. 6 - Draw an energy diagram for a two-step reaction,...Ch. 6 - Which value if any corresponds to a faster...Ch. 6 - Prob. 6.22PCh. 6 - Problem 6.23 For each rate equation, what effect...Ch. 6 - Prob. 6.24PCh. 6 - Identify the catalyst in each equation. a....Ch. 6 - Draw the products of homolysis or heterolysis of...Ch. 6 - Explain why the bond dissociation energy for bond...Ch. 6 - Classify each transformation as substitution,...Ch. 6 - Prob. 6.29PCh. 6 - 6.30 Draw the products of each reaction by...Ch. 6 - 6.31 (a) Add curved arrows for each step to show...Ch. 6 - Prob. 6.32PCh. 6 - Prob. 6.33PCh. 6 - Prob. 6.34PCh. 6 - Calculate H for each reaction. a HO+CH4CH3+H2O b...Ch. 6 - Homolysis of the indicated CH bond in propene...Ch. 6 - Prob. 6.37PCh. 6 - Prob. 6.38PCh. 6 - 6.39. a. Which value corresponds to a negative...Ch. 6 - Prob. 6.40PCh. 6 - For which of the following reaction is S a...Ch. 6 - Prob. 6.42PCh. 6 - Prob. 6.43PCh. 6 - 6.44 Consider the following reaction: .
Use curved...Ch. 6 - Prob. 6.45PCh. 6 - Draw an energy diagram for the Bronsted-Lowry...Ch. 6 - Prob. 6.47PCh. 6 - Indicate which factors affect the rate of a...Ch. 6 - Prob. 6.49PCh. 6 - 6.50 The conversion of acetyl chloride to methyl...Ch. 6 - Prob. 6.51PCh. 6 - Prob. 6.52PCh. 6 - The conversion of (CH3)3Cl to (CH3)2C=CH2 can...Ch. 6 - 6.54 Explain why is more acidic than , even...Ch. 6 - Prob. 6.55PCh. 6 - Prob. 6.56PCh. 6 - Prob. 6.57PCh. 6 - Although Keq of equation 1 in problem 6.57 does...Ch. 6 - Prob. 6.59P
Knowledge Booster
Similar questions
- What functional group distinguishes each of the following hydrocarbon derivatives? a. halohydrocarbons b. alcohols c. ethers d. aldehydes e. ketones f. carboxylic acids g. esters h. amines Give examples of each functional group. What prefix or suffix is used to name each functional group? What are the bond angles in each? Describe the bonding in each functional group. What is the difference between a primary, secondary, and tertiary alcohol? For the functional groups in ah, when is a number required to indicate the position of the functional group? Carboxylic acids are often written as RCOOH. What does COOH indicate and what does R indicate? Aldehydes are sometimes written as RCHO. What does CHO indicate?arrow_forwardArrange the following compounds in decreasing order of boiling point. Highest Boiling Point 1 Ethanoic acid (carboxylic acid) 2 Ethanamide (amide) 3 propan-1-ol (alcohol) 4 n-butane (alkane) Lowest Boiling Pointarrow_forwardIdentify each organic compound as an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and provide a name for the compound. H2C-CH, CHarrow_forward
- Identify each organic compound as an alkane, alkene, alkyne, aromatic hydrocarbon, alcohol, ether, aldehyde, ketone, carboxylic acid, ester, or amine, and provide a name for the compound. CH3 b. CH;-CH2-CH-CH2-0-CH2-CH;arrow_forwardClassify each of the following molecules as alcohol,aldehyde, ketone, carboxylic acid, amine, or ether.arrow_forwardPrepare CH3COOC2HS, ethyl acetate, using ethyl alcohol. Write the chemical reaction.arrow_forward
- Write the chemical equation for a pentanoate ion acting as base when it reacts with hydrochloric acid (HCI). Which is formula of this rule of reaction?arrow_forwardLSaxw_byUjt4NKKTEABPFImknTAVIxeSATH3-MO9AEbrFOXuga ponse TUIse The structure of glycogen is very similar to that of amylose Secondary alcohols are readily oxidized with common oxidizing agents to carboxylic acids Amines react with strong acids such as HCI, to form ammonium salts In general, oils come from animal sources and fats from vegetable sources Amines are weak bases, they are considerably more basic than alcohols, and water Carboxylic acids are less acidic than alcohols Steroids are lipids that do not contain fatty acids Alkylamines have boiling points are higher than those of alkanes, but lower than those of alcohols 4- Tio druck & 1 8. 9. Y ! OX { Hi J K : NI pause O O O O O O O O OOarrow_forwardModified true or false. If statement is true, write TRUE, otherwise change the italicized words/phrases in the statement. Cations in hard water like Ca2+ and Mg2+ can form precipitates with carboxylates in soaps, reducing their efficiency as cleansing agents. If an ester is to be prepared with ethanol, using at least 70% ethanol could maximize the yield.arrow_forward
- Complete the organic reaction.arrow_forwardwhat is the possible names of this compound, i mean if -OH bonded to first, second or third Carbon atomarrow_forwardWrite the chemical equation for the reaction of ethanoic acid with N-methylethanamine. Which is formula of this rule of reaction?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning