Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 5, Problem 6E
Draw the Lewis Structures for
(a)
(b)
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Draw the Lewis structures for CO2 and CO, and predict the number of σ and π bonds for each molecule.(a) CO2(b) CO
Cyanogen (CN)2 is known as pseodohalogen because it has some properties like halogens. It is composed of two CN’s joined together.(i) Draw the Lewis structure for all the possible combination for (CN)2.(ii) Calculate the formal charge and determine which one of the structures that you have drawn is most stable.(iii) For the stable structure, determine the geometry around the two central atoms.(iv) For the stable structure, draw the dipole arrows for the bonds.(v) Base on the stable structure, determine the polarity of molecule and state your reason.
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Chapter 5 Solutions
Chemistry Atoms First2e
Ch. 5 - Explain how σ and bonds are similar and how they...Ch. 5 - Use valence bond theory to explain the bonding in...Ch. 5 - Use valence bond theory to explain the bonding in...Ch. 5 - How many and bonds are present in the molecule...Ch. 5 - A friend tell you N2 has three bonds due to...Ch. 5 - Draw the Lewis Structures for CO2andCO , and...Ch. 5 - Why is the concept of hybridization required in...Ch. 5 - Give the shape that describes each hybrid orbital...Ch. 5 - Explain why a carbon atom cannot from five bonds...Ch. 5 - What is the hybridization of the central atom in...
Ch. 5 - A molecule with the formula AB3 could have one of...Ch. 5 - Methionine, CH3SCH2CH2CH(NH2)CO2H, is an amino...Ch. 5 - Sulfuric acid is manufactured by a series of...Ch. 5 - Two important industrial chemicals,...Ch. 5 - Analysis of a compound indicates that it contains...Ch. 5 - Consider nitrous acid, HNO2(HONO). (a) Write a...Ch. 5 - Strike-anywhere matches contain a layer of KC1O3...Ch. 5 - Identify the hybridization of each carbon atom in...Ch. 5 - Write Lewis structures for NF3andPF5 . On the...Ch. 5 - In addition to NF3, two other fluoro derivatives...Ch. 5 - The bond energy of a C-C single bond averages...Ch. 5 - For the carbonate ion, CO32 -, draw all of the...Ch. 5 - A useful solvent that will dissolve salts as well...Ch. 5 - For the molecule allene, H2C=C=CH2, give the...Ch. 5 - Identify the hybridization of the central atom in...Ch. 5 - Describe the molecular geometry and hybridization...Ch. 5 - For each of the following molecules, indicate the...Ch. 5 - For each of the following structures, determine...Ch. 5 - Draw the orbital diagram for carbon in CO2 showing...Ch. 5 - Sketch the distribution of electron density in the...Ch. 5 - How are the following similar, and how do they...Ch. 5 - If molecular orbitals are created by combining...Ch. 5 - Can a molecule with an odd number of electrons...Ch. 5 - Can a molecule with an even number of electrons...Ch. 5 - Why are bonding molecular orbital lower in energy...Ch. 5 - Calculate the bond order for an ion with this...Ch. 5 - Explain why an electron in the bonding molecular...Ch. 5 - Predict the valence electron molecular orbital...Ch. 5 - Determine the bond order of each member of the...Ch. 5 - For the first ionizations energy for an N2...Ch. 5 - Compare the atomic and molecular orbitaI diagrams...Ch. 5 - Which of the period 2 homonuclear diatomic...Ch. 5 - A friend tells you that the 2s orbital for...Ch. 5 - True or false: Boron contains 2s22p1 valence...Ch. 5 - What charge would be needed on F2 to generate an...Ch. 5 - Predict whether the MO diagram for S2 would show...Ch. 5 - Explain why N22+ is diamagnetic, while O24+, which...Ch. 5 - Using the MO diagrams, predict the bond order for...
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- Acetylene 1C2H22 and nitrogen 1N22 both contain a triplebond, but they differ greatly in their chemical properties.(a) Write the Lewis structures for the two substances. (b) Byreferring to Appendix C, look up the enthalpies of formationof acetylene and nitrogen. Which compound is more stable?(c) Write balanced chemical equations for the completeoxidation of N2 to form N2O51g2 and of acetylene to formCO21g2 and H2O1g2. (d) Calculate the enthalpy of oxidationper mole for N2 and for C2H2 (the enthalpy of formationof N2O51g2 is 11.30 kJ>mol). (e) Both N2 and C2H2 possesstriple bonds with quite high bond enthalpies (Table 8.3).Calculate the enthalpy of hydrogenation per mole for bothcompounds: acetylene plus H2 to make methane, CH4;nitrogen plus H2 to make ammonia, NH3.arrow_forward2(a) Provide the Lewis structures for both CH3OH and C2H3Cl. 2(b) What is the largest bond angle among all the bond angles in CH3OH and C2H3Cl? Listthe three atoms making this largest bond angle, and estimate the value of the angle.2(c) What intermolecular forces are present(i) between CH3OH molecules?(ii) between C2H3Cl molecules?arrow_forwardDetermine the electron-group arrangement, molecular shape, and ideal bond angle(s) for each of the following:(a) SO₄²⁻(b) NO₂⁻(c) PHarrow_forward
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