General, Organic, and Biological Chemistry (3rd Edition)
3rd Edition
ISBN: 9780134042428
Author: Laura D. Frost, S. Todd Deal
Publisher: PEARSON
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Chapter 5, Problem 5.60AP
Acetylsalicylic acid (aspirin) can be synthesized by combining salicylic add and acetic acid through a condensation reaction. The —OH group from phenol on the salicylic acid condenses with the
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Acetylsalicylic acid (aspirin) can be synthesized by combining salicylic acid and acetic acid through a condensation reaction. The-OH group from phenol on the salicylic acid
condenses with the carboxylic acid group of acetic acid forming acetylsalicylic acid
OH
OH
HO
CH₂
Condensation
reaction
Acetylsalicylic acid (aspirin) can be synthesized by combining salicylic acid and acetic acid through a condensation reaction. The −OH−OH group from phenol on the salicylic acid condenses with the carboxylic acid group of acetic acid forming acetylsalicylic acid. Draw the structure of acetylsalicylic acid.
Salicylic acid is added into a test tube, followed by methanol and sulfuric acid as the catalyst. It is heated for 10-15 minutes and poured into a beaker with crushed ice. This is the esterification of Oil of wintergreen. Write the complete reaction equation and describe the odor of the reactants (salicylic acid and methanol) and the products (oil of wintergreen).
Chapter 5 Solutions
General, Organic, and Biological Chemistry (3rd Edition)
Ch. 5 - When vinegar (CH3COOH) and baking soda (NaHCO3)...Ch. 5 - In your own words, define free energy change, G....Ch. 5 - Classify the following as exothermic or...Ch. 5 - Prob. 5.4PPCh. 5 - Prob. 5.5PPCh. 5 - Classify the following as spontaneous or...Ch. 5 - Prob. 5.7PPCh. 5 - Prob. 5.8PPCh. 5 - Prob. 5.9PPCh. 5 - Prob. 5.10PP
Ch. 5 - a. How does increasing the temperature increase...Ch. 5 - a. Describe activation energy for a chemical...Ch. 5 - Why does the rate of a chemical reaction decrease...Ch. 5 - Prob. 5.14PPCh. 5 - Enzymes increase the rate of a biological chemical...Ch. 5 - Prob. 5.16PPCh. 5 - Prob. 5.17PPCh. 5 - Prob. 5.18PPCh. 5 - Categorize the following reactions as synthesis,...Ch. 5 - Categorize the following reactions as synthesis,...Ch. 5 - Prob. 5.21PPCh. 5 - Prob. 5.22PPCh. 5 - Write the products and balance the following...Ch. 5 - Prob. 5.24PPCh. 5 - Prob. 5.25PPCh. 5 - List the differences between general chemical...Ch. 5 - Are the substances shown in italics undergoing...Ch. 5 - Prob. 5.28PPCh. 5 - Prob. 5.29PPCh. 5 - Prob. 5.30PPCh. 5 - Prob. 5.31PPCh. 5 - Prob. 5.32PPCh. 5 - Prob. 5.33PPCh. 5 - Prob. 5.34PPCh. 5 - Prob. 5.35PPCh. 5 - Prob. 5.36PPCh. 5 - Prob. 5.37PPCh. 5 - Write the main product of hydration for the...Ch. 5 - Methane (a.k.a. natural gas) can react with oxygen...Ch. 5 - Prob. 5.40APCh. 5 - Which reaction occurs at a faster rate, an...Ch. 5 - Prob. 5.42APCh. 5 - Prob. 5.43APCh. 5 - Two curves for the same reaction are shown in the...Ch. 5 - Prob. 5.45APCh. 5 - Draw and label a reaction energy diagram for an...Ch. 5 - Prob. 5.47APCh. 5 - Prob. 5.48APCh. 5 - Write the products that would result from the...Ch. 5 - Prob. 5.50APCh. 5 - Prob. 5.51APCh. 5 - Prob. 5.52APCh. 5 - Prob. 5.53APCh. 5 - Prob. 5.54APCh. 5 - Prob. 5.55APCh. 5 - Identify the reactant that is oxidized and the...Ch. 5 - Prob. 5.57APCh. 5 - Write the products of the following reactions:Ch. 5 - Prob. 5.59APCh. 5 - Acetylsalicylic acid (aspirin) can be synthesized...Ch. 5 - Prob. 5.61APCh. 5 - Fill in the missing organic produce for the...Ch. 5 - Prob. 5.63APCh. 5 - Prob. 5.64APCh. 5 - How do low-carb diets work? We store glucose...Ch. 5 - Prob. 5.66CPCh. 5 - Prob. 5.67CPCh. 5 - Prob. 5.68CPCh. 5 - Prob. 5.69CPCh. 5 - Which reaction has the larger activation energy?Ch. 5 - Prob. 1IA.2QCh. 5 - A catalyst speeds up a chemical reaction by...Ch. 5 - Prob. 1IA.4QCh. 5 - Examine your sketch from question 3. Does a...Ch. 5 - Prob. 1IA.6QCh. 5 - Prob. 2IA.1QCh. 5 - Prob. 2IA.2QCh. 5 - Prob. 2IA.3QCh. 5 - One of the reactions in the data set is a single...Ch. 5 - Prob. 2IA.5QCh. 5 - Categorize the following reactions as a synthesis,...Ch. 5 - Prob. 3IA.1QCh. 5 - Prob. 3IA.2QCh. 5 - Prob. 3IA.3QCh. 5 - Prob. 3IA.4QCh. 5 - Prob. 3IA.5QCh. 5 - Prob. 1ICCh. 5 - Find out how unsaturated fats are saturated and...
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- Write a chemical equation that involves water as a reactant for the formation of the a. water free radical b. hydroxyl free radicalarrow_forwardA student is asked to prepare methyl salicylate from salicylic acid and methanol. How would the student have to set up this reaction?arrow_forwarda drop of aniline is added to 2.5 ml distilled water. zonrox is added to the mixture. write the reaction for the oxidation of aniline.arrow_forward
- Synthesis of Benzoic Acid Is the reaction between sodium benzoate and hydrochloric acid exothermic or endothermic? What type of reaction is this? What are the products? Why is ice cold water rather than room temperature or warm water used to wash the remainder of the benzoic acid out of the beaker?arrow_forwardWhat are the roles of methyl salicylate and sulfuric acid in the synthesis of salicylic acid?arrow_forwardOdour given when butyric acid react with isoamyl. Odour given when acetic acid react with isoamyl. Odour given when salicylic acid reacts with methanol Odour given when ethanol acid react with cinnamicarrow_forward
- 22 The oxidation of glucose with a weak oxidizing agent (Benedict) results in the formation of a primary alcohol on carbon #1 (CH,OH) a carboxylic acid at carbon #6 (COOH) O a bydrogenated carbon at carbon #1 (CH,OH) a carboxylic acid at carbon #1 (COOH) a carboxylic acid at both carbons #1 and #6 (COOH)arrow_forwardWhat method that can be used to change Lemon Myrtle oil into Rose oilarrow_forwardThe synthesis of aspirin is a common esterification reaction. It is based on the balanced reaction given in the background of this lab. Calculate the theoretical yield of aspirin given that 3.52-mL of acetic anhydride was reacted with 0.9457-g of salicylic acid. Synthesized solids often need to be purified prior to use. What are some ways you could purify synthesized aspirin in the laboratory? Explain why you would not expect to smell acetic acid after the addition of sodium bicarbonate to the esterification reaction mixture.arrow_forward
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