(a) Interpretation: The structure of polystyrene, the polymer obtained from the free-radical polymerization of styrene is to be drawn. Concept introduction: The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

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Answer 1

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Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 5, Problem 5.46AP

Interpretation Introduction

(a)

Interpretation:

The structure of polystyrene, the polymer obtained from the free-radical polymerization of styrene is to be drawn.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Interpretation Introduction

(b)

Interpretation:

The way by which the structure of the polymer product differ from the one in part (a) if a few percent of 1,4−divinylbenzene is added in the mixture is to be stated.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

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Question 5 (this is one question I really need help with)Methyl methacrylate is polymerized by free radical polymerization at 70 oC to form long polymer chains.(a) If benzoyl peroxide is used as the initiator for the polymerization of methyl methacrylate please write the chemical structures of the compounds formed during the initiation step of the polymerization. What would happen if the reaction is not heated at 70 oC?(b) Write the chemical structures of the polymers formed during the propagation and termination steps of the polymerization.(c) Write the trade name of the polymer formed by the polymerization of methyl methacrylate and two of its common applications.(d) If a polymer with degree of polymerization 100 is synthesized during the reaction, determine its molecular weight (in g/mol). (e) If from the polymerization of methyl methacrylate a polymer of 20 mg is produced, calculate the moles of the monomer units in the sample. Also, given that methyl methacrylate is a liquid,…

One common type of cation exchange resin is prepared by polymerization of a mixture containing styrene and 1,4-divinylbenzene . The polymer is then treated with concentrated sulfuric acid to sulfonate a majority of the aromatic rings in the polymer. Q.) Show the product of sulfonation of each benzene ring.

(d) Another variation on this type of polymer is used in hair gels. In these, the polymer chains are cross-linked by a compound known as pentaerythritol. но- OH но- OH pentaerythritol ( By what type of chemicat reaction are the cross-links in this polymer formed? (i) it is important that the gel should be easily washed out of hair What is it about the structure of the polymer that allows this to happen?

Answer 2

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Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 5, Problem 5.46AP

Interpretation Introduction

(a)

Interpretation:

The structure of polystyrene, the polymer obtained from the free-radical polymerization of styrene is to be drawn.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Interpretation Introduction

(b)

Interpretation:

The way by which the structure of the polymer product differ from the one in part (a) if a few percent of 1,4−divinylbenzene is added in the mixture is to be stated.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

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Answer 3

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 5, Problem 5.46AP

Interpretation Introduction

(a)

Interpretation:

The structure of polystyrene, the polymer obtained from the free-radical polymerization of styrene is to be drawn.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Interpretation Introduction

(b)

Interpretation:

The way by which the structure of the polymer product differ from the one in part (a) if a few percent of 1,4−divinylbenzene is added in the mixture is to be stated.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

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Answer 4

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 5, Problem 5.46AP

Interpretation Introduction

(a)

Interpretation:

The structure of polystyrene, the polymer obtained from the free-radical polymerization of styrene is to be drawn.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Interpretation Introduction

(b)

Interpretation:

The way by which the structure of the polymer product differ from the one in part (a) if a few percent of 1,4−divinylbenzene is added in the mixture is to be stated.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Expert Solution & Answer

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Answer 5

Chapter 5, Problem 5.46AP

Interpretation Introduction

(a)

Interpretation:

The structure of polystyrene, the polymer obtained from the free-radical polymerization of styrene is to be drawn.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Interpretation Introduction

(b)

Interpretation:

The way by which the structure of the polymer product differ from the one in part (a) if a few percent of 1,4−divinylbenzene is added in the mixture is to be stated.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Answer 6

Chapter 5, Problem 5.46AP

Interpretation Introduction

(a)

Interpretation:

The structure of polystyrene, the polymer obtained from the free-radical polymerization of styrene is to be drawn.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Answer 7

Chapter 5, Problem 5.46AP

Interpretation Introduction

(a)

Interpretation:

The structure of polystyrene, the polymer obtained from the free-radical polymerization of styrene is to be drawn.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The way by which the structure of the polymer product differ from the one in part (a) if a few percent of 1,4−divinylbenzene is added in the mixture is to be stated.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The way by which the structure of the polymer product differ from the one in part (a) if a few percent of 1,4−divinylbenzene is added in the mixture is to be stated.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 5 - Prob. 5.1P Ch. 5 - Prob. 5.2P Ch. 5 - Prob. 5.3P Ch. 5 - Prob. 5.4P Ch. 5 - Prob. 5.5P Ch. 5 - Prob. 5.6P Ch. 5 - Prob. 5.7P Ch. 5 - Prob. 5.8P Ch. 5 - Prob. 5.9P Ch. 5 - Prob. 5.10P

Solution Summary: The author explains that the structure of polystyrene, obtained from the free-radical polymerization, is shown in Figure 3.

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