(a) Interpretation: The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated. Concept introduction: The general steps involved in the free-radical chain mechanism are as follows: • The first step is the initiation step. • The next step is the propagation step. • The third step is the termination step.

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Answer 1

Question

Chapter 5, Problem 5.21P

Interpretation Introduction

(a)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

Interpretation Introduction

(b)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

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3-Chloro-2-methylpropene reacts with sodium methoxide in methanol to form 3-methoxy-2-methylpropene. For each of the following changes in the reaction conditions, state whether the reaction rate would increase, decrease, or remain the same. Explain your reasoning. In some cases the identity of the major organic product would be expected to change; in such cases, give the expected major product. (a) dimethyl sulfoxide (DMSO) is used in place of methanol (b) methanol is used by itself without sodium methoxide (c) 1-chloro-2,2,-dimethylpropane is used in place of 3-chloro-2-methylpropene

Show the chemical reaction on how to convert cyclopentene into these compounds. (a) 1,2-dimethylcyclopropane (b) Cyclopentanol (c) Iodocyclopentane (d) Cyclopentane.

3-Chloro-2-methylpropene reacts with sodium methoxide in methanol to form 3-methoxy-2-methylpropene. For each of the following changes in the reaction conditions, state whether the reaction rate would increase, decrease, or remain the same. Explain your reasoning. In some cases the identity of the major organic product would be expected to change; in such cases, give the expected major product. (a) the same quantities of reagents are dissolved in half the volume of methanol (b) 3-bromo-2-methylpropene is used in place of 3-chloro-2-methylpropene (c) sodium methanethiolate (CH3SNa) is used in place of of sodium methoxide

Answer 2

Question

Chapter 5, Problem 5.21P

Interpretation Introduction

(a)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

Interpretation Introduction

(b)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

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Answer 3

Question

Chapter 5, Problem 5.21P

Interpretation Introduction

(a)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

Interpretation Introduction

(b)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

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Answer 4

Question

Chapter 5, Problem 5.21P

Interpretation Introduction

(a)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

Interpretation Introduction

(b)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

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Answer 5

Chapter 5, Problem 5.21P

Interpretation Introduction

(a)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

Interpretation Introduction

(b)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

Answer 6

Chapter 5, Problem 5.21P

Interpretation Introduction

(a)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

Answer 7

Chapter 5, Problem 5.21P

Interpretation Introduction

(a)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The product formed by the reaction of given alkene with hydrogen bromide in the presence of hydrogen peroxide and explanation corresponding to the dominant product if more than one product formed is to be stated.

Concept introduction:

The general steps involved in the free-radical chain mechanism are as follows:

• The first step is the initiation step.

• The next step is the propagation step.

• The third step is the termination step.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 5 - Prob. 5.1P Ch. 5 - Prob. 5.2P Ch. 5 - Prob. 5.3P Ch. 5 - Prob. 5.4P Ch. 5 - Prob. 5.5P Ch. 5 - Prob. 5.6P Ch. 5 - Prob. 5.7P Ch. 5 - Prob. 5.8P Ch. 5 - Prob. 5.9P Ch. 5 - Prob. 5.10P

Solution Summary: The author explains the steps involved in the free-radical chain mechanism. The bromine free radical attacks the molecule of 1-pentene.

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