To drraw: The structure of ( S ) − 2 − iodobutane . Interpretation: The structure of ( S ) − 2 − iodobutane is to be drawn. Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

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Answer 1

Question

Chapter 5, Problem 5.34SP

(a)

Interpretation Introduction

To drraw: The structure of (S)−2−iodobutane.

Interpretation: The structure of (S)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

(b)

Interpretation Introduction

To determine: The specific rotation of (R)−2−iodobutane.

Interpretation: The specific rotation of (R)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

(c)

Interpretation Introduction

To determine: The percentage composition of a mixture of (R) and (S)−2−iodobutane.

Interpretation: The percentage composition of a mixture of (R) and (S)−2−iodobutane is to be calculated on the basis of the given information.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

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5. The specific rotation of (S)-2-iodobutane is +15.90°. Draw the structure of (S)-2- iodobutane, predict the specific rotation of (R)-2-iodobutane, and determine the percentage composition of a mixture of (R)- and (S)-2-iodobutane with a specific rotation of -7.95°.

The specific rotation of (S)-carvone (at 20 degrees) is +61. A chemist prepared a mixture of (R)-carvone and its enantiomer, and this mixture had an observed rotation of -55. (a) What is the specific rotation of (R)-carvone at 20 degrees?

The specific rotation of (S)-carvone (at 20 degrees) is +61. A chemist prepared a mixture of (R)-carvone and its enantiomer, and this mixture had an observed rotation of -55. (a) What is the specific rotation of (R)-carvone at 20 degrees? (b) What percentage of the mixture is (S)- carvone? Choose from the following options. 1. 90% (S)-carvone and 10% (R) 2. 10% (S)-carvone and 90% (R) 3. 95% (S)-carvone and 5% (R) 4. 5% (S)- carvone and 95% (R)

Answer 2

Question

Chapter 5, Problem 5.34SP

(a)

Interpretation Introduction

To drraw: The structure of (S)−2−iodobutane.

Interpretation: The structure of (S)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

(b)

Interpretation Introduction

To determine: The specific rotation of (R)−2−iodobutane.

Interpretation: The specific rotation of (R)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

(c)

Interpretation Introduction

To determine: The percentage composition of a mixture of (R) and (S)−2−iodobutane.

Interpretation: The percentage composition of a mixture of (R) and (S)−2−iodobutane is to be calculated on the basis of the given information.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

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Answer 3

Question

Chapter 5, Problem 5.34SP

(a)

Interpretation Introduction

To drraw: The structure of (S)−2−iodobutane.

Interpretation: The structure of (S)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

(b)

Interpretation Introduction

To determine: The specific rotation of (R)−2−iodobutane.

Interpretation: The specific rotation of (R)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

(c)

Interpretation Introduction

To determine: The percentage composition of a mixture of (R) and (S)−2−iodobutane.

Interpretation: The percentage composition of a mixture of (R) and (S)−2−iodobutane is to be calculated on the basis of the given information.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

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Answer 4

Question

Chapter 5, Problem 5.34SP

(a)

Interpretation Introduction

To drraw: The structure of (S)−2−iodobutane.

Interpretation: The structure of (S)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

(b)

Interpretation Introduction

To determine: The specific rotation of (R)−2−iodobutane.

Interpretation: The specific rotation of (R)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

(c)

Interpretation Introduction

To determine: The percentage composition of a mixture of (R) and (S)−2−iodobutane.

Interpretation: The percentage composition of a mixture of (R) and (S)−2−iodobutane is to be calculated on the basis of the given information.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

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Answer 5

Chapter 5, Problem 5.34SP

(a)

Interpretation Introduction

To drraw: The structure of (S)−2−iodobutane.

Interpretation: The structure of (S)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

(b)

Interpretation Introduction

To determine: The specific rotation of (R)−2−iodobutane.

Interpretation: The specific rotation of (R)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

(c)

Interpretation Introduction

To determine: The percentage composition of a mixture of (R) and (S)−2−iodobutane.

Interpretation: The percentage composition of a mixture of (R) and (S)−2−iodobutane is to be calculated on the basis of the given information.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 6

Chapter 5, Problem 5.34SP

(a)

Interpretation Introduction

To drraw: The structure of (S)−2−iodobutane.

Interpretation: The structure of (S)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 7

Chapter 5, Problem 5.34SP

(a)

Interpretation Introduction

To drraw: The structure of (S)−2−iodobutane.

Interpretation: The structure of (S)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 8

(b)

Interpretation Introduction

To determine: The specific rotation of (R)−2−iodobutane.

Interpretation: The specific rotation of (R)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 9

(b)

Interpretation Introduction

To determine: The specific rotation of (R)−2−iodobutane.

Interpretation: The specific rotation of (R)−2−iodobutane is to be drawn.

Concept introduction: The enantiomers of a chiral compound can be named the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 10

(c)

Interpretation Introduction

To determine: The percentage composition of a mixture of (R) and (S)−2−iodobutane.

Interpretation: The percentage composition of a mixture of (R) and (S)−2−iodobutane is to be calculated on the basis of the given information.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 11

(c)

Interpretation Introduction

To determine: The percentage composition of a mixture of (R) and (S)−2−iodobutane.

Interpretation: The percentage composition of a mixture of (R) and (S)−2−iodobutane is to be calculated on the basis of the given information.

Concept introduction: The enantiomers of a chiral compound can be named with the help of right hand and left hand configuration. In fisher projection, chiral carbon atom is represented by a cross. When two groups on a fisher projection are interchanged, the configuration of chiral carbon also changes from (R) to (S) or (S) to (R).

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 5.2 - Determine whether the following objects are chiral...Ch. 5.2A - Prob. 5.2P Ch. 5.2B - Prob. 5.3P Ch. 5.2B - Prob. 5.4P Ch. 5.2C - Prob. 5.5P Ch. 5.3 - Prob. 5.6P Ch. 5.3 - Prob. 5.7P Ch. 5.4D - Prob. 5.8P Ch. 5.4D - Prob. 5.9P Ch. 5.4D - Prob. 5.10P

Solution Summary: The author explains how the enantiomers of a chiral compound can be named with the help of right hand and left hand configuration.

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