Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
9th Edition
ISBN: 9781292151229
Author: Wade, LeRoy G.
Publisher: PEARSON
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Chapter 5.4D, Problem 5.9P
Interpretation Introduction

Interpretation: The specific rotation of epinephrine is to be calculated on the basis of given information.

Concept introduction: Physical properties of a compound like boiling point, density affects the angular rotation of polarized light by a chiral compound. The concentration of the compound affects the rotation of polarized light in Polarimeter. The rotation is also dependent upon the length of the cell and optical activity of the compound.

To determine: The specific rotation of epinephrine on the basis of given information.

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A solution of 2.0 g of (+)-glyceraldehyde, HOCH2CHOHCHO, in 10.0 mL of water was placed in a 100-mm cell. Using the sodium D line, a rotation of +1.74° was found at 25 °C. Determine the specific rotation of (+)@glyceraldehyde.
If a solution of a compound (50.0 g/100 mL of solution) has a measured rotation of +150 in a 2 dm tube, the specific rotation is: O +15 O +20 O +35 O +8
Guanosine has a maximum absorbance of 275 nm. ϵ275= 8400M−1cm−1 and the path length is 1 cm. Using a spectrophotometer, you find the that A275=0.70. What is the concentration of guanosine?
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