The more stable chair conformation of β-D-glucopyranose is to be drawn. Concept introduction: For substituted cyclohexane, the isomer having substituents at equatorial position is most stable. Preferably, the bulkier groups are more stable at equatorial position than axial due to reduced 1-3 diaxial butane gauche interaction.

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Answer 1

Question

Chapter 4, Problem 4.67P

Interpretation Introduction

Interpretation:

The more stable chair conformation of β-D-glucopyranose is to be drawn.

Concept introduction:

For substituted cyclohexane, the isomer having substituents at equatorial position is most stable. Preferably, the bulkier groups are more stable at equatorial position than axial due to reduced 1-3 diaxial butane gauche interaction.

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Answer 2

Question

Chapter 4, Problem 4.67P

Interpretation Introduction

Interpretation:

The more stable chair conformation of β-D-glucopyranose is to be drawn.

Concept introduction:

For substituted cyclohexane, the isomer having substituents at equatorial position is most stable. Preferably, the bulkier groups are more stable at equatorial position than axial due to reduced 1-3 diaxial butane gauche interaction.

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Answer 3

Question

Chapter 4, Problem 4.67P

Interpretation Introduction

Interpretation:

The more stable chair conformation of β-D-glucopyranose is to be drawn.

Concept introduction:

For substituted cyclohexane, the isomer having substituents at equatorial position is most stable. Preferably, the bulkier groups are more stable at equatorial position than axial due to reduced 1-3 diaxial butane gauche interaction.

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Answer 4

Question

Chapter 4, Problem 4.67P

Interpretation Introduction

Interpretation:

The more stable chair conformation of β-D-glucopyranose is to be drawn.

Concept introduction:

For substituted cyclohexane, the isomer having substituents at equatorial position is most stable. Preferably, the bulkier groups are more stable at equatorial position than axial due to reduced 1-3 diaxial butane gauche interaction.

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Answer 5

Chapter 4, Problem 4.67P

Interpretation Introduction

Interpretation:

The more stable chair conformation of β-D-glucopyranose is to be drawn.

Concept introduction:

For substituted cyclohexane, the isomer having substituents at equatorial position is most stable. Preferably, the bulkier groups are more stable at equatorial position than axial due to reduced 1-3 diaxial butane gauche interaction.

Answer 6

Chapter 4, Problem 4.67P

Interpretation Introduction

Interpretation:

The more stable chair conformation of β-D-glucopyranose is to be drawn.

Concept introduction:

For substituted cyclohexane, the isomer having substituents at equatorial position is most stable. Preferably, the bulkier groups are more stable at equatorial position than axial due to reduced 1-3 diaxial butane gauche interaction.

Answer 7

Chapter 4, Problem 4.67P

Interpretation Introduction

Interpretation:

The more stable chair conformation of β-D-glucopyranose is to be drawn.

Concept introduction:

For substituted cyclohexane, the isomer having substituents at equatorial position is most stable. Preferably, the bulkier groups are more stable at equatorial position than axial due to reduced 1-3 diaxial butane gauche interaction.

Answer 8

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Answer 9

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Answer 11

Ch. 4 - Prob. 4.1P Ch. 4 - Prob. 4.2P Ch. 4 - Prob. 4.3P Ch. 4 - Prob. 4.4P Ch. 4 - Prob. 4.5P Ch. 4 - Prob. 4.6P Ch. 4 - Prob. 4.7P Ch. 4 - Prob. 4.8P Ch. 4 - Prob. 4.9P Ch. 4 - Prob. 4.10P

Solution Summary: The author explains that the most stable conformation of -D-glucopyranose is drawn by placing the substituents at equatorial positions.

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Chapter 4 Solutions