Essential Organic Chemistry, Global Edition
Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
Question
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Chapter 3.7, Problem 25P

(a)

Interpretation Introduction

Interpretation:

Between the given molecules the compound that can form hydrogen bonding has to be identified.

Concept introduction:

Hydrogen bonding: It is an electromagnetic attraction between polar molecules with hydrogen bonds to a larger atom (for example oxygen or nitrogen) atoms.

This type of bonding does not sharing of electrons in a covalent bond; it is attraction between the positive and negative poles of charges atoms.

Polarity: It is a well separation of electric charge leading to a molecule or chemical compounds having an electrical dipole moment. Generally the polar molecules must contain polar bonds due to a different in electronegative between the bonded atoms.

(b)

Interpretation Introduction

Interpretation:

The compound that forms hydrogen bonds with a solvent such as ethanol has to be predicted.

Concept introduction:

Hydrogen bonding: It is a electromagnetic attraction between polar molecules with hydrogen bonds to a larger atom (for example oxygen or nitrogen) atoms.

This type of bonding does not sharing of electrons in a covalent bond; it is attraction between the positive and negative poles of charges atoms.

Polarity: It is a well separation of electric charge leading to a molecule or chemical compounds having an electrical dipole moment. Generally the polar molecules must contain polar bonds due to a different in electronegative between the bonded atoms.

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Students have asked these similar questions
Which of the following compounds forms hydrogen bonds between its molecules? 1. CH3CH2OCH2CH2OH  2. CH3CH2N(CH3)2  3. CH3CH2CH2CH2Br 4. CH3CH2CH2NHCH3  5. CH3CH2CH2COOH   6. CH3CH2CH2CH2F
a. Which of the following compounds forms hydrogen bonds between its molecules? 1. CH3CH2OCH2CH2OH 2. CH3CH2N(CH3)2 3. CH3CH2CH2CH2Br 4. CH3CH2CH2NHCH3 5. CH3CH2CH2COOH 6. CH3CH2CH2CH2F b. Which of the preceding compounds forms hydrogen bonds with a solvent such as ethanol?
In each pair of compounds, pick the one with the higher boiling point. Explain your reasoning.a. CH3OH or CH3SHb. CH3OCH3 or CH3CH2OHc. CH4 or CH3CH3

Chapter 3 Solutions

Essential Organic Chemistry, Global Edition

Ch. 3.3 - Draw a condensed and a skeletal structure for the...Ch. 3.3 - What is each compounds systematic name?Ch. 3.4 - Prob. 17PCh. 3.4 - Give two names for each of the following alkyl...Ch. 3.5 - Are the following compounds primary, secondary, or...Ch. 3.5 - Name the following amines and tell whether they...Ch. 3.5 - Draw the structures and provide systematic names...Ch. 3.6 - Predict the approximate size of the following bond...Ch. 3.7 - What is the smallest straight-chain alkane that is...Ch. 3.7 - Prob. 24PCh. 3.7 - Prob. 25PCh. 3.7 - Prob. 26PCh. 3.7 - List the compounds in each set from highest...Ch. 3.8 - Rank the following compounds in each set from most...Ch. 3.8 - In which solvent would cyclohexane have the lowest...Ch. 3.8 - Prob. 30PCh. 3.9 - Prob. 31PCh. 3.9 - a. Draw the three staggered conformations and the...Ch. 3.9 - a. Draw the most stable conformation of pentane...Ch. 3.11 - Draw 1,2,3,4,5,6-hexachlorocyclohexane with a. all...Ch. 3.12 - At any one time, would you expect there to be more...Ch. 3.13 - Prob. 36PCh. 3 - a. How many hydrogens does an alkane with 17...Ch. 3 - Prob. 2PCh. 3 - Draw a condensed structure and a skeletal...Ch. 3 - Prob. 39PCh. 3 - Prob. 40PCh. 3 - Which of the following represents a cis isomer?Ch. 3 - a. How many primary carbons does each of the...Ch. 3 - Name the following amines and tell whether they...Ch. 3 - Which of the following conformers of isobutyl...Ch. 3 - What is each compounds name? a. CH3CH2CH2OCH2CH3Ch. 3 - Draw the structural formula for an alkane that has...Ch. 3 - Which has a. the higher boiling point:...Ch. 3 - Ansaid and Motrin belong to the group of drugs...Ch. 3 - A student was given the structural formulas of...Ch. 3 - Which of the following conformers has the highest...Ch. 3 - Prob. 51PCh. 3 - Draw skeletal structures for the following: a....Ch. 3 - Prob. 53PCh. 3 - For rotation about the C-3 8 C-4 bond of...Ch. 3 - Prob. 55PCh. 3 - What is each compounds systematic name?Ch. 3 - Draw the two chair conformers for each of the...Ch. 3 - Draw the nine constitutional isomers with...Ch. 3 - Prob. 59PCh. 3 - Prob. 60PCh. 3 - Prob. 61PCh. 3 - Using Newman projections, draw the most stable...Ch. 3 - For each of the following disubstituted...Ch. 3 - Prob. 64PCh. 3 - Prob. 65PCh. 3 - What is each compounds systematic name?Ch. 3 - Prob. 67PCh. 3 - Bromine is a larger atom than chlorine, but the...Ch. 3 - Prob. 69PCh. 3 - Prob. 70PCh. 3 - a. Draw a potential energy diagram for rotation...
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