An Introduction to Thermal Physics
1st Edition
ISBN: 9780201380279
Author: Daniel V. Schroeder
Publisher: Addison Wesley
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Chapter 3.1, Problem 6P
To determine
The formula for the energy for the system with only quadratic degrees of freedom in terms of temperature.
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The volume V of an ideal gas varies directly with the temperature T and inversely with the pressure P. If a cylinder of 50 liters contains oxygen at a temperature of 200 K and a pressure of 5 atmospheres, what would the gas pressure be if the volume was changed to 30 liters and the temperature raised to 240 K?
Problem 1:
In statistical mechanics, the internal energy of an ideal gas is given by:
N.
aNkB
2/3
(3NKB
U = U(S,V) =
е
where a is a constant.
1- Show that the variation of the internal energy is given by:
2
dS -
\3V
2
dU =
dV
\3NkB
2- Using the fundamental relation of thermodynamic dU = T.ds – p. dV, show that the equation of
state PV = nRT follows from the first expression of U.
A (1.1x10^1) liter bottle is filled with nitrogen (N2) at STP (Standard Temperature
and Pressure is 1 atm and 273 K) and closed tight. If the temperature is raised to
100° C, what will be the new pressure in SI units to two significant figures.
Note: Your answer is assumed to be reduced to the highest power possible.
Your Answer:
x10
Answer
Chapter 3 Solutions
An Introduction to Thermal Physics
Ch. 3.1 - Use Table 3.1 to compute the temperature of solid...Ch. 3.1 - Use the definition of temperature to prove the...Ch. 3.1 - Figure 3.3 shows graphs of entropy vs. energy for...Ch. 3.1 - Can a miserly system, with a concave-up...Ch. 3.1 - Prob. 5PCh. 3.1 - Prob. 6PCh. 3.1 - Prob. 7PCh. 3.2 - Prob. 8PCh. 3.2 - In solid carbon monoxide, each CO molecule has two...Ch. 3.2 - An ice cube (mass 30 g) at 0C is left sitting on...
Ch. 3.2 - In order to take a nice warm bath, you mix 50...Ch. 3.2 - Estimate the change in the entropy of the universe...Ch. 3.2 - When the sun is high in the sky, it delivers...Ch. 3.2 - Experimental measurements of the heat capacity of...Ch. 3.2 - Prob. 15PCh. 3.2 - A bit of computer memory is some physical object...Ch. 3.3 - Prob. 17PCh. 3.3 - Prob. 18PCh. 3.3 - Prob. 19PCh. 3.3 - Prob. 20PCh. 3.3 - Prob. 21PCh. 3.3 - Prob. 22PCh. 3.3 - Prob. 23PCh. 3.3 - Prob. 24PCh. 3.3 - Prob. 25PCh. 3.3 - Prob. 26PCh. 3.4 - What partial-derivative relation can you derive...Ch. 3.4 - A liter of air, initially at room temperature and...Ch. 3.4 - Sketch a qualitatively accurate graph of the...Ch. 3.4 - As shown in Figure 1.14, the heat capacity of...Ch. 3.4 - Experimental measurements of heat capacities are...Ch. 3.4 - A cylinder contains one liter of air at room...Ch. 3.4 - Prob. 33PCh. 3.4 - Polymers, like rubber, are made of very long...Ch. 3.5 - Prob. 35PCh. 3.5 - Prob. 36PCh. 3.5 - Prob. 37PCh. 3.5 - Suppose you have a mixture of gases (such as air,...Ch. 3.6 - Prob. 39P
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