An Introduction to Thermal Physics
An Introduction to Thermal Physics
1st Edition
ISBN: 9780201380279
Author: Daniel V. Schroeder
Publisher: Addison Wesley
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Chapter 3.1, Problem 2P

Use the definition of temperature to prove the zeroth law of thermodynamics, which says that if system A is thermal equilibrium with system B, and system B is in thermal equilibrium with system C, then system A is in thermal equilibrium with system C. (If this exercise seems totally pointless to you, you’re in good company: Everyone considered this “law” to be completely obvious until 1931, when Ralph Fowler pointed out that it was an unstated assumption of classical thermodynamics.)

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In a certain physical system, there are two energy states available to a particle: the ground state with energy E₁ = 0 eV, and the excited state with energy E₂ = 1.5 eV. The system is in thermal equilibrium at a temperature T = 300 K. Calculate the Gibbs factor (also known as the Boltzmann factor) for the excited state . Give your answer to two decimal places.
The volume V of an ideal gas varies directly with the temperature T and inversely with the pressure P. If a cylinder of 50 liters contains oxygen at a temperature of 200 K and a pressure of 5 atmospheres, what would the gas pressure be if the volume was changed to 30 liters and the temperature raised to 240 K?
A bottle of volume V = 0.15 m³ contains helium gas (a monatomic gas) at a pressure p = 722,266 Pa (Pascal = N/m² and temperature T = 300 K. Calculate a numerical value for the internal energy U of this gas. Include units in your answer, using Sl units (m for meters, kg for kilograms, s for seconds, J for joules, K for kelvin, etc.). Write your answer as an exponential as described in the instructions.

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An Introduction to Thermal Physics

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The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY