GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
11th Edition
ISBN: 9780134193601
Author: Petrucci
Publisher: PEARSON
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Chapter 3, Problem 126SAE
Interpretation Introduction

Interpretation:

The oxidation state of Mn in MgMnO4 should be assigned.

Concept introduction:

The chemical reaction in which both oxidation and reduction process takes place is known as redox reaction. In this reaction, transfer of electrons takes place among the elements.

Oxidation is the process in which either loss of electrons, oxidation number increases, or loss of hydrogen atoms takes place. An element is oxidized, when oxidation number increases.

Reduction is the process in which either gain of electrons, oxidation number decreases, or gain of hydrogen atoms takes place. An element is reduced, when oxidation number decreases.

Oxidation state is also known as oxidation number. It is defined as the numbers which are assign to the elements in a chemical combination and number represents the electrons which an atom can share, lose or gain to form chemical bonding with an atom of another element.

Therefore, transfer of electrons refers to the oxidation state.

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b. (i) (ii) A green solid has the empirical formula FeBr3·5NH3 H₂O. Upon reaction with an excess of aqueous AgNO3 it is found that 1 mole of the solid precipitates 3 moles of AgBr. Heating the green solid leads to loss of 1 mole of H₂O to yield a blue solid with the same ratio of Fe:Br:NH3 as found in the green solid. The reaction of 1 mole of the blue solid with excess of aqueous AgNO3 produces 2 moles of AgBr. Draw and name the octahedral green and blue complexes. An octahedral complex having the formula [M(dien)(NH3)(OH₂)F] has a total of 15 isomers. In the sum formula "dien" represents the tridentate diethylenetriamine ligand, which can adopt meridional or facial coordination modes. Draw structures of 8 possible isomers, clearly showing any pairs of enantiomers. The tridentante ligand may be abbreviated as below for simplicity. H₂N : = ΝΗ NH :NH2 N diethylenetriamine (dien) N N
Complete and balance the following equations: (a) Mg;N2(s) + H20(I) (b) NO(8) + O2(8) → (c) N2O5(8) + H20(I) (d) NH3(aq) + H*(aq) (e) N,H4(1) + O2(8) Which ones of these are redox reactions?
2. (Balance the equation) FeCl+NaOH>Fe(OH);+Nacl

Chapter 3 Solutions

GENERAL CHEMISTRY-MOD.MASTERINGCHEM.

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