Concept explainers
(a)
Interpretation:
The formula of the product formed by the reaction of propene with
Concept introduction:
Reaction of unsaturated compounds (
(b)
Interpretation:
The formula of the product formed by the reaction of propene with
Concept introduction:
Reaction of alkenes with chlorine gas
(c)
Interpretation:
The formula of the product formed by the reaction of propene with
Concept introduction:
Reaction of alkenes with hydrogen halide
Addition of hydrogen halide to unsymmetrical alkene occurs in accordance with Markovnikov’s rule. It states that addition of hydrogen halide to unsymmetrical alkene occurs in such a manner that hydrogen attaches to the carbon having more number of carbon and halide part goes to the carbon with less number of hydrogen atoms.
(d)
Interpretation:
The formula of the product formed by the reaction of propene with
Concept introduction:
Reaction of alkenes with water in the presence of acid is an example of hydration reaction to give corresponding alcohol.
Addition of water to unsymmetrical alkene occurs in accordance with Markovnikov’s rule. It states that the addition of water to unsymmetrical alkene occurs in such a manner that hydrogen attaches to the carbon having more number of carbon and hydroxide part goes to the carbon with less number of hydrogen atoms.
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GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
- TRUE OR FALSE (a) A functional group is a group of atoms in an organic molecule that undergoes a predictable set of chemical reactions. (b) The functional group of an alcohol, an aldehyde, and a ketone have in common the fact that each contains a single oxygen atom. (c) A primary alcohol has one —OH group, a secondary alcohol has two —OH groups, and a tertiary alcohol has three —OH groups. (d) There are two alcohols with the molecular formula C3H8O. (e) There are three amines with the molecular formula C3H9N. (f) Aldehydes, ketones, carboxylic acids, and esters all contain a carbonyl group. (g) A compound with the molecular formula of C3H6O may be either an aldehyde, a ketone, or a carboxylic acid. (h) Bond angles about the carbonyl carbon of an aldehyde, a ketone, a carboxylic acid, and an ester are all approximately 109.5°. (i) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O. (j) The molecular formula of the smallest carboxylic…arrow_forwarda) True or false: Alkenes undergo addition reactions andaromatic hydrocarbons undergo substitution reactions.(b) Using condensed structural formulas, write the balancedequation for the reaction of 2-pentene with Br2and name the resulting compound. Is this an addition ora substitution reaction? (c) Write a balanced chemicalequation for the reaction of Cl2 with benzene to make paradichlorobenzenein the presence of FeCl3 as a catalyst. Isthis an addition or a substitution reaction?arrow_forwardIllustrate the chemical structural formula for 3-methyl-3-ethylpentane. (b) Identify its chemical family as an isomer. (c) Provide the balanced chemical reaction equation for the combustion of one mole of this fuel with an equivalence ratio of ϕ=0.735arrow_forward
- This question is about the chemistry of alkenes, which are unsaturated hydrocarbons. (a) State what is meant by the term unsaturated as applied to a hydrocarbon. (1) (b) An organic compound, X, is an unsaturated hydrocarbon with molecular formula CH₂. (i) Draw the displayed formulae and give the names of two molecules with molecular formula C₂H, which are E/Z isomers. (3) Isomer 1 Isomer 2 Name: Name:arrow_forward5.Write the structural formula of the ester that, when hydrolyzed, would yield the following:(a) methanol and propanoic acid(b) 1-octanol and acetic acid (c) ethanol and butanoic acidarrow_forward(i) Draw the structural formula of compounds L, M, N and P (ii) Name the type of chemical reaction for the formation of compound N.arrow_forward
- Write the line-angle formula for the organic compounds (a) propene; (b) heptan-1-ol;(c) chloroacetic acid; (d) hexanoic acid.arrow_forward(a) Calculate the standard enthalpy change for the combustion of 1 mol of benzene, C6H61l2, to CO21g2 and H2O1l2.(b) Compare the quantity of heat produced by combustion of 1.00 g propane with that produced by 1.00 g benzene.arrow_forwardGive the molecular formula of a hydrocarbon containingsix carbon atoms that is (a) a cyclic alkane, (b) a cyclicalkene, (c) a linear alkyne, (d) an aromatic hydrocarbon.arrow_forward
- 5. Give the structural formulae and name the functional groups of the following compounds. (a) 3-chlorobut-1-ene (b) butanedioic acid Name the functional group: (c) propanamide Name the functional group: (d) 3-methylbutanal Name the functional group: Name the functional group:arrow_forwardAlcohols A, B, and C all have the composition C4H10O. Molecules of alcohol A contain a branched carbon chain and can be oxidized to an aldehyde; molecules of alcohol B contain a linear carbon chain and can be oxidizedto a ketone; and molecules of alcohol C can be oxidized to neither an aldehyde nor a ketone. Write the Lewis structures of these molecules.arrow_forwardPropane, C3H8, is a hydrocarbon that is commonly used as a fuel.(a) Write a balanced equation for the complete combustion of propane gas.(b) Calculate the volume of air at 25 °C and 1.00 atmosphere that is needed to completely combust 25.0 grams of propane. Assume that air is 21.0 percent O2 by volume. (Hint:use the information that 1.00 L of air at 25 °C and 1.00 atm contains 0.275 g of O2 per liter.)(c) The heat of combustion of propane is −2,219.2 kJ/mol. Calculate the heat of formation, ΔH°f of propane given that ΔH°f of H2O(l) = −285.8 kJ/mol and ΔH°f of CO2(g) = −393.5 kJ/mol. (d) Assuming that all of the heat released in burning 25.0 grams of propane is transferred to 4.00 kilograms of water, calculate the increase in temperature of the water.arrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning