Concept explainers
(a)
Interpretation:
The formula of the product obtained upon dissolution of
Concept introduction:
Nucleophilic substitution reaction
(b)
Interpretation:
The reaction mechanism of the given nucleophilic substitution reaction is to be determined.
Concept introduction:
Nucleophilic substitution reaction
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GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
- 34) The product formed by the reaction of toluene with chlorine in the presence of sunlight is: (a) o-chlorotoluene (b) 2,4-dichlorotoluene (c) p-chlorotoluene (d) Benzylchloridearrow_forward(1) Write a complete chemical equation showing reactants, products, and catalysts needed (if any) for the following reaction and (2) Draw and name the organic compound found in every reaction. (a) Complete hydrogenation of 2-Methylhexa-1,5-diene (b) Complete halogenation (Br2) of 3-Ethyl-2,2-dimethylhept-3-ene (c) Reaction of (4E)-2.4-Dimethylhexa-1,4-diene with a mole of water (d) Reaction of cis-3,3-Dimethyl-4-propylocta-1,5-diene with two mole of HBr (e) Reaction of trans-1-Bromo-3-chlorocyclopentane with potassium hydroxide (f) Formation of Gilman reagent using isopropyl bromide (g) Ozonolysis of 3,3-Dimethyloct-4-yne (h) Complete halogenation (Cl2) of 3-Ethyl-5-methyl-1,6,8-decatriyne (i) Partial hydrogenation using Lindlar's Catalyst 2,2,5,5-Tetramethylhex-3-yne (i) Reaction of 3.4-Dimethylcyclodecyne with sodium amidearrow_forwardKetene, H2C=C=O, is an important industrial chemical. Predict the products that would be formed when ketene reacts with **hint: Markovnikov addition occurs. (a) ethanol (b) acetic acid (c) ethylamine.arrow_forward
- (a) Draw the four isomers of C₅H₁₀O that can be oxidizedto an aldehyde. (b) Draw the three isomers of C₅H₁₀O that canbe oxidized to a ketone. (c) Draw the isomers of C₅H₁₀O that cannot be easily oxidized to an aldehyde or ketone. (d) Name any isomer that is an alcohol.arrow_forwardEthers (general formula R—O—R)have many important uses. Until recently,methyl tert-butyl ether (MTBE, right)was used as an octane booster and fueladditive for gasoline. It increases the oxy-gen content of the fuel, which reducesCO emissions. MTBE is synthesized bythe catalyzed reaction of 2-methylpropene with methanol.(a) Write a balanced equation for the synthesis of MTBE. (Hint:Alcohols add to alkenes similarly to the way water does.)(b) If the government required that auto fuel mixtures contain2.7% oxygen by mass to reduce CO emissions, how many gramsof MTBE would have to be added to each 100. g of gasoline?(c) How many liters of MTBE would be in each liter of fuel mix-ture? (The density of both gasoline and MTBE is 0.740 g/mL.)(d) How many liters of air (21% O₂ by volume) are needed at24C and 1.00 atm to fully combust 1.00 L of MTBE?arrow_forward1. (a) Draw structures of the seven isomeric alkynes of formula C6H10 - (b) Give the IUPAC and derived name of each. (c) Indicate which ones will react with Ag' or Cu(NH3)2.arrow_forward
- (b) NABH, CH3 COCH,CH3 CH3CH2OH (c)arrow_forwardIdentify any carbon atoms that change hybridization and the change in hybridization during the reactions in (a) 2-butene is treated with water in dilute acid(b) ethanol is dehydrated to yield ethenearrow_forwardWhich products are formed when hydrobromic acid is added to (a) trans-2-hexene, (b) 2-methyl- 2-pentene, and (c) 4-methylcyclohexene, and how many regioisomers can be formed in each case?arrow_forward
- (i) Draw the structural formula of compounds L, M, N and P (ii) Name the type of chemical reaction for the formation of compound N.arrow_forwardWrite structural formulas for compounds that meet the following descriptions:(a) An alkene, C6H12, that cannot have cis–trans isomersand whose longest chain is 5 carbons long(b) An alkene with a chemical formula of C10H12 that hascis–trans isomers and contains a benzene ring.arrow_forward7. The general formula for noncyclic alkenes is: (a) CH-2 (b) CH (c) CH2 (d) CH (e) CH,arrow_forward
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