General Chemistry: Principles and Modern Applications (11th Edition)
11th Edition
ISBN: 9780132931281
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
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Chapter 24, Problem 67SAE
In your own words, describe the following terms or symbols: (a) coordination number, (b)
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(b) Consider the oxalate (ox) ligand and answer the following questions:(i) Draw the structure of the ox ligand.(ii) Identify all the donor atoms of the ligand.(iii) What is the denticity of the ligand?(iv) What is the charge of the ligand?(v) Draw the structure of a homoleptic octahedral complex with ox as the ligand.Clearly show the geometry at the metal centre.(vi) Identify the stereoisomer in the structure drawn.
Heating 2.0 mol of a coordination compound gives 1.0mol NH3, 2.0 mol H2O, 1.0 mol HCl, and 1.0 mol(NH4)3[Ir2Cl9]. Write the formula of the original (sixcoordinate) coordination compound and name it.
Heating 3.0 mol of a coordination compound gives 1.5 mol of ammonia, 3.0 mol of water 1.5 mol of HCl and 1.5 mol of (NH4)3[Ir2Cl9]. Write the formula of the original (six-coordinate) coordination compound and name it.
Chapter 24 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
Ch. 24 - Prob. 1ECh. 24 - Prob. 2ECh. 24 - Prob. 3ECh. 24 - Write appropriate formulas for the following. a....Ch. 24 - Prob. 5ECh. 24 - Prob. 6ECh. 24 - Prob. 7ECh. 24 - Prob. 8ECh. 24 - Prob. 9ECh. 24 - Prob. 10E
Ch. 24 - Prob. 11ECh. 24 - Prob. 12ECh. 24 - If A, B, C, and D are four different ligands, a....Ch. 24 - Prob. 14ECh. 24 - Prob. 15ECh. 24 - The structures of four complex ions are given....Ch. 24 - Prob. 17ECh. 24 - Prob. 18ECh. 24 - Prob. 19ECh. 24 - In contrast to the case of Co2+ considered in...Ch. 24 - Prob. 21ECh. 24 - Prob. 22ECh. 24 - Prob. 23ECh. 24 - Prob. 24ECh. 24 - Prob. 25ECh. 24 - Prob. 26ECh. 24 - Prob. 27ECh. 24 - Prob. 28ECh. 24 - Prob. 29ECh. 24 - Prob. 30ECh. 24 - Prob. 31ECh. 24 - Prob. 32ECh. 24 - Prob. 33ECh. 24 - Prob. 34ECh. 24 - Prob. 35ECh. 24 - Prob. 36ECh. 24 - Prob. 37ECh. 24 - Draw dashed and solid wedge diagrams of...Ch. 24 - Prob. 39IAECh. 24 - Prob. 40IAECh. 24 - Prob. 41IAECh. 24 - Prob. 42IAECh. 24 - Prob. 43IAECh. 24 - Prob. 44IAECh. 24 - Prob. 45IAECh. 24 - Prob. 46IAECh. 24 - Prob. 47IAECh. 24 - Prob. 48IAECh. 24 - Prob. 49IAECh. 24 - Prob. 50IAECh. 24 - Prob. 51IAECh. 24 - Prob. 52IAECh. 24 - Prob. 53IAECh. 24 - Prob. 54IAECh. 24 - The compound CoCl22H2O4NH2 may be one of the...Ch. 24 - Prob. 56IAECh. 24 - Provide a valence bond description of the bonding...Ch. 24 - Prob. 58IAECh. 24 - Prob. 59IAECh. 24 - Prob. 60IAECh. 24 - Prob. 61IAECh. 24 - Prob. 62IAECh. 24 - The graph that follows represents the molar...Ch. 24 - Prob. 64FPCh. 24 - Prob. 65FPCh. 24 - The crystal field stabilization energy (CFSE) can...Ch. 24 - In your own words, describe the following terms or...Ch. 24 - Briefly describe each of the following ideas,...Ch. 24 - Prob. 69SAECh. 24 - The oxidation state of Ni in the complex ion...Ch. 24 - Prob. 71SAECh. 24 - Prob. 72SAECh. 24 - Prob. 73SAECh. 24 - Prob. 74SAECh. 24 - Prob. 75SAECh. 24 - The most soluble of the following solids in...Ch. 24 - Prob. 77SAECh. 24 - Write appropriate formulas for the following...Ch. 24 - Prob. 79SAECh. 24 - Prob. 80SAECh. 24 - Prob. 81SAECh. 24 - Prob. 82SAECh. 24 - Prob. 83SAECh. 24 - Prob. 84SAE
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- What structural feature is used to determine whether a compound can exist as optical isomers?arrow_forward(a) Name this coordination compound: [Ag(NH3)2]NO3. (b) Write the formula of pentaaquaisothiocyanatoiron(III) chloride.arrow_forwardFour different octahedral chromium coordination compounds exist that all have the same oxidation state for chromium and have H2O and Cl as the ligands and counterions. When 1 mole of each of the four compounds is dissolved in water, how many moles of silver chloride will precipitate upon addition of excess AgNO3?arrow_forward
- Platinum(II) forms many complexes, among them those with the following ligands. Give the formula and charge of each complex. (a) two ammonia molecules and one oxalate ion (C2O42-) (b) two ammonia molecules, one thiocyanate ion (SCN-), and one bromide ion (c) one ethylenediamine molecule and two nitrite ionsarrow_forward(c) Consider the following coordination compound [Mn(acac)2Br2]² and answer the questions which follow: (i) Draw the structure of the acac ligand. Clearly show the charge on the structure. (ii) Draw all possible isomers of [Mn(acac) 2Br2]², an octahedral complex Clearly show the geometry at the central metal ion.arrow_forwardA complex ion is formed from one Fe*, two CN and four NO, ions. (a) What is the structural formula and name of the complex ion? (b) Identify the type of isomerism and draw the isomer structures exhibited by the complex ion. (c) Draw the molecular orbital diagram and calculate the CFSE for the complex ion.arrow_forward
- CoCl3(H2N-CH2-CH2-NH2)2(H2O) corresponds to the empirical formula of two coordination compounds denoted A and B. When A is reacted with silver nitrate, 2/3 of the chlorine atoms precipitate. B, submitted to the same treatment, exhibits the precipitation of 1/3 of the present chlorine atoms. What are the formulas of compounds A and B?arrow_forwardPyridine (CsHgN), abbreviated py, is the molecule N: (a) Would you expect pyridine to act as a monodentate or bidentate ligand? (b) For the equilibrium reaction [Ru(py),(bipy)]²+ + 2 py = [Ru(py),J* + bipy would you predict the equilibrium constant to be larger or smaller than one?arrow_forwardA coordination compound has been determined to be composed of 18.4% Co, 26.6% NH3, 30.0% SO4 , and 25.0% Br–, by mass. The compound was also determined to have two different isomers, A and B, such that the solution of isomer-A was found to react with AgNO3(aq) to produce AgBr precipitate, but the reaction with Ba(NO3)2(aq) did not produce any precipitate. While the solution of isomer-B did not produce any precipitate when reacted with AgNO3(aq), but it produced BaSO4 precipitated when the solution is reacted with Ba(NO3)2(aq). (a) Determine the empirical formula of the compound written in the form of Co(NH3)x(SO4)yBrz. (b) Assuming that all of NH3 molecules in the formula are ligands, deduce the Werner’s formula for isomers A and B, respectively, and give the systemic name for each isomer.(c) Write molecular equations for the reaction of each isomer with AgNO3(aq) and Ba(NO3)2(aq).arrow_forward
- (a) Draw a Lewis dot and cross structure (including any lone pairs) for a NBr3 molecule and determine the shape of the molecule and number of valence electrons. (b) Six ammonia ligands form a complex ion with Co²+. What is the overall charge of the complex ion? Write the formula for the complex ion. What is the coordination number of the complex ion? Explain how ammonia ligands form a complex ion with Co²+? What is the geometry of the complex ion? Would you expect the complex to be coloured? Explain why? i. ii. iii. iv. V. vi.arrow_forwardCoCl3(H2N-CH2-CH2-NH2)2(H2O) corresponds to the empirical formula of two coordination compounds denoted A and B. When A is reacted with silver nitrate, 2/3 of the chlorine atoms precipitate. B, submitted to the same treatment, exhibits the precipitation of 1/3 of the present chlorine atoms. What are the spatial structures of complex ions A and B? (If necessary, draw their different stereoisomers).arrow_forward(b) Explain the bonding in coordination compounds in terms of Werner's postulates.arrow_forward
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