The structure of the following complexes has to be drawn and whether they exhibit optical isomerism has to be determined. (a) I r ( e n ) 3 2 + (b) [ I r ( H 2 O ) 3 C l 3 ] Concept Introduction: Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism. In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

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Answer 1

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Chapter 22, Problem 22.79QP

Interpretation Introduction

Interpretation:

The structure of the following complexes has to be drawn and whether they exhibit optical isomerism has to be determined.

(a) Ir(en)32+ (b) [Ir(H2O)3Cl3]

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

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Explain how the equation 4Fe(OH)2(s) + O2(g)→2Fe2O3(s) + 4H2O(l) in the article illustrates the oxidation of the iron ions in the reactants

Answer 2

Question

Chapter 22, Problem 22.79QP

Interpretation Introduction

Interpretation:

The structure of the following complexes has to be drawn and whether they exhibit optical isomerism has to be determined.

(a) Ir(en)32+ (b) [Ir(H2O)3Cl3]

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

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Answer 3

Question

Chapter 22, Problem 22.79QP

Interpretation Introduction

Interpretation:

The structure of the following complexes has to be drawn and whether they exhibit optical isomerism has to be determined.

(a) Ir(en)32+ (b) [Ir(H2O)3Cl3]

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

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Answer 4

Question

Chapter 22, Problem 22.79QP

Interpretation Introduction

Interpretation:

The structure of the following complexes has to be drawn and whether they exhibit optical isomerism has to be determined.

(a) Ir(en)32+ (b) [Ir(H2O)3Cl3]

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

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Answer 5

Chapter 22, Problem 22.79QP

Interpretation Introduction

Interpretation:

The structure of the following complexes has to be drawn and whether they exhibit optical isomerism has to be determined.

(a) Ir(en)32+ (b) [Ir(H2O)3Cl3]

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 6

Chapter 22, Problem 22.79QP

Interpretation Introduction

Interpretation:

The structure of the following complexes has to be drawn and whether they exhibit optical isomerism has to be determined.

(a) Ir(en)32+ (b) [Ir(H2O)3Cl3]

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 7

Chapter 22, Problem 22.79QP

Interpretation Introduction

Interpretation:

The structure of the following complexes has to be drawn and whether they exhibit optical isomerism has to be determined.

(a) Ir(en)32+ (b) [Ir(H2O)3Cl3]

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 8

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Answer 10

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Answer 11

Ch. 22.3 - Another complex studied by Werner had a...Ch. 22.4 - Prob. 22.1E Ch. 22.4 - Prob. 22.2E Ch. 22.5 - Prob. 22.2CC Ch. 22.5 - Prob. 22.3E Ch. 22.5 - Prob. 22.4E Ch. 22.5 - Prob. 22.3CC Ch. 22.7 - Prob. 22.5E Ch. 22.7 - Prob. 22.6E Ch. 22.7 - Prob. 22.7E

Solution Summary: The author explains that the structure of the following complexes has to be drawn and whether they exhibit optical isomerism.

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Chapter 22 Solutions