The structure of the following complexes has to be drawn and whether they exhibit optical isomerism has to be determined. (a) I r ( e n ) 3 2 + (b) [ I r ( H 2 O ) 3 C l 3 ] Concept Introduction: Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism. In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Question

Want to see the full answer?

Answer 1

Question

Chapter 22, Problem 22.79QP

Interpretation Introduction

Interpretation:

The structure of the following complexes has to be drawn and whether they exhibit optical isomerism has to be determined.

(a) Ir(en)32+ (b) [Ir(H2O)3Cl3]

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

What is the IUPAC name of [Pd(CN)2(en)2][PtCl4]?

Name and draw all the possible stereoisomers (diastereoisomers, enantiomers) of the following complexes, which you expect to be optically active? Why? [Rh(H2O)4Cl2]NO2 [Ir(PR3)2(H)(CO)] [V(NH3)3Cl3] [Co(CO)2(en)ClBr]NO2

draw the structure of [Fe(NH3)3(OH2)3][PtCl4]

Answer 2

Question

Chapter 22, Problem 22.79QP

Interpretation Introduction

Interpretation:

The structure of the following complexes has to be drawn and whether they exhibit optical isomerism has to be determined.

(a) Ir(en)32+ (b) [Ir(H2O)3Cl3]

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 22, Problem 22.79QP

Interpretation Introduction

Interpretation:

The structure of the following complexes has to be drawn and whether they exhibit optical isomerism has to be determined.

(a) Ir(en)32+ (b) [Ir(H2O)3Cl3]

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 22, Problem 22.79QP

Interpretation Introduction

Interpretation:

The structure of the following complexes has to be drawn and whether they exhibit optical isomerism has to be determined.

(a) Ir(en)32+ (b) [Ir(H2O)3Cl3]

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 22, Problem 22.79QP

Interpretation Introduction

Interpretation:

The structure of the following complexes has to be drawn and whether they exhibit optical isomerism has to be determined.

(a) Ir(en)32+ (b) [Ir(H2O)3Cl3]

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 6

Chapter 22, Problem 22.79QP

Interpretation Introduction

Interpretation:

The structure of the following complexes has to be drawn and whether they exhibit optical isomerism has to be determined.

(a) Ir(en)32+ (b) [Ir(H2O)3Cl3]

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 7

Chapter 22, Problem 22.79QP

Interpretation Introduction

Interpretation:

The structure of the following complexes has to be drawn and whether they exhibit optical isomerism has to be determined.

(a) Ir(en)32+ (b) [Ir(H2O)3Cl3]

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of a molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 8

Expert Solution & Answer

Answer 9

Expert Solution & Answer

Answer 10

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 11

Ch. 22.3 - Another complex studied by Werner had a...Ch. 22.4 - Prob. 22.1E Ch. 22.4 - Prob. 22.2E Ch. 22.5 - Prob. 22.2CC Ch. 22.5 - Prob. 22.3E Ch. 22.5 - Prob. 22.4E Ch. 22.5 - Prob. 22.3CC Ch. 22.7 - Prob. 22.5E Ch. 22.7 - Prob. 22.6E Ch. 22.7 - Prob. 22.7E

Solution Summary: The author explains that the structure of the following complexes has to be drawn and whether they exhibit optical isomerism.

Concept explainers

Want to see the full answer?

Chapter 22 Solutions