Concept explainers
Interpretation:
Using crystal field theory, the crystal field energy diagram of low-spin complex
Concept Introduction:
There are five d-orbitals in a metal ion. They have similar energy levels that they are degenerated. Under the influence of ligands during complex formation, the degeneracy in d-orbitals is destroyed that they are split into two sets of orbitals - one set having lower energy and the another set is higher in energy. Crystal field splitting refers to the difference in energy levels between these two sets of d-orbitals.
When ligands approach the metal ion the degeneracy in d-orbitals of the metal ion is destroyed and they split into two different energy levels. In case of octahedral complex, the
Trending nowThis is a popular solution!
Chapter 22 Solutions
General Chemistry - Standalone book (MindTap Course List)
- Give the number of unpaired electrons in octahedral complexes with strong-field ligands for (a) Rh3+ (b) Mn3+ (c) Ag+ (d) Pt4+ (e) Au3+arrow_forwardWhat types of isomers are possible for the following compounds or complex ions? (a) K[Co(NH3)2Cl4] (b) Pt(en)Cl2 (square-planar) (c) [Co(NH3)5Cl]2+ (d) [Ru(phen)3]Cl3 (e) Na2[MnCl4] (tetrahedral) (f) [Co(NH3)5NO2)2+arrow_forwardAn aqueous solution of [Rh(C2O4)3]3− is yellow. Predict the approximate wavelength and predominant color of light absorbed by the complex.arrow_forward
- General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
- Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning