That the boiling point of ether is lower than the boiling point of alcohol.

Expert Solution & Answer

Answer to Problem 13TE

The boiling point of alcohols is higher than ether mainly due to the presence of intermolecular hydrogen bonding which is lacking in ethers and hydrocarbons.

Explanation of Solution

Intermolecular Hydrogen bonding occurs between the electronegative element like oxygen, nitrogen, or fluorine atom of one molecule and hydrogen of another molecule attached to the another highly electronegative atom.

Both alcohols and ether have similar molar masses but in alcohol due to the presence of the oxygen element there occurs a strong intermolecular hydrogen bond between the oxygen atom of one alcohol and hydrogen of another alcohol molecule connected with oxygen atom.

Conclusion:

Therefore, the boiling point of alcohols is higher than ether because of intermolecular hydrogen bonding which is lacking in ethers and hydrocarbons.

Chapter 22, Problem 12TE

Chapter 22, Problem 14TE

Chapter 22 Solutions

Conceptual Physical Science Explorations

Ch. 22 - What are some uses of hydrocarbons?Ch. 22 - How do two structural isomers differ from each...Ch. 22 - How are two structural isomers similar to each...Ch. 22 - What physical property of hydrocarbons is used in...Ch. 22 - To how many atoms is a saturated carbon atom...Ch. 22 - What is the difference between a saturated...Ch. 22 - How many multiple bonds must a hydrocarbon have in...Ch. 22 - Aromatic compounds contain what kind of ring?Ch. 22 - What is a heteroatom?Ch. 22 - Which heteroatom is characteristic of an alcohol?

Ch. 22 - Why are low formula mass alcohols soluble in...Ch. 22 - What distinguishes an alcohol from an ether?Ch. 22 - Which heteroatom is characteristic of an amine?Ch. 22 - Do amines tend to be acidic, neutral, or basic?Ch. 22 - Are alkaloids found in nature?Ch. 22 - Which elements make up the carbonyl group?Ch. 22 - How are ketones and aldehydes related to each...Ch. 22 - How are amides and carboxylic acids related to...Ch. 22 - What happens to the double bond of a monomer...Ch. 22 - What is released in the formation of a...Ch. 22 - Rank the following hydrocarbons in order of...Ch. 22 - Prob. 2TC Ch. 22 - Rank the following molecule in order of the...Ch. 22 - Rank the following organic molecules in order of...Ch. 22 - What property of carbon allows for the formation...Ch. 22 - Prob. 2TE Ch. 22 - Hydrocarbons release a lot of energy when ignited....Ch. 22 - There are five atoms in the methane molecule, CH4...Ch. 22 - What is the chemical formula for the following...Ch. 22 - What is the chemical formula for the following...Ch. 22 - Shown below is the structure of 2-methyl-pentane....Ch. 22 - Prob. 8TE Ch. 22 - Prob. 9TE Ch. 22 - Prob. 10TE Ch. 22 - Prob. 11TE Ch. 22 - Why do heteroatoms make such a difference in the...Ch. 22 - Prob. 13TE Ch. 22 - A common inactive ingredient in products such as...Ch. 22 - Suggest an explanation for why aspirin has a sour...Ch. 22 - An amino acid is an organic molecule that contains...Ch. 22 - Identify the following functional groups in the...Ch. 22 - The chemical compound lysine is shown below. What...Ch. 22 - Prob. 19TE Ch. 22 - Prob. 20TE Ch. 22 - Why does the melting point of hydrocarbons...Ch. 22 - Prob. 2RAT Ch. 22 - Prob. 3RAT Ch. 22 - Prob. 4RAT Ch. 22 - Why might a high-formula- mass alcohol be...Ch. 22 - Alkaloid salts are not very soluble in the organic...Ch. 22 - Explain why caprylic acid, CH3 (CH2)6COOH...Ch. 22 - How many oxygen atoms are bonded to the carbon of...Ch. 22 - One solution to the problem of our overflowing...Ch. 22 - Which would you expect to be more viscous-a...

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