Concept explainers
a)
Interpretation:
A sugar that is
Concept Introduction:
Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,
b)
Interpretation:
A sugar that is
Concept Introduction:
Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,
c)
Interpretation:
A sugar that is
Concept Introduction:
Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,
d)
Interpretation:
A sugar that is
Concept Introduction:
Epimers are the monosaccharides which differ in the structure at only one of the asymmetric center and they are particular kind of stereoisomers that are not enantiomers. For example,
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Organic Chemistry (8th Edition)
- Draw the products formed when B-D-galactose is treated with each reagent. a. Ag,0 + CH3I b. NaH + CgHsCH2CI c. The product in (b), then H30* d. Ac20 + pyridine e. CeHsCOCI + pyridine f. The product in (c), then CgHsCOCI + pyridinearrow_forwardD-Arabinose can exist in both pyranose and furanose forms. a. Draw the α and β anomers of D-arabinofuranose. b. Draw the α and β anomers of D-arabinopyranose.arrow_forwardWhat is the configuration of each of the asymmetric centers in the Fischer projection ofa. d-glucose? b. d-galactose? c. d-ribose? d. d-xylose? e. d-sorbose?arrow_forward
- m) Which pyranose ring (A, B, C, or D) in the tetrasaccharide below is derived from D-altrose? The Fischer projections for the four aldohexoses that make up this tetrasaccharide are shown below. B C D HOH CHO CHO CHO CHO HO+H HTOH Fонно н HOH HOH H-OH H-OH H-+-OH H-TOHHOH HOH H+OH HOHнтон нон CHOH CHOH CHOH CHOH De D-glue Dalose Datrone i NH Į HOH STEP 1 OH, HO- answer 1. Just add arrows and charges for steps 1, 2, and 3 in formation of this enamine з no arrows needed here OH н Н ЮН -OH STEP 3 :ÖH н H STEP 2 на это про за почarrow_forwardDraw Haworth projection formulas for the a-anomer of monosaccharides with each of the following Fischer projection formulas. a. CHO HOH H- HO- H -ОН -Η OH CH₂OH b. CHO H -OH H -ОН HO H CH₂OHarrow_forwardWhich one of the following is NOT a possible completion of the following reaction? CH₂OH HO- HO- 1. NaBH, ? 2. acidic workup HO- H A. D-talose B. D-tagatose C. the C-3 epimer of D-gulose D. the C-5 epimer of L-psicose E. the C-5 epimer of L-allose F. the C-3 epimer of D-idose G. g. the C-3 epimer of L-glucose -H -H -H -OH CH₂OHarrow_forward
- Which one of the following is NOT a possible completion of the following reaction? CH₂OH HO HO 1. NaBH 2. acidic workup HO 80 F3 A. D-talose B. D-tagatose C. the C-3 epimer of D-gulose D. the C-5 epimer of L-psicose E. the C-5 epimer of L-allose F. the C-3 epimer of D-idose G. g. the C-3 epimer of L-glucose OA B C OD OE OF U G H- F4 F5 H H -H -OH CH₂OH F6 F7 DII FBarrow_forwardDraw the products formed when β-D-galactose is treated with each reagent. a. Ag2O + CH3I b. NaH + C6H5CH2Cl c. The product in (b), then H3O+ d. Ac2O + pyridine e. C6H5COCl + pyridine f. The product in (c), then C6H5COCl + pyridinearrow_forwardPart A What sugar is the C-3 epimer of D-psicose? Spell out the full name of the compound.arrow_forward
- Draw Fischer projection of the mirror image (enantiomer) D-robose c. Are these molecules superimposable? d. What type of isomerism is represented by these mirror images? e. Construct a model of a third isomer that is not a mirror image of the two above.arrow_forward6. The Fischer projection for fructose is shown below. Is it a D-sugar or an L-sugar? a. It is a D-sugar because the hydroxyl at carbon A is to the right. b. It is a D-sugar because the carbonyl at carbon B is to the right. c. It is a D-sugar because the hydroxyl at carbon C is to the right d. It is an L-sugar because the carbonyl at carbon B is to the right. e. It is an L-sugar because the hydroxyl at carbon C is to the right. ACH2OH BFO H OH H OH H-OH CH2OH 7. Which of the following tynes of carbohydrates can be hydrelvzed to givo smaller molecules?arrow_forwardОН 2. the Fischer projection that corresponds to the monosaccharide shown in the box. О н HO OH но- OH НО 0 OH OH OH H-OH -ОН 3. the Haworth projection that corresponds to the structure shown in the box. OCH, НО OH athul algasida О Н H-OH H-OH но-н но- HO -O OCH, OH O H H-OH НО-Н H-OH H-OH OH ОН НО НО OOCH, HO H-OH но-н но-н OH H-OH OH НО OH OCH, OH OH О н H-OH H-OH H НО но-н ОН НО -oOCH, ОН он онarrow_forward
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